苯,1,2,3,4,5,6-六氟苯 | 783-33-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯,1,2,3,4,5,6-六氟苯
• 英文名称: Benzene*Hexafluorobenzene
• 英文别名: Benzene--hexafluorobenzene (1/1)；benzene;1,2,3,4,5,6-hexafluorobenzene
• CAS: 783-33-5
• 化学式: C₆F₆*C₆H₆
• 分子量: 264.17
• InChiKey: NOJOEBYKHSSSBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.21
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  六氟苯 、 苯 生成 苯,1,2,3,4,5,6-六氟苯
  参考文献：
  名称：

  C6H6-C6F6共晶体中压力诱导的Diels-Alder反应对石墨烷结构的影响

  摘要：

  芳烃的压力诱导聚合（PIP）是构建sp 3的新方法通过压缩苯及其衍生物合成碳骨架和具有菱形结构的纳米线。通过压缩苯-六氟苯共晶体（CHCF），在PIP产品中鉴定出具有分层结构的H-F-取代石墨烷。根据由原位中子衍射确定的晶体结构和通过气相色谱-质谱鉴定的中间产物，我们发现，在20 GPa的CHCF下，倾斜的柱形成苯和六氟苯交替堆积的状态，并导致[4 + 2]聚合物，然后转变为短程有序H-F-取代的石墨烷。该反应过程涉及[4 + 2] Diels–Alder，逆Diels–Alder和1–1'偶联反应，而前者是PIP中的关键反应。

  DOI：

  10.1002/anie.201813120

文献信息

• COMPONENT FOR ROTARY MACHINE
  申请人：Konno Yuya

  公开号：US20110135946A1

  公开（公告）日：2011-06-09

  A component for a rotary machine which is configured such that a hard film composed of ceramics and an anti-fouling film composed of a fluorine-containing diamond-like carbon film are laminated on the surface of a base material, and which has superior drain erosion resistance and fouling resistance in an environment where a gas comes in direct contact therewith.
• AZEOTROPIC AND AZEOTROPE-LIKE COMPOSITIONS OF E-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE AND ETHYLENE OXIDE AND USES THEREOF
  申请人：Robin Mark L.

  公开号：US20120309824A1

  公开（公告）日：2012-12-06

  Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene and ethylene oxide. Also disclosed are double azeotropic compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and ethylene oxide. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as dielectrics. Also disclosed is a method for sterilizing an article by using such azeotropic or azeotrope-like compositions.