N-(phenyl(pyridin-2-yl)methylene)aniline | 30894-24-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-(phenyl(pyridin-2-yl)methylene)aniline
• 英文别名: Benzenamine, N-(phenyl-2-pyridinylmethylene)-；N,1-diphenyl-1-pyridin-2-ylmethanimine
• CAS: 30894-24-7
• 化学式: C₁₈H₁₄N₂
• 分子量: 258.323
• InChiKey: KUZJJHWMZUTJRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(phenyl(pyridin-2-yl)methylene)aniline 在 (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate 、 三乙胺 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以97%的产率得到N-(phenyl(pyridin-2-yl)methyl)aniline
  参考文献：
  名称：

  分批和连续流动的二丙胺的光催化和化学选择性转移加氢

  摘要：

  描述了用于间歇和连续流动的亚胺化学选择性转移氢化的可见光光催化方法。该反应利用Et 3 N作为氢源和单电子供体，从而能够选择性还原衍生自含有其他可还原官能团（包括腈，卤化物，酯和酮）的二芳基酮亚胺的亚胺。Et 3 N的双重作用已通过荧光猝灭测量，瞬态吸收光谱和氘标记研究得到了证实。连续流处理有助于直接扩大反应规模。

  DOI：

  10.1021/acs.orglett.7b03565
• 作为产物：
  描述：

  α,α'-Diphenyl-2-pyridylazidomethane 以 十二烷 为溶剂， 反应 0.5h， 生成 N-(phenyl(pyridin-2-yl)methylene)aniline 、 N-(2-pyridinyl)benzophenone imine
  参考文献：
  名称：

  Desbene, P. L.; Jehanno, N., Journal of Heterocyclic Chemistry, 1984, vol. 21, p. 1313 - 1319

  摘要：

  DOI：

文献信息

• Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands
  申请人：——

  公开号：US20040015017A1

  公开（公告）日：2004-01-22

  A process for the hydrogenation, using molecular hydrogen (H 2 ), of a catalytic system, wherein the catalytic system comprises a base and a complex of formula; (II) wherein Y represents simultaneously or independently a hydrogen or halogen atom, a hydroxy group, or an alkoxy, carboxyl or other anionic radical, and N 2 P 2 is a tetradentate diimine-diphosphino ligand.

  一种用分子氢（H2）进行加氢的催化体系的方法，其中催化体系包括一种碱和一个具有以下公式的配合物：（II），其中Y同时或独立地代表氢或卤素原子、羟基、烷氧基、羧基或其他阴离子基团，而N2P2是一种四齿二亚胺-二膦配体。
• Enantioenriched Ruthenium-Tris-Bipyridine Complexes Bearing One Helical Bipyridine Ligand: Access to Fused Multihelicenic Systems and Chiroptical Redox Switches
  作者：Martin Kos、Rafael Rodríguez、Jan Storch、Jan Sýkora、Elsa Caytan、Marie Cordier、Ivana Císařová、Nicolas Vanthuyne、J. A. Gareth Williams、Jaroslav Žádný、Vladimír Církva、Jeanne Crassous

  DOI：10.1021/acs.inorgchem.1c01379

  日期：2021.8.16

  2-pyridyl groups are described. The preparation was performed via an adapted Mallory reaction using aromatic imines as precursors. The obtained novel class of helical 2,2′-bipyridine ligands was then coordinated to Ru(bipy)22+ units, thus affording the first diastereomerically and enantiomerically pure [RuL(bipy)2]2+ (11a,c, L = 6a,c) or [Ru2L′(bipy)4]4+ (12, L′ = 10b) complexes. The topology and stereochemistry

  描述了被一个或两个 2-吡啶基取代的新型氮杂[ n ]螺旋烯（6a - d，10a，b，n = 4-7）的合成和光物理和手性光学特性。该制备是通过使用芳族亚胺作为前体的经过调整的 Mallory 反应进行的。然后将获得的新型螺旋 2,2'-联吡啶配体与 Ru(bipy) 2 2+单元配位，从而提供第一个非对映异构和对映异构纯 [RuL(bipy) 2 ] 2+ ( 11a , c , L = 6a , c ) 或 [Ru 2L'(bipy) 4 ] 4+ ( 12 , L' = 10b ) 复合物。详细研究了这些新型金属螺旋结构的拓扑结构和立体化学，特别是使用 X 射线晶体学。有趣的是，与钌 (II) 的配位使得能够在同一支架内制备包含氮杂-和钌-螺旋烯的融合多螺旋系统。详细检查了这些复合物的光物理、手性和氧化还原特性，并证明了有效的氧化还原触发的手性转换活性。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• JP2004/513929
  申请人：——

  公开号：——

  公开（公告）日：——