6-(Diethylamino)-2-methylhex-2-enamide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 6-(Diethylamino)-2-methylhex-2-enamide
• 英文别名: 6-(diethylamino)-2-methylhex-2-enamide
• 化学式: C₁₁H₂₂N₂O
• 分子量: 198.31
• InChiKey: ALXUOLQRSSGTMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  46.3
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Use of polymeric reaction product
  申请人：——

  公开号：US20030170306A1

  公开（公告）日：2003-09-11

  A reaction product (A) which can be prepared by reaction, under free radical conditions, of at least one monomer (a) capable of free radical reaction, in the presence of at least one free radical initiator and of a radical of the formula (III) 1 where R 1 to R 3 , in each case independently of one another, are hydrogen, methyl or a radical-stabilizing and/or bulky group selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, cycloalkyl, alcohol, ether, polyether, amine, aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another in each case, are defined in the same way as R 1 to R 5 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and, if required, may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 3 are a radical-stabilizing and/or bulky group as defined above, has various uses.

  一种反应产物(A)，可以通过在自由基条件下，至少一种能够自由基反应的单体(a)在至少一种自由基引发剂和式(III)1的自由基存在下反应制备而成。其中，R1到R3分别独立地为氢、甲基或从未取代或取代的线性或支链烷基、环烷基、醇、醚、聚醚、胺、芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、从未取代或取代的线性或支链烯基或炔基、-C（O）R5、-C（O）OR5、-CR5R6-O-R7、-O-C（O）R5、-CN、-O-CN、-S-CN、-O-C═NR5、-S-C═NR5、-O-CR5R6-CR7R8NR9R10、-N═C═O、-C═NR5、-CR5R6-Hal、-C（S）R5、-CR5R6-P（O）R7R8、-CR5R6-PR7R8、-CR5R6-NR7R8、-CR5R6（OR7）（OR8）、-CR5R6（OR7）（NR8）、-CR5R6（NR7）（NR8）、酸酐、缩醛或缩酮基、-SO2R5、氨基甲酸酰基、-NR5C（S）NR6、-NR5C（S）-OR6、-N═C═S、-NO2、-C═N-OH、-N（R5）═NR6、-PR5R6R7、-OSiR5R6R7或-SiR5R6R7，其中，R5到R10在每种情况下独立地定义为R1到R5相同的方式，或者R1到R4中的两个基团形成一个C4到C7环，该环本身可以是取代或未取代的，并且如有必要，可以含有一个或多个杂原子，但至少两个基团R1到R3是上述定义的稳定/笨重基团之一。该产物具有多种用途。
• Method for the production of a polymerisation reaction product
  申请人：——

  公开号：US20040034182A1

  公开（公告）日：2004-02-19

  A process for the preparation of a reaction product (A) comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction, in the presence of at least one compound of the formula (I) 1 where R 1 to R 4 , independently of one another, are each hydrogen, methyl or a group which stabilizes radicals and/or is bulky and which is selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, a cycloalkyl, alcohol, ether, polyether, amine or aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another, are each defined in the same way as R 1 to R 4 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 4 are a group which stabilizes radicals and/or is bulky, as defined above, and diphenylethylene, dinaphthylethylene, 4,4′-vinylidenebis(N,N′-dimethylaniline), 4,4′-vinylidenebis(aminobenzene), cis- and trans-stilbene and mixtures of two or more thereof are excluded as compounds of the formula (I), and a process for the preparation of a reaction product (A′) comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction, in the presence of at least one compound of the formula (II) 2 where R 1 to R 4 and R 11 and R 12 , independently of one another, are each hydrogen, methyl or a group which stabilizes radicals and/or is bulky and which is selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, a cycloalkyl, alcohol, ether, polyether, amine or aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another, are each defined in the same way as R 1 to R 4 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 4 are a group which stabilizes radicals and/or is bulky, as defined above.

