There is provided an aqueous resin composition excellent in settability, flexibility, retort resistance, hygienicity, sprayability and dispersibility in water, and used to coat an internal surface of a can. The aqueous resin composition contains: polyester resin having a specific structure in a molecular chain thereof and/or at a terminal of the molecular chain, the polyester resin having added thereto an opened ring of a compound having a molecule with a carboxylic anhydride group therein, at least no less than 10% by mole of the compound being a compound having a molecule with no less than two carboxylic anhydride groups, the polyester resin having a resin acid value of 150 to 800 eq/106g and a number-average molecular weight of 5,000 to 100,000; resol-type phenol resin corresponding to a copolymer of a formaldehyde and a phenol compound containing no less than 50% by weight of a phenol compound having no less than three reactive point with formaldehyde, the resol-type phenol resin having no less than one alkoxy methyl group on average per aromatic nucleus; a basic compound; and water, or water and an organic solvent.
本发明提供了一种
水性
树脂组合物,该
树脂组合物在沉降性、柔韧性、耐蒸煮性、卫生 性、可喷涂性和在
水中的分散性方面都非常出色,可用于罐头内表面的涂层。这种
水性
树脂组合物含有在其分子链和/或分子链末端具有特定结构的聚酯
树脂,该聚酯
树脂中加入了具有羧 酸酐基团的分子的化合物的开环,至少不少于 10%(以分子计)的化合物是具有不少 于两个
羧酸酐基团的分子的化合物,该聚酯
树脂的
树脂酸值为 150 至 800 eq/106g, 平均分子量为 5,000 至 100,000;溶胶型
酚醛
树脂,相当于
甲醛和
酚化合物的共聚物,其中含有不少于 50%(按重量计)与
甲醛有不少于三个反应点的
酚化合物,溶胶型
酚醛
树脂的每个芳香核平均具有不少于一个烷氧基甲基;碱性化合物;以及
水或
水和有机溶剂。