2-[N,N-bis(9,9-dimethylfluoren-2-yl)aminophenyl]-5,5'-bithienyl | 503475-44-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-[N,N-bis(9,9-dimethylfluoren-2-yl)aminophenyl]-5,5'-bithienyl
• 英文别名: 2-[N,N-bis-(9,9-dimethylfluoren-2-yl)aminophenyl]-5,5'-bisthiophene；N-(9,9-dimethylfluoren-2-yl)-9,9-dimethyl-N-[4-(5-thiophen-2-ylthiophen-2-yl)phenyl]fluoren-2-amine
• CAS: 503475-44-3
• 化学式: C₄₄H₃₅NS₂
• 分子量: 641.901
• InChiKey: JUTNAWVSKUWQQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  59.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-[N,N-bis(9,9-dimethylfluoren-2-yl)aminophenyl]-5,5'-bithienyl 在 正丁基锂 、 碘 作用下， 以 乙醚 为溶剂， 生成 N-(9,9-dimethylfluoren-2-yl)-N-[4-[5-(5-iodothiophen-2-yl)thiophen-2-yl]phenyl]-9,9-dimethylfluoren-2-amine
  参考文献：
  名称：

  EP2386607

  摘要：

  公开号：
• 作为产物：
  描述：

  2-碘-9,9-二甲基芴 在 四(三苯基膦)钯 氢氧化钾 、 1,10-菲罗啉 、 potassium carbonate 、 copper(l) chloride 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 12.0h， 生成 2-[N,N-bis(9,9-dimethylfluoren-2-yl)aminophenyl]-5,5'-bithienyl
  参考文献：
  名称：

  The role of borole in a fully conjugated electron-rich system

  摘要：

  3,3′-双锂代双噻吩复合物与TipB(OMe)2的反应生成了一种扩展共轭富电子π电子系统的硼杂环，本文描述了通过引入推-拉取代基对电子产生的扰动。

  DOI：

  10.1039/b312028g

文献信息

• Convergent Synthesis of Near-Infrared Absorbing, “Push-Pull”, Bisthiophene-Substituted, Zinc(II) Phthalocyanines and their Application in Dye-Sensitized Solar Cells
  作者：Mine Ince、François Cardinali、Jun-Ho Yum、M. Victoria Martínez-Díaz、Mohammad K. Nazeeruddin、Michael Grätzel、Tomás Torres

  DOI：10.1002/chem.201200020

  日期：2012.5.14

  Zinc(II) phthalocyanine dyes that contain triarylamine‐terminated bisthiophene and hexylbisthiophene groups have been synthesized by a convergent approach by using carboxytriiodo–ZnPc as a precursor. Further transformation of the iodo groups by a Pd‐catalyzed reaction allowed easy preparation of further extended π‐conjugated carboxy–ZnPcs. These dyes have been used as sensitizers in dye‐sensitized

  含有三芳基胺封端的双噻吩和己基双噻吩基团的锌（II）酞菁染料已通过收敛方法使用羧基三碘代-ZnPc作为前体合成。通过Pd催化反应对碘基的进一步转化，可以轻松制备进一步扩展的π共轭羧基-ZnPcs。这些染料已被用作染料敏化太阳能电池中的敏化剂，具有全色响应和中等的整体效率。
• NAPHTHALENE MONOIMIDE DERIVATIVES AND USE THEREOF AS PHOTOSENSITIZERS IN SOLAR CELLS AND PHOTODETECTORS
  申请人：PSCHIRER Neil Gregory

  公开号：US20120165530A1

  公开（公告）日：2012-06-28

  The present invention relates to compounds of the formulae Ia and Ib in which the variables R, n, A, B, R 1 and R 2 are each as defined in the description. The present invention further relates to the use of compounds of the formula Ia or Ib or mixtures of compounds of the formulae Ia and Ib and/or isomers or mixtures of the isomers of the compounds of the formulae Ia and Ib as photosensitizers in solar cells and photodetectors, and to solar cells and photodetectors which comprise such compounds of the formula Ia or Ib or mixtures of compounds of the formulae Ia and Ib and/or isomers or mixtures of the isomers of the compounds of the formulae Ia and Ib as photosensitizers.

