N,N'-diphenyl-N,N'-di(p-tolyl)pyrene-1,6-diamine | 668019-96-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N'-diphenyl-N,N'-di(p-tolyl)pyrene-1,6-diamine
• 英文别名: 1-N,6-N-bis(4-methylphenyl)-1-N,6-N-diphenylpyrene-1,6-diamine
• CAS: 668019-96-3
• 化学式: C₄₂H₃₂N₂
• 分子量: 564.729
• InChiKey: FWKFTAWTOFEJOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.2
• 重原子数：
  44
• 可旋转键数：
  6
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,6-二溴芘 、 4-甲基-N-苯基苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以63%的产率得到N,N'-diphenyl-N,N'-di(p-tolyl)pyrene-1,6-diamine
  参考文献：
  名称：

  Emission Color Tuning and Deep Blue Dopant Materials Based on 1,6-Bis(N-phenyl-p-(R)-phenylamino)pyrene

  摘要：

  Panchromatic 1,6-bis(N-phenyl-p-(R)-phenylamino)pyrenes, 2R, were obtained from Buchwald-Hartwig coupling reactions between N-phenyl-p-(R)-phenylamines and 1,6-dibromopyrene. The photophysical properties of 2R corresponded well to the electron-withdrawing and -donating nature of the diarylamine substituents, exhibiting a full color visible range between 454 and 620 nm. In particular, a deep blue 2CN showed a high radiative rate constant of 2.85 x 10(8) s(-1) with high emission quantum efficiency of 79%. Further applications of 2CN its it blue dopant were attempted using multilayer organic light-emitting devices. A maximum efficiency of 3.98 cd/A with CIE coordinates of x = 0.14, y = 0.10 were obtained.

  DOI：

  10.1021/jo901783a

文献信息

• ORGANIC LIGHT EMITTING DIODE FOR HIGH EFFICIENCY
  申请人：SFC CO., LTD.

  公开号：US20170018723A1

  公开（公告）日：2017-01-19

  Disclosed herein is an organic light-emitting diode, comprising: a first electrode, a second electrode opposite the first electrode, and a light-emitting layer and an electron-density-controlling layer in that order between the first electrode and the second electrode, wherein the electron-density-controlling layer includes at least one selected from among compounds represented by Chemical Formulas A to D, and the light-emitting layer includes at least one anthracene compound represented by Chemical Formula H. The electron-density-controlling layer may be disposed between the light-emitting layer and an electron transport layer.

  本文揭示了一种有机发光二极管，包括：第一电极，与第一电极相对的第二电极，以及依次位于第一电极和第二电极之间的发光层和控制电子密度层，其中控制电子密度层包括至少一种化学式A至D所代表的化合物中的一种，发光层包括至少一种化学式H所代表的蒽化合物。控制电子密度层可以位于发光层和电子传输层之间。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND ELECTRONIC APPARATUS PROVIDED WITH THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20200111965A1

  公开（公告）日：2020-04-09

  An organic electroluminescence device including a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer contains a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by formulas (11), (21), (31), (41), (51), (61), (71) and (81). In the formula (1), at least one of R 1 to R 8 is a deuterium atom.

  一种有机电致发光器件，包括阴极、阳极以及设置在阴极和阳极之间的发光层，其中该发光层包含以下式（1）所表示的化合物和从以下式（11）、（21）、（31）、（41）、（51）、（61）、（71）和（81）所表示的化合物组成的化合物中选择的一个或多个化合物。在式（1）中，R1至R8中的至少一个是氘原子。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：SEO Jeong Dae

  公开号：US20100155714A1

  公开（公告）日：2010-06-24

  Disclosed is an organic electroluminescent device including a substrate, a first and a second electrode, and an emitting layer formed between the first electrode and the second electrode. The emitting layer includes a plurality of materials which is a blue emitting material using a following chemical formula as dopant. In this case, at least one of A 1 and A 2 is selected from a substituted or non-substituted aromatic group, a heterocyclic group, an aliphatic group, and hydrogen.

  揭示了一种有机电致发光器件，包括基板、第一和第二电极，以及形成在第一电极和第二电极之间的发光层。发光层包括多种材料，其中一种是使用以下化学式作为掺杂剂的蓝色发光材料。在这种情况下，A1和A2中至少有一个是从取代或非取代芳香基团、杂环基团、脂肪基团和氢中选择的。
• POLYCYCLIC AROMATIC COMPOUND, MATERIAL FOR AN ORGANIC DEVICE, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY APPARATUS AND LIGHTING APPARATUS
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US20200207787A1

  公开（公告）日：2020-07-02

  A polycyclic aromatic compound in which a plurality of aromatic rings are connected by a boron atom and an oxygen atom, a sulfur atom or a selenium atom and substituted by a specific aryl such as anthracene, is useful as a material for an organic device. By the polycyclic aromatic compound, an organic EL device having at least one of efficiency and device life can be provided.

  一种多环芳香化合物，其中多个芳香环通过硼原子和氧原子、硫原子或硒原子连接，并以特定的芳基（如蒽）取代，可用作有机器件的材料。通过这种多环芳香化合物，可以提供至少在效率和器件寿命方面具有优势的有机EL器件。
• ORGANIC LIGHT-EMITTING DIODE HAVING LONG LIFESPAN, LOW VOLTAGE, AND HIGH EFFICIENCY PROPERTY
  申请人：SFC CO., LTD.

  公开号：US20210288266A1

  公开（公告）日：2021-09-16

  The present disclosure relates to an organic light-emitting diode and, more particularly, to an organic-light-emitting diode comprising: a first electrode; a second electrode facing the first electrode; and a light-emitting layer intercalated between the first electrode and the second electrode, wherein the light-emitting layer comprises at least one of the amine compounds represented by the following Chemical Formula A and at least one of the anthracene compounds represented by the following Chemical Formula B or C. The structures of Chemical Formulas A to C are the same as in the specification.

  本公开涉及一种有机发光二极管，更具体地说，涉及一种包括：第一电极；朝向第一电极的第二电极；以及夹在第一电极和第二电极之间的发光层的有机发光二极管，其中该发光层包括下述化学式A表示的胺化合物中的至少一种，以及下述化学式B或C表示的蒽化合物中的至少一种。化学式A至C的结构与规范中的相同。