6-(anthracen-9-ylethynyl)-N-(pyridin-2-yl)pyridin-2-amine | 1410168-87-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 6-(anthracen-9-ylethynyl)-N-(pyridin-2-yl)pyridin-2-amine
• 英文别名: 6-(2-anthracen-9-ylethynyl)-N-pyridin-2-ylpyridin-2-amine
• CAS: 1410168-87-4
• 化学式: C₂₆H₁₇N₃
• 分子量: 371.441
• InChiKey: HPQLVCJCPHUENF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(pyridin-2-yl)-6-[(trimethylsilyl)ethynyl]pyridin-2-amine 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 四丁基氟化铵 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 19.0h， 生成 6-(anthracen-9-ylethynyl)-N-(pyridin-2-yl)pyridin-2-amine
  参考文献：
  名称：

  Selective, sensitive and reversible “turn-on” fluorescent cyanide probes based on 2,2′-dipyridylaminoanthracene–Cu2+ ensembles

  摘要：

  通过连接 2,2â²-二吡啶基胺和蒽单元，得到了高发射性化合物，其 Cu2+ 组合被开发为有效的荧光开启 CNâ 探针。

  DOI：

  10.1039/c2cc36140j

文献信息

• NOVEL LUMINESCENT MATERIALS
  申请人：XIE Yongshu

  公开号：US20150329773A1

  公开（公告）日：2015-11-19

  The invention provides photoluminescent compounds, reactive intermediates used to synthesize photoluminescent compounds, and methods of synthesizing and using photoluminescent compounds, among others. The compounds comprise phenanthrene and dipyridylamine moieties. The compounds are colored and fluoresce upon excitation. Methods are included for using the compounds to detect metal ions by spectral changes of wavelength shift or a change in fluorescence intensity. Compositions in polymers and solvents are provided for use as a film, paint, reflective surfaces, and electroluminescent devices are provided.
• US9410081B2
  申请人：——

  公开号：US9410081B2

  公开（公告）日：2016-08-09
• [EN] NOVEL LUMINESCENT MATERIALS<br/>[FR] NOUVEAUX MATÉRIAUX LUMINESCENTS
  申请人：UNIV EAST CHINA SCIENCE & TECH

  公开号：WO2014059586A1

  公开（公告）日：2014-04-24

  The invention provides photoluminescent compounds, reactive intennediates used to synthesize photoluminescent compounds, and methods of synthesizing and using photoluminescent compounds, among others. The compounds comprise phenanthrene and dipyridylamine moieties. The compounds are colored and fluoresce upon excitation. Methods are included for using the compounds to detect metal ions by spectral changes of wavelength shift or a change in fluorescence intensity. Compositions in polymers and solvents are provided for use as a film, paint, reflective surfaces, and electroluminescent devices are provided.
• Selective, sensitive and reversible “turn-on” fluorescent cyanide probes based on 2,2′-dipyridylaminoanthracene–Cu2+ ensembles
  作者：Yongshu Xie、Yubin Ding、Xin Li、Cheng Wang、Jonathan P. Hill、Katsuhiko Ariga、Weibing Zhang、Weihong Zhu

  DOI：10.1039/c2cc36140j

  日期：——

  2,2′-Dipyridylamine and anthracene units were linked to afford highly emissive compounds whose Cu2+ ensembles were developed as effective fluorescence turn-on CN− probes.

  通过连接 2,2â²-二吡啶基胺和蒽单元，得到了高发射性化合物，其 Cu2+ 组合被开发为有效的荧光开启 CNâ 探针。