  本发明涉及公式Ia和Ib的化合物，其中变量R、n、A、B、R1和R2在描述中各自定义。本发明还涉及将公式Ia或Ib或公式Ia和Ib的混合物和/或公式Ia和Ib的异构体或异构体混合物用作太阳能电池和光电探测器中的光敏剂，以及包含这些公式Ia或Ib的化合物或公式Ia和Ib的混合物和/或公式Ia和Ib的异构体或异构体混合物作为光敏剂的太阳能电池和光电探测器。
• Molecular Engineering of Organic Sensitizers for Solar Cell Applications
  作者：Sanghoon Kim、Jae Kwan Lee、Sang Ook Kang、Jaejung Ko、J.-H. Yum、Simona Fantacci、Filippo De Angelis、D. Di Censo、Md. K. Nazeeruddin、Michael Grätzel

  DOI：10.1021/ja066376f

  日期：2006.12.1

  Novel organic sensitizers comprising donor, electron-conducting, and anchoring groups were engineered at molecular level and synthesized. The functionalized unsymmetrical organic sensitizers 3-5-[N,N-bis(9,9-dimethylfluorene-2-yl)phenyl]-thiophene-2-yl}-2-cyano-acrylic acid (JK-1) and 3-5'-[N,N-bis(9,9-dimethylfluorene-2-yl)phenyl]-2,2'-bisthiophene-5-yl}-2-cyano-acrylic acid (JK-2), upon anchoring

  在分子水平上设计并合成了包含供体、电子传导和锚定基团的新型有机敏化剂。功能化的不对称有机敏化剂 3-5-[N,N-bis(9,9-dimethylfluorene-2-yl)phenyl]-thiophene-2-yl}-2-cyano-acrylic acid (JK-1) 和 3 -5'-[N,N-双(9,9-二甲基芴-2-基)苯基]-2,2'-双噻吩-5-基}-2-氰基-丙烯酸(JK-2)，在锚定在 TiO2 薄膜上，表现出前所未有的入射光子电流转换效率为 91%。使用含有 0.6 M-甲基-N-丁基咪唑鎓碘化物、0.04 M 碘、0.025 M LiI、0.05 M 硫氰酸胍和 0.28 M 叔丁基吡啶的 15/85 (v/v) 电解液的光伏数据戊腈和乙腈的混合物显示短路光电流密度为 14.0 +/- 0.2 mA/cm2，753 +/- 10 mV 的开路电压和 0.76 +/-
• Novel conjugated organic dyes containing bis-dimethylfluorenyl amino phenyl thiophene for efficient solar cell
  作者：Sanghoon Kim、Hyunbong Choi、Duckhyun Kim、Kihyung Song、Sang Ook Kang、Jaejung Ko

  DOI：10.1016/j.tet.2007.06.061

  日期：2007.9

  Two novel organic dyes (JK- 5 and JK- 6) containing bis-dimethylfluorenyl amino phenyl thiophene and additional methine unit are synthesized. Nanocrystalline TiO2 dye-sensitized solar cell was fabricated using these dyes. A solar-to-electric conversion efficiency of 5.12% and 4.78% is achieved with JK- 5 and JK- 6, respectively. (c) 2007 Elsevier Ltd. All rights reserved.
• Dye for dye-sensitized solar cell, and solar cell prepared from same
  申请人：Lee Jae-Kwan

  公开号：US20070240756A1

  公开（公告）日：2007-10-18

  The present embodiments relate to a dye for a dye-sensitized solar cell and a dye-sensitized solar cell prepared from the same. The dye includes a fluorenyl-containing compound. The dye according to the present embodiments is applied to a light absorption layer to improve photovoltaic efficiency and increase an open-circuit voltage.