N-(9,9-dimethylfluoren-2-yl)-N-[4-[5-(5-ethenylthiophen-2-yl)thiophen-2-yl]phenyl]-9,9-dimethylfluoren-2-amine | 950923-79-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(9,9-dimethylfluoren-2-yl)-N-[4-[5-(5-ethenylthiophen-2-yl)thiophen-2-yl]phenyl]-9,9-dimethylfluoren-2-amine
• CAS: 950923-79-2
• 化学式: C₄₆H₃₇NS₂
• 分子量: 667.938
• InChiKey: GXRQTYIUKSEQRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.7
• 重原子数：
  49
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  59.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-(9,9-dimethylfluoren-2-yl)-N-[4-[5-(5-ethenylthiophen-2-yl)thiophen-2-yl]phenyl]-9,9-dimethylfluoren-2-amine 在 哌啶 、 三氯氧磷 作用下， 以 乙腈 为溶剂， 反应 8.0h， 生成 5-{5'-[N,N-bis(9,9-dimethylfluoren-2-yl)-4-aminophenyl]-2,2'-bithiophen-5-yl}-2-cyanopenta-2,4-dienoic acid
  参考文献：
  名称：

  Novel conjugated organic dyes containing bis-dimethylfluorenyl amino phenyl thiophene for efficient solar cell

  摘要：

  Two novel organic dyes (JK- 5 and JK- 6) containing bis-dimethylfluorenyl amino phenyl thiophene and additional methine unit are synthesized. Nanocrystalline TiO2 dye-sensitized solar cell was fabricated using these dyes. A solar-to-electric conversion efficiency of 5.12% and 4.78% is achieved with JK- 5 and JK- 6, respectively. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.06.061
• 作为产物：
  描述：

  2-[N,N-bis(9,9-dimethylfluoren-2-yl)aminophenyl]-5,5'-bithienyl 在 potassium tert-butylate 、 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 N-(9,9-dimethylfluoren-2-yl)-N-[4-[5-(5-ethenylthiophen-2-yl)thiophen-2-yl]phenyl]-9,9-dimethylfluoren-2-amine
  参考文献：
  名称：

  Novel conjugated organic dyes containing bis-dimethylfluorenyl amino phenyl thiophene for efficient solar cell

  摘要：

  Two novel organic dyes (JK- 5 and JK- 6) containing bis-dimethylfluorenyl amino phenyl thiophene and additional methine unit are synthesized. Nanocrystalline TiO2 dye-sensitized solar cell was fabricated using these dyes. A solar-to-electric conversion efficiency of 5.12% and 4.78% is achieved with JK- 5 and JK- 6, respectively. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.06.061

文献信息

• Novel conjugated organic dyes containing bis-dimethylfluorenyl amino phenyl thiophene for efficient solar cell
  作者：Sanghoon Kim、Hyunbong Choi、Duckhyun Kim、Kihyung Song、Sang Ook Kang、Jaejung Ko

  DOI：10.1016/j.tet.2007.06.061

  日期：2007.9

  Two novel organic dyes (JK- 5 and JK- 6) containing bis-dimethylfluorenyl amino phenyl thiophene and additional methine unit are synthesized. Nanocrystalline TiO2 dye-sensitized solar cell was fabricated using these dyes. A solar-to-electric conversion efficiency of 5.12% and 4.78% is achieved with JK- 5 and JK- 6, respectively. (c) 2007 Elsevier Ltd. All rights reserved.