Allylcyclopentadien-Maleinsaeureanhydrid-Addukt | 91963-33-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Allylcyclopentadien-Maleinsaeureanhydrid-Addukt
• 英文别名: 1-allyl-norborn-5-ene-2,3-dicarboxylic acid anhydride；allylbicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic anhydride；allyl-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid anhydride；Allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride；1-prop-2-enyl-4-oxatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• CAS: 91963-33-6
• 化学式: C₁₂H₁₂O₃
• 分子量: 204.225
• InChiKey: PSOVZHUHEHOEMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Allylcyclopentadien-Maleinsaeureanhydrid-Addukt 、 1,12-二氨基十二烷 生成 N,N'-Dodecamethylene-bis-(allyl-bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid imide)
  参考文献：
  名称：

  Allyl or methallyl-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid imides

  摘要：

  式子I中的亚烯基或甲基亚烯基E，当n为1时，R是氢、烷基、烯基、环烷基、芳基或苄基，当n为2时，R是烷基或芳基。这些中间体可用于制备具有优异物理性能的交联聚合物。该聚合物可以用于制备玻璃纤维增强和碳纤维增强塑料以及电绝缘材料。

  公开号：

  US04515962A1

文献信息

• Crosslinked polymers prepared from allyl or
  申请人：Ciba-Geigy Corporation

  公开号：US04667003A1

  公开（公告）日：1987-05-19

  Crosslinked polymers with excellent physical properties are prepared by heating at 180.degree.-300.degree. C. the imides of the formula I ##STR1## in which E is allyl or methallyl, R is hydrogen, alkyl, alkenyl, cycloalkyl, aryl or benzyl when n is 1, and R is alkylene or arylene when n is 2. The polymers can be used, in particular, for the preparation of glass fiber-reinforced and carbon fibre-reinforced plastics and as electrical insulating materials.

  通过在180℃-300℃下加热式I的酰亚胺，其中E为烯丙基或甲烯丙基，当n为1时，R为氢、烷基、烯基、环烷基、芳基或苄基，当n为2时，R为烷基或芳基，制备出具有优异物理性能的交联聚合物。这些聚合物特别适用于制备玻璃纤维增强和碳纤维增强塑料以及电绝缘材料。
• Substituted unsaturated, sulfonyloxy group-containing bicyclic imides as
  申请人：Ciba-Geigy Corporation

  公开号：US04709047A1

  公开（公告）日：1987-11-24

  Imides of formula I ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen or methyl, R.sup.3 is a direct bond, alkylene, oxaalkylene, cycloalkylene, arylene or arylene-T-arylene where T is methylene or isopropylidene, and R.sup.4 alkyl, cycloalkyl, aryl, benzyl or alkaryl are suitable as catalysts for the crosslinking of specific unsaturated imides.

  公式I的亚醰酸酯中，其中R.sup.1 和R.sup.2 分别是氢或甲基，R.sup.3 是直接键，烷基，氧代烷基，环烷基，芳基或芳基-T-芳基，其中T 是亚甲基或异丙基，R.sup.4 是烷基，环烷基，芳基，苄基或烷基芳基，适用于特定不饱和亚醰酸酯的交联催化剂。
• Substituted, unsaturated, bicyclic imides containing hydroxyl groups,
  申请人：Ciba-Geigy Corporation

  公开号：US04728742A1

  公开（公告）日：1988-03-01

  Imides of the formula I ##STR1## wherein R.sup.1, R.sub.2, R.sup.3 and n have the meanings defined in claim 1, are intermediates for producing polymers having excellent physical properties, and for producing sulfonic acid esters.

  公式I中，R.sup.1，R.sub.2，R.sup.3和n的含义如权利要求1所定义，是生产具有优异物理特性的聚合物和磺酸酯的中间体。
• Alkenyl-substituted bisnadimides, process for manufacturing the same,
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：US05663257A1

  公开（公告）日：1997-09-02

  An alkenyl-substituted bisnadimide represented by the following formula [1]: ##STR1## [wherein R.sup.1 and R.sup.2 individually represent a hydrogen atom or a methyl group, and E is an alkylene.multidot.phenylene group or an alkylene.multidot.phenylene.multidot.alkylene group represented by the following formula [2]: ##STR2## (wherein a is an integer of 0 or 1, and R.sup.3 and R.sup.3' individually represent a C.sub.1 -C.sub.4 alkylene group or a C.sub.5 -C.sub.8 cycloalkylene group)], a process for the preparation of the same and a process for curing the same are disclosed. Further, an adhesive material and a coating material containing the bisnadimide as a curing component are also disclosed. A cured material obtaind from the bisnadimide has excellent heat resistance, mechanical strength, toughness, adhesion property to many kinds of substrates, and so on. The adhesive material shows excellent heat resistance and the coating material shows excellent boiling water resistance.

  以下是一种以烯基取代的双腈酰胺化合物，其化学式为[1]： ##STR1## [其中R.sup.1和R.sup.2分别表示氢原子或甲基基团，E表示由以下化学式[2]表示的烷基.苯基基团或烷基.苯基.烷基基团： ##STR2## （其中a为0或1的整数，R.sup.3和R.sup.3'分别表示C.sub.1-C.sub.4烷基或C.sub.5-C.sub.8环烷基）]，公开了其制备方法和固化方法。此外，还公开了含有双腈酰胺化合物作为固化组分的粘合材料和涂料材料。由双腈酰胺化合物制得的固化材料具有优异的耐热性、机械强度、韧性、对许多基材的粘附性等性能。粘合材料具有优异的耐热性，涂料材料具有优异的耐沸水性。
• Curable mixtures containing an epoxide resin, an imide and a curing
  申请人：Ciba-Geigy Corporation

  公开号：US04579916A1

  公开（公告）日：1986-04-01

  Heat-curable mixtures, containing (a) an epoxide resin having on average more than one epoxide group in the molecule, (b) an allyl-substituted or methallyl-substituted imide of the formula I ##STR1## in which E is allyl or methallyl, G is hydrogen or methyl, n is 1 or 2, and R is hydrogen, alkyl, alkenyl, cycloalkyl, aryl, benzyl or arylene, and (c) a curing catalyst, have good storage stability and processability and produce moulded materials having high mechanical strength values and good resistance to heat.

  热固性混合物包含（a）分子中平均含有多于一个环氧基团的环氧树脂，（b）式I的烯丙基取代或甲烯基取代的酰亚胺，其中E是烯丙基或甲烯基，G是氢或甲基，n是1或2，R是氢，烷基，烯基，环烷基，芳基，苄基或芳烃基，（c）固化催化剂，具有良好的储存稳定性和可加工性，并产生具有高机械强度值和良好耐热性的模压材料。