o-C6H4F(CH=NC6H3Et2-2,6) | 1033852-67-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-C6H4F(CH=NC6H3Et2-2,6)
• 英文别名: N-(2,6-diethylphenyl)-1-(2-fluorophenyl)methanimine
• CAS: 1033852-67-3
• 化学式: C₁₇H₁₈FN
• 分子量: 255.335
• InChiKey: FCBWSWLIYXFCHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  o-C6H4F(CH=NC6H3Et2-2,6) 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  Al and Zn complexes bearing N,N,N-tridentate quinolinyl anilido-imine ligands: synthesis, characterization and catalysis in l-lactide polymerization

  摘要：

  和3c。

  DOI：

  10.1039/c2dt30594a

文献信息

• Synthesis of Ti, Zr, and Hf complexes with a new tetra-azane ligand by one-pot HCl-elimination and their properties as catalysts for production of UHMWPE
  作者：Xiangdong Ji、Wei Yao、Xuyang Luo、Wei Gao、Ying Mu

  DOI：10.1039/c5nj02151k

  日期：——

  The first example for the HCl-elimination reaction being applied in the attachment of an amido-containing ligand to Zr and Hf.

  HCl-消除反应的第一个例子是将含有氨基配体附着到锆和铪上。
• Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides
  作者：Qiumiao Shen、Xiaoli Ma、Wenling Li、Wenqing Liu、Yi Ding、Zhi Yang、Herbert W. Roesky

  DOI：10.1002/chem.201902000

  日期：2019.9.12

  The effective catalytic activity of organoaluminum compounds for the monohydroboration of carbodiimides has been demonstrated. Two aluminum complexes, 2 and 3, were synthesized and characterized. The efficient catalytic performances of four aluminum hydride complexes L1AlH2 (L1=HC(CMeNAr)2, Ar=2,6‐Et2C6H3; 1), L2AlH2(NMe3) (L2=o‐C6H4F(CH=N‐Ar), Ar=2,6‐Et2C6H3; 2), L3AlH (L3=2,6‐bis(1‐methylethyl)‐

  有机铝化合物对碳二亚胺单硼氢化反应的有效催化活性已得到证实。合成并表征了两种铝配合物2和3。四种氢化铝配合物L 1 AlH 2 (L 1 =HC(CMeNAr) 2 , Ar=2,6-Et 2 C 6 H 3 ; 1 )、L 2 AlH 2 (NMe 3 ) (L 2 = o -C 6 H 4 F(CH=N-Ar), Ar=2,6-Et 2 C 6 H 3 ; 2 ), L 3 AlH (L 3 =2,6-双(1-甲基乙基)- N- (2-吡啶基亚甲基)苯胺；3 )，和L 4 AlH(NMe 3 ) (L 4 = o -C 6 H 4 ( N -Dipp)(CH=N-Dipp)，Dipp=2,6- i Pr 2 C 6 H 3 ; 4 ) 和烷基铝配合物 L 1 AlMe 2 ( 5 ) 用于在无溶剂和温和条件下研究碳二亚胺的单硼氢化反应。化合物1-3和5可以产生单硼氢化N-硼基甲脒，而4
• [N,N,N,N]四齿配体第四副族过渡金属配合 物及其制备方法和用途
  申请人：吉林大学

  公开号：CN105001255B

  公开（公告）日：2017-12-22

  本发明属于烯烃聚合催化剂的技术领域。本发明的[N,N,N,N]四齿配体第四副族过渡金属配合物，具有如下I或II型的结构通式，将Ti、Zr或Hf的卤化物的甲苯溶液与I型四齿配体的甲苯溶液混合，反应1～12小时，蒸出溶剂甲苯，继续反应1～3小时即可得到配合物粗产物，进一步在有机溶剂中重结晶得到具有I型结构通式的配合物；以本发明的配合物为主催化剂，可用于催化乙烯聚合反应。本发明的配合物结构稳定，耐热性能好，寿命长，催化活性高，催化乙烯聚合所得聚乙烯具有超高分子量。
• Al and Zn complexes bearing N,N,N-tridentate quinolinyl anilido-imine ligands: synthesis, characterization and catalysis in l-lactide polymerization
  作者：Nan Yang、Lan Xin、Wei Gao、Jingshun Zhang、Xuyang Luo、Xiaoming Liu、Ying Mu

  DOI：10.1039/c2dt30594a

  日期：——

  Reactions of N,N,N-tridentate quinolinyl anilido-imine ligands with AlMe3 afford mononuclear aluminum complexes κ3-[2-[ArNC(H)]C6H4}N(8-C9H6N)]}AlMe2 (Ar = 2,6-Me2C6H3 (1a), 2,6-Et2C6H3 (1b), 2,6-iPr2C6H3 (1c)) or dinuclear complexes AlMe3κ1-[2-[ArNC(H)C6H4]N(8-C9H6N)}-κ2]AlMe2 (R = 2,6-Me2C6H3 (2a), 2,6-Et2C6H3 (2b), 2,6-iPr2C6H3 (2c)) depending on the ratios of reactants used. Similar reactions of ZnEt2 with these ligands give the monoligated ethyl zinc complexes κ3-[2-[ArNC(H)]C6H4}N(8-C9H6N)]}ZnEt (Ar = 2,6-Me2C6H3 (3a), 2,6-Et2C6H3 (3b), 2,6-iPr2C6H3 (3c)) or bisligated complexes κ3-[2-[ArNC(H)]C6H4}N(8-C9H6N)]}Znκ2-[2-[ArNC(H)]C6H4}N(8-C9H6N)]} (Ar = 2,6-Me2C6H3 (4a), 2,6-Et2C6H3 (4b), 2,6-iPr2C6H3 (4c)). These complexes were well characterized by NMR and the structures of 1a, 2a, 2c, 3b and 4c were confirmed by X-ray diffraction analysis. The aluminum and zinc complexes were tested to initiate lactide polymerization in which the zinc complexes show moderate to high activities in the presence of benzyl alcohol.

  和3c。