Methyl 1-adamantyl(bromo)acetate | 97041-95-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Methyl 1-adamantyl(bromo)acetate
• 英文别名: methyl 2-(1-adamantyl)-2-bromoacetate
• CAS: 97041-95-7
• 化学式: C₁₃H₁₉BrO₂
• 分子量: 287.197
• InChiKey: NCLJXJRYQZAGGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  methyl bromo(3-bromo-1-adamantyl)acetate 生成 Methyl 1-adamantyl(bromo)acetate
  参考文献：
  名称：

  KRASUTSKIJ, T. A.;CHESSKAYA, N. S.;RODIONOV, V. N.;BAULA, O. P.;YURCHENKO+, ZH. ORGAN. XIMII, 1985, 21, N 8, 1677-1684

  摘要：

  DOI：

文献信息

• RESIST COMPOSITION, METHOD OF FORMING RESIST PATTERN, NOVEL COMPOUND AND METHOD OF PRODUCING THE SAME, AND ACID GENERATOR
  申请人：Kawaue Akiya

  公开号：US20090068591A1

  公开（公告）日：2009-03-12

  A compound represented by formula (I); and a compound represented by formula (b1-1): wherein X represents —O—, —S—, —O—R 3 — or —S—R 4 —, wherein each of R 3 and R 4 independently represents an alkylene group of 1 to 5 carbon atoms; R 2 represents an alkyl group of 1 to 6 carbon atoms, an alkoxy group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, a halogen atom, a hydroxyalkyl group of 1 to 6 carbon atoms, a hydroxyl group or a cyano group; a represents an integer of 0 to 2; Q 1 represents an alkylene group of 1 to 12 carbon atoms or a single bond; Y 1 represents an alkylene group of 1 to 4 carbon atoms or a fluorinated alkylene group; M + represents an alkali metal ion; and A + represents an organic cation.

  化合物的化学式（I）代表的化合物；以及化学式（b1-1）代表的化合物：其中X代表—O—，—S—，—O—R3—或—S—R4—，其中R3和R4分别独立代表1至5个碳原子的烷基基团；R2代表1至6个碳原子的烷基基团，1至6个碳原子的烷氧基团，1至6个碳原子的卤代烷基团，卤原子，1至6个碳原子的羟基烷基团，羟基或氰基；a代表0至2的整数；Q1代表1至12个碳原子的烷基基团或单键；Y1代表1至4个碳原子的烷基基团或氟代烷基基团；M+代表碱金属离子；A+代表有机阳离子。
• NOVEL COMPOUND AND METHOD OF PRODUCING THE SAME, ACID GENERATOR, RESIST COMPOSITION AND METHOD OF FORMING RESIST PATTERN
  申请人：Hada Hideo

  公开号：US20090162788A1

  公开（公告）日：2009-06-25

  A resist composition including a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the acid-generator component (B) including an acid generator (B1) consisting of a compound represented by general formula (b1-1) shown below: wherein R X represents a hydrocarbon group which may have a substituent exclusive of a nitrogen atom; each of Q 2 and Q 3 independently represents a single bond or a divalent linkage group; Y 1 represents an alkylene group or fluorinated alkyl group of 1 to 4 carbon atoms; and Z + represents an organic cation exclusive of an ion represented by general formula (w-1).

  一种抗蚀组合物，包括基础组分（A），在酸作用下在碱性显影液中表现出改变的溶解度，以及酸发生组分（B），在暴露后产生酸，酸发生组分（B）包括一个由下式（b1-1）表示的化合物组成的酸发生剂（B1）：其中RX表示一个可具有除氮原子以外的取代基的碳氢基团；Q2和Q3各自独立地表示单键或双价连接基团；Y1表示1到4个碳原子的烷基或氟代烷基；Z+表示一种有机阳离子，不包括由通式（w-1）表示的离子。
• Novel compound and method of producing the same, acid generator, resist composition and method of forming resist pattern
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP2073060A1

  公开（公告）日：2009-06-24

  A resist composition including a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the acid-generator component (B) including an acid generator (B1) consisting of a compound represented by general formula (b1-1) shown below: wherein Rx represents a hydrocarbon group which may have a substituent exclusive of a nitrogen atom; each of Q2 and Q3 independently represents a single bond or a divalent linkage group; Y1 represents an alkylene group or fluorinated alkyl group of 1 to 4 carbon atoms; and Z+ represents an organic cation exclusive of an ion represented by general formula (w-1).

  一种抗蚀剂组合物，包括在酸作用下碱显影溶液中的溶解度会发生变化的碱成分（A）和在接触时会产生酸的酸生成成分（B），酸生成成分（B）包括由下图所示通式（b1-1）所代表的化合物组成的酸生成物（B1）： 其中 Rx 代表烃基，该烃基可能具有不包括氮原子的取代基；Q2 和 Q3 各自独立地代表单键或二价连接基；Y1 代表 1 至 4 个碳原子的亚烷基或氟化烷基；Z+ 代表不包括通式（w-1）所代表离子的有机阳离子。
• Krasutskii, P. A.; Chesskaya, N. S.; Rodionov, V. N., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, # 8, p. 1533 - 1539
  作者：Krasutskii, P. A.、Chesskaya, N. S.、Rodionov, V. N.、Baula, O. P.、Yurchenko, A. G.

  DOI：——

  日期：——
• KRASUTSKIJ, P. A.;CHESSKAYA, N. S.;RODIONOV, V. N., BECTH. KIEV. POLITEXN. IN-TA. XIM. MASHINOSTR. I TEXNOL., 1984, N 21, 11-+
  作者：KRASUTSKIJ, P. A.、CHESSKAYA, N. S.、RODIONOV, V. N.

  DOI：——

  日期：——