申请人:Halasa Farhan Adel
公开号:US20050131181A1
公开(公告)日:2005-06-16
This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of
wherein R and R′ can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula
wherein R and R′ can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.
本发明揭示了一种合成胺官能化单体的过程,其中包括(1)将二级胺与2,3-二卤代丙烯反应,以产生含有乙烯卤代基的二级胺,其结构式选自以下组中的一种:其中R和R'可以相同或不同,代表含有1至约10个碳原子的烯丙基,烷氧基或烷基基团,X代表卤素原子,m代表4至约10的整数,X代表卤素原子;以及(2)将含有乙烯卤代基的二级胺与乙烯基镁卤反应,以产生具有结构式的单体:其中R和R'可以相同或不同,代表含有1至约10个碳原子的烷基,烯丙基或烷氧基基团,m代表约4至约10的整数。