  一种制备反应产物（A）的方法包括以下步骤（i）：（i）在自由基条件下，反应混合物至少包括一种自由基反应的单体（a），在至少一种化合物（I）1的存在下反应，其中R1至R4独立地是氢、甲基或稳定自由基和/或是笨重的基团，选择自未取代或取代的、线性或支链的含有两个或更多碳原子的烷基、环烷基、醇、醚、聚醚、胺或芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、取代或未取代的、线性或支链的烯基或炔基、—C（O）R5、—C（O）OR5、—CR5R6—O—R7、—O—C（O）R5、—CN、—O—CN、—S—CN、—O—C═NR5、—S—C═NR5、—O—CR5R6—CR7R8NR9R10、—N═C═O、—C═NR5、—CR5R6-Hal、—C（S）R5、—CR5R6—P（O）R7R8、—CR5R6—PR7R8、—CR5R6—NR7R8、—CR5R6（OR7）（OR8）、—CR5R6（OR7）（NR8）、—CR5R6（NR7）（NR8）、酐、缩醛或缩酮基团、—SO2R5、酰胺基团、—NR5C（S）NR6、—NR5C（S）—OR6、—N═C═S、—NO2、—C═N—OH、—N（R5）═NR6、—PR5R6R7、—OSiR5R6R7或—SiR5R6R7，其中R5至R10独立地与R1至R4的定义相同，或者R1至R4中的两个基团形成一个C4-C7环，该环可以被取代或未取代，并且可能含有一个或多个杂原子，但需注意至少有两个基团R1至R4是稳定自由基和/或笨重的基团，如上所定义，而联苯乙烯、二萘乙烯、4,4′-乙烯基双（N,N′-二甲基苯胺）、4,4′-乙烯基双（氨基苯）和顺式和反式的蒽烯及其混合物被排除在化合物（I）的定义之外，以及一种制备反应产物（A′）的方法包括以下步骤（i）：（i）在自由基条件下，反应混合物至少包括一种自由基反应的单体（a），在至少一种化合物（II）2的存在下反应，其中R1至R4和R11和R12独立地是氢、甲基或稳定自由基和/或是笨重的基团，选择自未取代或取代的、线性或支链的含有两个或更多碳原子的烷基、环烷基、醇、醚、聚醚、胺或芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、取代或未取代的、线性或支链的烯基或炔基、—C（O）R5、—C（O）OR5、—CR5R6—O—R7、—O—C（O）R5、—CN、—O—CN、—S—CN、—O—C═NR5、—S—C═NR5、—O—CR5R6—CR7R8NR9R10、—N═C═O、—C═NR5、—CR5R6-Hal、—C（S）R5、—CR5R6—P（O）R7R8、—CR5R6—PR7R8、—CR5R6—NR7R8、—CR5R6（OR7）（OR8）、—CR5R6（OR7）（NR8）、—CR5R6（NR7）（NR8）、酐、缩醛或缩酮基团、—SO2R5、酰胺基团、—NR5C（S）NR6、—NR5C（S）—OR6、—N═C═S、— 、—C═N—OH、—N（R5）═NR6、—PR5R6R7、—OSiR5R6R7或—SiR5R6R7，其中R5至R10独立地与R1至R4的定义相同，或者R1至R4中的两个基团形成一个C4-C7环，该环可以被取代或未取代，并且可能含有一个或多个杂原子，但需注意至少有两个基团R1至R4是稳定自由基和/或笨重的基团，如上所定义。
• Shade enhancing agent
  申请人：Kao Corporation

  公开号：EP0249380A2

  公开（公告）日：1987-12-16

  A shade enhancing agent comprises an aqueous resin emulsion composition obtained by polymerizing a monomer in the presence of a cationic surfactant or a cationic protective colloid, polymerizing a monomer and adding a cationic protective colloid or polymerizing a monomer in the presence of a cationic or nonionic emulsifying dispersant so as to have a cationic group in the molecule, a dry film of said composition having a glass transition point (Tg) in the range between 20°c and 110°c and a refractive index of 1.50 or less, said emulsion composition having a zeta potential in the range between +5 and +80 mV at an ion strength of 10-3 and a pH value of 7.

