3-(6-(2-tetrahydropyranyloxy)hexyl)thiophene | 160757-93-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: 3-(6-(2-tetrahydropyranyloxy)hexyl)thiophene
• 英文别名: 3-[6-(tetrahydropyranyloxy)hexyl]thiophene；2-{[6-(Thiophen-3-YL)hexyl]oxy}oxane；2-(6-thiophen-3-ylhexoxy)oxane
• CAS: 160757-93-7
• 化学式: C₁₅H₂₄O₂S
• 分子量: 268.42
• InChiKey: ZXLIITNXVRWITA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  46.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(6-(2-tetrahydropyranyloxy)hexyl)thiophene 在 盐酸 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以85%的产率得到3-(6-hydroxyhexyl)-thiophene
  参考文献：
  名称：

  Blanchetiere, D.; Noyere, C.; Catel, J., Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 91, # 1-4, p. 93 - 102

  摘要：

  DOI：
• 作为产物：
  描述：

  3-溴噻吩 、 magnesium,2-hexoxyoxane,chloride 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 作用下， 以 四氢呋喃 为溶剂， 以48%的产率得到3-(6-(2-tetrahydropyranyloxy)hexyl)thiophene
  参考文献：
  名称：

  Blanchetiere, D.; Noyere, C.; Catel, J., Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 91, # 1-4, p. 93 - 102

  摘要：

  DOI：

文献信息

• Incorporation of π-Conjugated Polymer into Silica:  Preparation of Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]/Silica and Poly(3-hexylthiophene)/Silica Composites
  作者：Masataka Kubo、Chiharu Takimoto、Yuya Minami、Takahiro Uno、Takahito Itoh、Masashi Shoyama

  DOI：10.1021/ma0508956

  日期：2005.8.1

  )hexyl)thiophene and subsequent cleavage of a tetrahydropyranyl group. Acid-catalyzed polycondensations of tetraethoxysilane (TEOS) were carried out in the presence of these polymers to give homogeneous composites with silica. The resulting composite materials were characterized by UV−vis and emission spectra.

  进行2-甲氧基-5-（2-乙基己氧基）-对苯二甲撑双（三苯基氯化chloride）与2-甲氧基-5-（2-乙基己氧基）苯-1,4-二甲醛的维蒂希反应，得到聚[2 -甲氧基-5-（2-乙基己氧基）-1,4-亚苯基亚乙烯基]（MEH-PPV）在链端用terminated部分终止。聚[3- hexylthiophene-共-3-（6-羟基己基）噻吩] 01用2-溴-3-己基噻吩和2-溴-3-（6-（2-四氢吡喃氧基）己基）区域选择性偶联反应制备噻吩然后切割四氢吡喃基。在这些聚合物的存在下，进行四乙氧基硅烷（TEOS）的酸催化缩聚反应，得到具有二氧化硅的均质复合材料。所得的复合材料通过紫外可见光谱和发射光谱进行表征。
• Conductive organic thin film, process for producing the same, electronic device employing the same, electrical cable, electrode, pyrrolyl compound, and theienyl compound
  申请人：——

  公开号：US20040109954A1

  公开（公告）日：2004-06-10

  It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (&rgr;) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×10 5 S/cm, and preferably at least 1×10 7 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

  本发明旨在提供一种导电有机薄膜，其有机分子包括末端配位基共价键结合到基板表面的一端，位于有机分子的任意部分并与其他分子聚合的共轭键合基，以及不包含活性氢且位于末端配位基和共轭键合基之间的极性功能基，其中有机分子被定向并且它们的共轭键合基被聚合，形成导电网络。该导电有机薄膜在室温（25℃）下的电导率（σ）至少为5.5×105S/cm，最好至少为1×107S/cm，不含掺杂剂，具有比黄金和银等金属更高的电导率。特别是，通过电解氧化聚合聚合的聚吡咯或聚噻吩共轭键合基的薄膜具有高导电性。
• Organic electronic device and its manufacturing method
  申请人：Yamamoto Shinichi

  公开号：US20050145839A1

  公开（公告）日：2005-07-07

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、形成在基板上的至少两个电极、形成在基板上并电性连接电极的导电有机薄膜以及用于涂覆电极至少一部分的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。
• Organic electronic device and method for manufacturing the same
  申请人：Yamamoto Shinichi

  公开号：US20070085076A1

  公开（公告）日：2007-04-19

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、至少两个形成在基板上的电极、形成在基板上并电性连接电极的导电有机薄膜，以及用于涂覆至少一部分电极的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。
• Conductive organic thin film, method for manufacturing the same, and electronic device, electric cable, electrode, pyrrolyl compound, and thienyl compound using the same
  申请人：Ogawa Kazufumi

  公开号：US20060257588A1

  公开（公告）日：2006-11-16

  It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×10 5 S/cm, and preferably at least 1×10 7 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

  本发明旨在提供一种导电有机薄膜，其中有机分子包括一个端部结合基，该基与基板表面共价结合，一个共轭结合基，该基位于有机分子的任何部分并与其他分子聚合，以及一个不包括活性氢的极性功能基，该基位于端部结合基和共轭结合基之间的任何部分，有机分子定向并且它们的共轭结合基聚合形成导电网络。该导电有机薄膜在室温（25°C）下的电导率（ρ）至少为5.5×105S/cm，最好至少为1×107S/cm，不需要掺杂剂，具有比金和银等金属更高的电导率。特别是，通过电解氧化聚合形成的聚吡咯或聚噻吩共轭键薄膜具有高导电性。