Cyclodocecylmethacrylamide | 13675-35-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cyclodocecylmethacrylamide
• 英文别名: N-Cyclododecylmethacrylamide；N-cyclododecyl-2-methylprop-2-enamide
• CAS: 13675-35-9
• 化学式: C₁₆H₂₉NO
• 分子量: 251.412
• InChiKey: KCSKCZXFHXRTAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  环十二胺 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 苯 为溶剂， 反应 12.0h， 以55.2%的产率得到Cyclodocecylmethacrylamide
  参考文献：
  名称：

  Photoinduced charge separation by chromophores encapsulated in the hydrophobic compartment of amphiphilic polyelectrolytes with various aliphatic hydrocarbons

  摘要：

  Terpolymers of 50 mol % sodium 2-(acrylamido)-2-methylpropanesulfonate (AMPS), 1 mol % 1-(pyrenylmethyl)methacrylamide (PyMAm), and 49 mol % lauryl- or cyclododecyl- or adamantylmethacrylamide units were synthesized. A copolymer of 99 mol % AMPS and 1 mol % PyMAm units was also prepared as a reference polymer. Charge-transfer (CT) complexation, fluorescence quenching, and photoinduced electron transfer (ET) were studied, using methylviologen (MV2+) as an acceptor. In the terpolymers, the polymer-bound pyrene (Py) chromophores are compartmentalized in hydrophobic microdomains of a micellelike microphase structure formed by the terpolymers in aqueous solution, while the chromophores are exposed to the aqueous phase in the reference copolymer. In the compartmentalized systems, the CT complexation of Py with MV2+ was suppressed, but the fluorescence quenching was enhanced. Charge recombination (CR) of the primary ion pair generated by laser excitation was slowed by an order of magnitude as compared to that in the reference copolymer system, while very fast photoinduced forward ET occurred (within ca. 20 ps). Thus, the terpolymer systems showed charge separation that persisted for hundreds of microseconds. These findings were qualitatively interpreted in terms of sterical protection of the Py chromophore from a close contact with MV2+, although MV2+ is highly concentrated on the surface of the hydrophobic microdomain of the terpolymers. A sterically hindered primary ion pair of a looser structure with a longer lifetime may be formed in the compartmentalized systems. The lauryl group was significantly less effective in protecting Py than were the cyclododecyl and adamantyl groups. A judicious choice of the hydrophobic group is suggested to achieve an optimal compartmentalization of Py, which will lead to an optimal efficiency for charge separation.

  DOI：

  10.1021/j100168a058

文献信息

• GRAFT COPOLYMER, METHOD FOR PRODUCING SAME AND RESIN COMPOSITION CONTAINING SUCH GRAFT COPOLYMER
  申请人：Kaneka Corporation

  公开号：EP1832613B9

  公开（公告）日：2012-08-29
• Graft Copolymer, Method For Producing The Same And Resin Composition Containing The Graft Copolymer
  申请人：Saegusa Kazunori

  公开号：US20080085975A1

  公开（公告）日：2008-04-10

  The present invention provides a novel graft copolymer and a resin composition that is excellent in the balance between flame retardancy and impact strength. Specifically, the present invention provides a polyorganosiloxane-containing graft copolymer comprising a polyorganosiloxane (A) segment, a polymer (C) segment having at least a unit derived from a nitrogen-atom-containing multifunctional monomer (B) having two or more radically polymerizable groups in its molecule, and a polymer (E) segment derived from an ethylenically unsaturated monomer (D) that has a glass transition temperature of 40° C. or higher, and a resin composition containing the graft copolymer.
• Photoinduced charge separation by chromophores encapsulated in the hydrophobic compartment of amphiphilic polyelectrolytes with various aliphatic hydrocarbons
  作者：Yotaro Morishima、Yukio Tominaga、Mikiharu Kamachi、Tadashi Okada、Yoshinori Hirata、Noboru Mataga

  DOI：10.1021/j100168a058

  日期：1991.7

  Terpolymers of 50 mol % sodium 2-(acrylamido)-2-methylpropanesulfonate (AMPS), 1 mol % 1-(pyrenylmethyl)methacrylamide (PyMAm), and 49 mol % lauryl- or cyclododecyl- or adamantylmethacrylamide units were synthesized. A copolymer of 99 mol % AMPS and 1 mol % PyMAm units was also prepared as a reference polymer. Charge-transfer (CT) complexation, fluorescence quenching, and photoinduced electron transfer (ET) were studied, using methylviologen (MV2+) as an acceptor. In the terpolymers, the polymer-bound pyrene (Py) chromophores are compartmentalized in hydrophobic microdomains of a micellelike microphase structure formed by the terpolymers in aqueous solution, while the chromophores are exposed to the aqueous phase in the reference copolymer. In the compartmentalized systems, the CT complexation of Py with MV2+ was suppressed, but the fluorescence quenching was enhanced. Charge recombination (CR) of the primary ion pair generated by laser excitation was slowed by an order of magnitude as compared to that in the reference copolymer system, while very fast photoinduced forward ET occurred (within ca. 20 ps). Thus, the terpolymer systems showed charge separation that persisted for hundreds of microseconds. These findings were qualitatively interpreted in terms of sterical protection of the Py chromophore from a close contact with MV2+, although MV2+ is highly concentrated on the surface of the hydrophobic microdomain of the terpolymers. A sterically hindered primary ion pair of a looser structure with a longer lifetime may be formed in the compartmentalized systems. The lauryl group was significantly less effective in protecting Py than were the cyclododecyl and adamantyl groups. A judicious choice of the hydrophobic group is suggested to achieve an optimal compartmentalization of Py, which will lead to an optimal efficiency for charge separation.