6-(diphenylamino)naphthalen-2-yl trifluoromethanesulfonate | 1264757-13-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 6-(diphenylamino)naphthalen-2-yl trifluoromethanesulfonate
• 英文别名: [6-(N-phenylanilino)naphthalen-2-yl] trifluoromethanesulfonate
• CAS: 1264757-13-2
• 化学式: C₂₃H₁₆F₃NO₃S
• 分子量: 443.446
• InChiKey: UKSRVFPLMKOEDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  55
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  6-(diphenylamino)naphthalen-2-yl trifluoromethanesulfonate 在 吡啶 、 4-二甲氨基吡啶 、 一氧化碳 、 palladium diacetate 、 三溴化硼 、 三苯基膦 、 platinum(II) chloride 、 sodium hydroxide 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 28.5h， 生成 8-(diphenylamino)-11-methylchrysen-2-yl trifluoromethanesulfonate
  参考文献：
  名称：

  Ph₂N-Susbtituted Ethylene-Bridged p-Phenylene Oligomers: Synthesis and Photophysical and Redox Properties

  摘要：

  For a series of p-phenylene-based oligomers terminated with two triphenylamines, their absorption, photoluminescence, and band gaps show a pattern of extensive pi-conjugation with increasing array size. Oligomers with large central arrays have greater quantum yields than their small analogues. Cyclic voltammetric (CV) measurements indicated two-step oxidations of the two diphenylamino groups for compounds 1-5 and one-step oxidations for the two amines of large oligomers 6 and 7.

  DOI：

  10.1021/jo1020163
• 作为产物：
  描述：

  二苯胺 、 三氟甲烷磺酸-6-溴-2-萘酯 在 三叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 1.58h， 以93%的产率得到6-(diphenylamino)naphthalen-2-yl trifluoromethanesulfonate
  参考文献：
  名称：

  Ph₂N-Susbtituted Ethylene-Bridged p-Phenylene Oligomers: Synthesis and Photophysical and Redox Properties

  摘要：

  For a series of p-phenylene-based oligomers terminated with two triphenylamines, their absorption, photoluminescence, and band gaps show a pattern of extensive pi-conjugation with increasing array size. Oligomers with large central arrays have greater quantum yields than their small analogues. Cyclic voltammetric (CV) measurements indicated two-step oxidations of the two diphenylamino groups for compounds 1-5 and one-step oxidations for the two amines of large oligomers 6 and 7.

  DOI：

  10.1021/jo1020163

文献信息

• ELECTROLUMINESCENT DEVICES HAVING PENDANT NAPHTHYLANTHRACENE-BASED POLYMERS
  申请人：Zheng Shiying

  公开号：US20070187673A1

  公开（公告）日：2007-08-16

  A naphthylanthracene-based polymer comprising a repeating unit of the formula wherein: Ar is an aryl or substituted aryl of from 6 to 60 carbon atoms; or a heteroaryl or substituted heteroaryl of from 4 to 60 carbon atoms; R 1 , R 2 , and R 3 are the same or different, and are each individually hydrogen, or alkyl, or alkenyl, or alkynyl, or alkoxy, or amino, or thioalkyl, or carboxyl, or carbonyl, wherein the alkyl, alkenyl, alkynyl, alkoxy, amino, thioalkyl, carboxy, or carbonyl can have from 1 to 40 carbon atoms; or aryl of from 6 to 60 carbon atoms; or heteroaryl of from 4 to 60 carbon atoms; or F, or Cl , or Br; or a cyano group; or a nitro group, or a sulfonate group; and L is a direct bond between naphthylanthracene and polymer backbone or a carbon linking group having 1 to 40 carbon atoms or a non-carbon linking group.

  一种基于萘并蒽的聚合物，包括如下重复单元，其中：Ar是含6至60个碳原子的芳基或取代芳基；或含4至60个碳原子的杂芳基或取代杂芳基；R1、R2和R3相同或不同，分别为氢、烷基、烯基、炔基、烷氧基、氨基、硫代烷基、羧基、酰基，其中烷基、烯基、炔基、烷氧基、氨基、硫代烷基、羧基或酰基可含有1至40个碳原子；或含6至60个碳原子的芳基；或含4至60个碳原子的杂芳基；或F、Cl、Br；或氰基；或硝基；或磺酸盐基；L是萘并蒽与聚合物骨架之间的直接键合或含有1至40个碳原子或非碳原子键合基。
• US7267892B2
  申请人：——

  公开号：US7267892B2

  公开（公告）日：2007-09-11
• Ph₂N-Susbtituted Ethylene-Bridged <i>p</i>-Phenylene Oligomers: Synthesis and Photophysical and Redox Properties
  作者：Balagopal Shainamma Shaibu、Sheng-Hsun Lin、Chi-Yen Lin、Ken-Tsung Wong、Rai-Shung Liu

  DOI：10.1021/jo1020163

  日期：2011.2.18

  For a series of p-phenylene-based oligomers terminated with two triphenylamines, their absorption, photoluminescence, and band gaps show a pattern of extensive pi-conjugation with increasing array size. Oligomers with large central arrays have greater quantum yields than their small analogues. Cyclic voltammetric (CV) measurements indicated two-step oxidations of the two diphenylamino groups for compounds 1-5 and one-step oxidations for the two amines of large oligomers 6 and 7.