2,4'-dihydroxybenzyl-6,6'-methylenediphenol | 197805-65-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,4'-dihydroxybenzyl-6,6'-methylenediphenol
• 英文别名: 2-[[2-Hydroxy-3-[(4-hydroxyphenyl)methyl]phenyl]methyl]-6-[(4-hydroxyphenyl)methyl]phenol；2-[[2-hydroxy-3-[(4-hydroxyphenyl)methyl]phenyl]methyl]-6-[(4-hydroxyphenyl)methyl]phenol
• CAS: 197805-65-5
• 化学式: C₂₇H₂₄O₄
• 分子量: 412.485
• InChiKey: SHDMFLVYEIIVOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 2,4'-dihydroxybenzyl-6,6'-methylenediphenol 在 乙基溴化镁 作用下， 生成 2-[[2-Hydroxy-3-[[4-hydroxy-3-[[2-hydroxy-5-[[2-hydroxy-3-[[2-hydroxy-3-[(4-hydroxyphenyl)methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]-6-[(4-hydroxyphenyl)methyl]phenol
  参考文献：
  名称：

  The chemistry of novolac resins. Part 4. The strategic synthesis of model compounds

  摘要：

  An ion assisted ortho-specific phenol-formaldehyde condensation process, incorporating selective protecting-deprotecting methodology has been adapted to prepare a range of model novolac compounds which are ideal for studying crosslinking with hexamethylenetetramine. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00903-4
• 作为产物：
  描述：

  2-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]phenol 在 乙基溴化镁 、 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 26.5h， 生成 2,4'-dihydroxybenzyl-6,6'-methylenediphenol
  参考文献：
  名称：

  The chemistry of novolac resins. Part 4. The strategic synthesis of model compounds

  摘要：

  An ion assisted ortho-specific phenol-formaldehyde condensation process, incorporating selective protecting-deprotecting methodology has been adapted to prepare a range of model novolac compounds which are ideal for studying crosslinking with hexamethylenetetramine. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00903-4

文献信息

• COMPOSITION FOR MAGNETIC RECORDING MEDIUM AND MAGNETIC RECORDING MEDIUM
  申请人：FUJIFILM Corporation

  公开号：US20150064500A1

  公开（公告）日：2015-03-05

  An aspect of the present invention relates to a composition, which is a composition for a magnetic recording medium and comprises an isocyanate compound in the form of an adduct of a polyhydroxyl compound having one or more aromatic carbon rings and three or more hydroxyl groups per molecule with a polyisocyanate having two or more isocyanate groups per molecule.
• The chemistry of novolac resins. Part 4. The strategic synthesis of model compounds
  作者：Pauline J. de Bruyn、Linda M. Foo、Audrey S.C. Lim、Mark G. Looney、David H. Solomon

  DOI：10.1016/s0040-4020(97)00903-4

  日期：1997.10

  An ion assisted ortho-specific phenol-formaldehyde condensation process, incorporating selective protecting-deprotecting methodology has been adapted to prepare a range of model novolac compounds which are ideal for studying crosslinking with hexamethylenetetramine. (C) 1997 Elsevier Science Ltd.