3-vinyloxy-propane-1,2-diol | 136917-94-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 3-vinyloxy-propane-1,2-diol
• 英文别名: Glycerin-1-vinylaether；3-Vinyloxy-propan-1,2-diol；3-(Ethenyloxy)propane-1,2-diol；3-ethenoxypropane-1,2-diol
• CAS: 136917-94-7
• 化学式: C₅H₁₀O₃
• 分子量: 118.133
• InChiKey: LANDRZNMJOEVQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-vinyloxy-propane-1,2-diol 生成 alkaline earth salt of/the/ methylsulfuric acid 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Schostakowski; Gratschewa, Zhurnal Obshchei Khimii, 1949, vol. 19, p. 1253,1254

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(乙烯氧基甲基)环氧乙烷 在 水 、 silica gel 、 iron(III) perchlorate 作用下， 以 丙酮 为溶剂， 生成 3-vinyloxy-propane-1,2-diol
  参考文献：
  名称：

  硅胶上的高氯酸铁为多用途试剂，用于催化环氧，醇和酯中碳-氧键的闭合和断裂

  摘要：

  Aliphatic alcohols and water in the presence of catalytic amounts of Fe3+ ion introduced as iron(Ill) perchlorate on silica gel carrier perform efficient regiospecific opening of an epoxy ring. Carbon acids esterification with various type alcohols was carried out using the system Fe(ClO4)(3)-silica gel in dichloromethane under conditions excluding solvolysis. Acetylation and formylation of alcohols was performed by efficient transesterification with ethyl acetate and ethyl formate.

  DOI：

  10.1023/b:rujo.0000003154.92028.84

文献信息

• Faworski; Schostakowski, Zhurnal Obshchei Khimii, 1943, vol. 13, p. 15
  作者：Faworski、Schostakowski

  DOI：——

  日期：——
• Schostakowski; Gratschewa, Zhurnal Obshchei Khimii, 1949, vol. 1, p. 1252
  作者：Schostakowski、Gratschewa

  DOI：——

  日期：——
• Iron Perchlorate on Silica Gel as Multi-purpose Reagent for Catalysis of Closure and Rupture of Carbon-Oxygen Bond in Epoxides, Alcohols, and Esters
  作者：P. Salechi、M. M. Khodaei、S. B. Ghareghani、A. R. Motlagh

  DOI：10.1023/b:rujo.0000003154.92028.84

  日期：2003.6

  Aliphatic alcohols and water in the presence of catalytic amounts of Fe3+ ion introduced as iron(Ill) perchlorate on silica gel carrier perform efficient regiospecific opening of an epoxy ring. Carbon acids esterification with various type alcohols was carried out using the system Fe(ClO4)(3)-silica gel in dichloromethane under conditions excluding solvolysis. Acetylation and formylation of alcohols was performed by efficient transesterification with ethyl acetate and ethyl formate.
• Schostakowski; Gratschewa, Zhurnal Obshchei Khimii, 1949, vol. 19, p. 1253,1254
  作者：Schostakowski、Gratschewa

  DOI：——

  日期：——