2-methacryloyloxyethyl dichloroacetate | 88029-82-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-methacryloyloxyethyl dichloroacetate
• 英文别名: 2-(2,2-Dichloroacetoxy)ethyl-2-methylacrylate；2-(2,2-dichloroacetyl)oxyethyl 2-methylprop-2-enoate
• CAS: 88029-82-7
• 化学式: C₈H₁₀Cl₂O₄
• 分子量: 241.071
• InChiKey: DANRFGPYJCEEGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-methacryloyloxyethyl dichloroacetate 、 足球烯 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 为溶剂， 反应 0.08h， 以59%的产率得到[1-((methacryloyloxy)ethyloxycarbonyl-1-chlorine)methane]-1,2-dihydro-C60-fullerene
  参考文献：
  名称：

  Synthesis of fullerene-containing methacrylates

  摘要：

  The Bingel-Hirsch reaction between fullerene C-60, and 2-methacryloyloxyethyl methyl malonate or 2-methacryloyloxyethyl dichloroacetate afforded the corresponding monocyclopropanation products.

  DOI：

  10.1016/j.mencom.2012.06.009
• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 、 二氯乙酰氯 在 吡啶 作用下， 反应 12.0h， 以75%的产率得到2-methacryloyloxyethyl dichloroacetate
  参考文献：
  名称：

  Synthesis of fullerene-containing methacrylates

  摘要：

  The Bingel-Hirsch reaction between fullerene C-60, and 2-methacryloyloxyethyl methyl malonate or 2-methacryloyloxyethyl dichloroacetate afforded the corresponding monocyclopropanation products.

  DOI：

  10.1016/j.mencom.2012.06.009

文献信息

• US4448923A
  申请人：——

  公开号：US4448923A

  公开（公告）日：1984-05-15
• US6384146B1
  申请人：——

  公开号：US6384146B1

  公开（公告）日：2002-05-07
• [EN] GRAFT, GRAFT-BLOCK, BLOCK-GRAFT, AND STAR-SHAPED COPOLYMERS AND METHODS OF MAKING THEM<br/>[FR] COPOLYMERES GREFFES, GREFFES-SEQUENCES, SEQUENCES-GREFFES ET EN ETOILE, ET LEURS TECHNIQUES DE PREPARATION
  申请人：UNIV NEW YORK STATE RES FOUND

  公开号：WO2000059968A1

  公开（公告）日：2000-10-12

  The present invention relates to a continuous method of preparing a block-graft or star-shaped copolymer. This method involves providing a living polymer, mixing the living polymer with a first monomer under conditions effective to produce a block copolymer, wherein the first monomer includes a polymerization site and a polymerization initiation site, and mixing the block copolymer with a second monomer under conditions effective to produce a block-graft or star-shaped copolymer. The present invention also relates to a continuous method of preparing a graft or graft-block copolymer. This method involves mixing a first monomer and a second monomer under conditions effective to produce a copolymer of the first and second monomers, wherein the second monomer comprises a polymerization site and a polymerization initiation site, mixing the copolymer with a third monomer under conditions effective to produce a graft copolymer, and mixing the graft copolymer with a fourth monomer under conditions effective to produce a graft-block copolymer. The present invention also relates to graft, graft-block, block-graft, and star-shaped copolymers produced by the methods of the present invention.