7-异丙基-2-氮杂环庚酮 | 102539-72-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酰胺类
• 中文名称: 7-异丙基-2-氮杂环庚酮
• 英文名称: 7-isopropyl-hexahydro-azepin-2-one
• 英文别名: 7-Isopropyl-hexahydro-azepin-2-on；7-Isopropylazepan-2-one；7-propan-2-ylazepan-2-one
• CAS: 102539-72-0
• 化学式: C₉H₁₇NO
• 分子量: 155.24
• InChiKey: BKJOSQCBZBMZKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (2S,5S)-9a-(tert-Butyl-dimethyl-silanyloxy)-5-isopropyl-2-phenyl-5,8,9,9a-tetrahydro-oxazolo[3,2-a]azepin-3-one 在 palladium on activated charcoal 氢气 、 sodium hydroxide 作用下， 以 甲醇 为溶剂， 以56%的产率得到7-异丙基-2-氮杂环庚酮
  参考文献：
  名称：

  通过氧恶唑烷酮的RCM反应方便地合成中型内酰胺

  摘要：

  由仲O-酰基扁桃酰胺经TBSOTf处理制得的氧恶唑烷酮，在Grubbs催化剂存在下进行RCM反应，得到恶唑并ze庚因或恶唑并ze嗪，它们易于通过还原反应转化为N-未取代的七元或八元内酰胺。治疗。

  DOI：

  10.1016/j.tetlet.2006.03.152

文献信息

• GLYCOLIC ACID COPOLYMER AND METHOD FOR PRODUCTION THEREOF
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1535943A1

  公开（公告）日：2005-06-01

  A glycolic acid copolymer comprising (a) 80 to less than 95 % by mole of glycolic acid monomer units, (b) 5.0 to 20.0 % by mole of non-glycolic, hydroxycarboxylic acid monomer units, and (c) 0 to 0.10 % by mole of diglycolic acid monomer units, the non-glycolic, hydroxycarboxylic acid monomer units (b) constituting a plurality of segments each independently consisting of at least one monomer unit (b), wherein the segments have an average chain length of from 1.00 to 1.50 in terms of the average number of monomer unit or units (b), the total of the components (a), (b) and (c) being 100 % by mole, the glycolic acid copolymer having a weight average molecular weight of 50,000 or more.

  一种乙醇酸共聚物，包括(a)80%至低于95%(摩尔)的乙醇酸单体单元，(b)5.0%至20.0%(摩尔)的非乙醇羟基羧酸单体单元，和(c)0%至0.10%（摩尔）的二羟基乙酸单体单元，非乙醇羟基羧酸单体单元（b）构成多个区段，每个区段独立地由至少一个单体单元（b）组成，其中区段的平均链长为 1.以单体单元(b)的平均数量计算，各组分(a)、(b)和(c)的总和为100%摩尔，乙醇酸共聚物的重量平均分子量为50,000或以上。
• Glycolic acid copolymer and method for production thereof
  申请人：Kuroda Yoshito

  公开号：US20050288479A1

  公开（公告）日：2005-12-29

  A glycolic acid copolymer comprising (a) 80 to less than 95% by mole of glycolic acid monomer units, (b) 5.0 to 20.0% by mole of non-glycolic, hydroxycarboxylic acid monomer units, and (c) 0 to 0.10% by mole of diglycolic acid monomer units, the non-glycolic, hydroxycarboxylic acid monomer units (b) constituting a plurality of segments each independently consisting of at least one monomer unit (b), wherein the segments have an average chain length of from 1.00 to 1.50 in terms of the average number of monomer unit or units (b), the total of the components (a), (b) and (c) being 100% by mole, the glycolic acid copolymer having a weight average molecular weight of 50,000 or more.

  一种乙醇酸共聚物，包括(a)80%至小于 95%（以摩尔计）的乙醇酸单体单元，(b)5.0%至 20.0%（以摩尔计）的非乙醇羟基羧酸单体单元，和(c)0%至 0.10%（以摩尔计）的二乙醇酸单体单元，非乙醇羟基羧酸单体单元(b)构成多个段，每个段独立地由至少一个单体单元(b)组成，其中段的平均链长为 1.以单体单元(b)的平均数量计算，各组分(a)、(b)和(c)的总和为100%摩尔，乙醇酸共聚物的重量平均分子量为50,000或以上。
• Ziegenbein et al., Chemische Berichte, 1955, vol. 88, p. 1906,1914
  作者：Ziegenbein et al.

  DOI：——

  日期：——
• Thermosetting resin composition, cured product, and production of cured product
  申请人：HITACHI, LTD.

  公开号：EP0153603B1

  公开（公告）日：1992-01-02
• SAFETY EQUIPMENT TO PROTECT A WEARER COMPRISING AN AROMATIC POLYAMIDE COMPOSITION, AND AROMATIC POLYAMIDE COMPOSITION SUITABLE FOR MAKING SAID SAFETY EQUIPMENT
  申请人：Solvay Advanced Polymers, L.L.C.

  公开号：EP1720616A1

  公开（公告）日：2006-11-15