3-ethynyl-4-[2-(4'-pyridinyl)ethenyl]pyridine | 1286209-96-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3-ethynyl-4-[2-(4'-pyridinyl)ethenyl]pyridine
• 英文别名: trans-1,2-dipyridylethene；(E)-3-Ethynyl-4-(2-(pyridin-4-yl)vinyl)pyridine；3-ethynyl-4-[(E)-2-pyridin-4-ylethenyl]pyridine
• CAS: 1286209-96-8
• 化学式: C₁₄H₁₀N₂
• 分子量: 206.247
• InChiKey: JHZVYKSUIZTKPM-ONEGZZNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  zinc(II) nitrate hexahydrate 、 1,4-dibromo-2,3,5,6-tetrakis(4-carboxyphenyl)benzene 、 3-ethynyl-4-[2-(4'-pyridinyl)ethenyl]pyridine 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Kinetic Separation of Propene and Propane in Metal−Organic Frameworks: Controlling Diffusion Rates in Plate-Shaped Crystals via Tuning of Pore Apertures and Crystallite Aspect Ratios

  摘要：

  A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5-tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.

  DOI：

  10.1021/ja200553m
• 作为产物：
  描述：

  3-[(trimethylsilyl)ethynyl]-4-[2-(4'-pyridinyl)ethenyl]pyridine 在 potassium carbonate 作用下， 以 甲醇 为溶剂， 反应 0.5h， 以80%的产率得到3-ethynyl-4-[2-(4'-pyridinyl)ethenyl]pyridine
  参考文献：
  名称：

  Kinetic Separation of Propene and Propane in Metal−Organic Frameworks: Controlling Diffusion Rates in Plate-Shaped Crystals via Tuning of Pore Apertures and Crystallite Aspect Ratios

  摘要：

  A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5-tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.

  DOI：

  10.1021/ja200553m

文献信息

• SELECTIVE ADSORBENT
  申请人：North Western University

  公开号：EP2825303A1

  公开（公告）日：2015-01-21
• [EN] SELECTIVE ADSORBENT<br/>[FR] ADSORBANT SÉLECTIF
  申请人：UNIV NORTHWESTERN

  公开号：WO2013138729A1

  公开（公告）日：2013-09-19

  Embodiments include selective adsorbents having a structure of Formula (I) where a connection to X represents a connection to a structure of Formula (II), and a connection to Y represents a connection to a structure of Formula (III), where each R1 is independently selected from the group consisting of fluorine, chlorine, bromine, and iodine, and each R2 is independently selected from the group consisting of a hydrogen, an alkyl, an aryl, and a trisubstitutedsilyl group.