Flame-retarded foamable styrene-based resin beads and a process for producing the resin beads are provided in which a combination of two organic bromine-containing compounds is used in order to accomplish a high flame retardancy level with a small amount of addition and decreased level of residual monomer. The flame-retarded foamable resin beads comprises a blowing agent added to resin beads by impregnating with the blowing agent during or after polymerization. The beads are produced by suspension polymerizing a monomer composition containing 0.5 to 5.0 parts by weight per 100 parts by weight of the monomer of a bromine-containing flame retardant comprising (a) an organic bromine-containing compound having 2,3-dibromo-2-alkylpropyl group and (b) an organic bromine-containing compound having a bromine content greater than 50 wt% and free of any bromine atom attached to a tertiary carbon atom.
本发明提供了阻燃型可发泡
苯乙烯基
树脂珠和生产该
树脂珠的工艺,其中使用了两种有机含
溴化合物的组合,以便以少量添加和降低残留单体
水平的方式实现高阻燃性。阻燃发泡
树脂珠包括在聚合过程中或聚合后通过浸渍发泡剂添加到
树脂珠中的发泡剂。这种
树脂珠是通过悬浮聚合单体组合物生产的,每 100 份单体中含有 0.5 至 5.0 份(按重量计)含
溴阻燃剂,该单体组合物包括(a)具有 2,3-二
溴-2-烷基丙基的含
溴有机化合物和(b)
溴含量大于 50 wt%且不含任何连接到叔碳原子上的
溴原子的含
溴有机化合物。