  一种遮光剂包括一种水性树脂乳液组合物，该组合物通过在阳离子表面活性剂或阳离子保护胶体存在下聚合单体、聚合单体并添加阳离子保护胶体或在阳离子或非离子乳化分散剂存在下聚合单体以使分子中含有阳离子基团而获得，所述组合物的干膜的玻璃化转变点（Tg）在 20°C 至 110°C 之间，折射率为 1.50 或更低，所述乳液组合物在离子强度为 10-3 和 pH 值为 7 时的 zeta 电位在 +5 至 +80 mV 之间。
• Papermaking method
  申请人：MITSUI-CYANAMID, LTD.

  公开号：EP0385626A1

  公开（公告）日：1990-09-05

  Disclosed are a papermaking method of preparing a paper having a reinforced strength wherein a polymer latex is added to a paper stock in an amount of from 2.5 to 30 % by weight. The polymer latex is prepared by neutralizing a seed polymer with an acid or a salt or by quaternizing it with a quaternizing agent. The surfaces of the emulsion grains are highly densely cationated. The seed polymer is formed by adding a monomer as represented by the following formula (I) or a mixture of the monomer (I) and copolymerizable ethylenic unsaturated monomer(s) (II) to a seed latex of a carboxyl-modified synthetic rubber latex or synthetic resin emulsion and polymerizing them: R, represents H or CH3; R2 represents. an alkylene group having from 2 to 5 carbon atoms; R3 and R4 each represent H or an alkyl group having from 1 to 5 carbon atoms; A represents or ; and R1, R3 and R4 and so selected that the monomer is hardly soluble or insoluble in water. The paper has a noticeably improved paper-strength.

  公开了一种制备具有增强强度的纸张的造纸方法，其中在纸浆中加入聚合物胶乳，加入量为 2.5% 至 30%（按重量计）。 聚合物胶乳是通过用酸或盐中和种子聚合物或用季铵化剂对其进行季铵化来制备的。乳胶颗粒的表面阳离子高度密集。种子聚合物是通过向羧基改性合成橡胶胶乳或合成树脂乳液的种子胶乳中加入下式 （I）所代表的单体或单体（I）与可共聚的乙烯基不饱和单体（II）的混合物并使其聚合而 形成的： R 代表 H 或 CH3； R2 代表具有 2 至 5 个碳原子的亚烷基； R3和R4各自代表H或具有1至5个碳原子的烷基； A 代表 或 和 R1、R3 和 R4 的选择使单体难溶或不溶于水。 纸张强度明显提高。
• Mortar concrete composition
  申请人：MITSUI CYANAMID LIMITED

  公开号：EP0392688A1

  公开（公告）日：1990-10-17

  Disclosed is a mortar · concrete composition comprising a polymer emulsion, a portland cement material and an aggregate, which is characterized in that the polymer emulsion is one prepared by neutralizing a seed polymer with an acid or a salt or by quaternizing it with a quaternizing agent, the surfaces of the emulsion grains being thereby highly densely cationated, where the seed polymer is formed by adding a monomer as represented by the following formula (I) or a mixture of the monomer (I) and copolymerizable ethylenic unsaturated monomer(s) (II) to a seed latex of a carboxyl-modified synthetic rubber latex or synthetic resin emulsion and polymerizing them: The polymer of the invention may noticeably reinforce the strength of the shaped product even when the amount of the polymer added is small. The polymer dispersion of the invention can be applied to not only the conventional ordinary materials but also concrete construction materials, although the application to the latter has heretofore been considered economically impossible.

  本发明公开了一种由聚合物乳液、硅酸盐水泥材料和骨料组成的砂浆-混凝土组合 物，其特征在于该聚合物乳液是通过用酸或盐中和种子聚合物或用季铵化剂对其进行 季铵化而制备的，因此乳液颗粒表面具有高度致密的阳离子化、种子聚合物是通过向羧基改性合成橡胶胶乳或合成树脂乳液的种子胶乳中加入下式 （I）所代表的单体或单体（I）与可共聚的乙烯基不饱和单体（II）的混合物并使其聚合而 形成的： 本发明的聚合物即使添加量较少，也可明显增强成型产品的强度。本发明的聚合物分散体不仅可用于传统的普通材料，还可用于混凝土建筑材料，尽管迄今为止，混凝土建筑材料的应用在经济上被认为是不可能的。