1,5-dimorpholinoanthracene-9,10-dione | 144775-89-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,5-dimorpholinoanthracene-9,10-dione
• 英文别名: 1,5-Dimorpholinoanthraquinone；1,5-dimorpholin-4-ylanthracene-9,10-dione
• CAS: 144775-89-3
• 化学式: C₂₂H₂₂N₂O₄
• mdl: MFCD00603670
• 分子量: 378.428
• InChiKey: AJHIVAGFIDZCHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  59.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  吗啉 、 1,5-二氯蒽醌 以 二甲基亚砜 为溶剂， 反应 1.0h， 以78.7%的产率得到1,5-dimorpholinoanthracene-9,10-dione
  参考文献：
  名称：

  Synthesis and Physical Property Measurement of New Red Pigment based on Anthraquinone Derivatives for Color Filter Pigments

  摘要：

  In this study, two red compounds for CF pigment bearing piperidine or morpholine group at 1,5-postion of anthraquinone were newly synthesized. It was observed that maximum values of UV-visible absorption of 1,5-DMAQ and 1,5-DPAQ were 488 and 498 nm, respectively, where 1,5-DMAQ has shown higher blue-shifted value than 1,5-DPAQ. These compounds show high molar extinction coefficient values of 10(3) L/mol.cm and can be processed in spin-coating method. The synthesized materials are expected to be candidates for CF pigments in solution process. In temperature study, 1,5-DPAQ and 1,5-DMAQ were decomposed at 184 degrees C and 225 degrees C.

  DOI：

  10.1080/15421406.2011.600624

文献信息

• Synthesis and Physical Property Measurement of New Red Pigment based on Anthraquinone Derivatives for Color Filter Pigments
  作者：Junghyo Park、Youngil Park、Jongwook Park

  DOI：10.1080/15421406.2011.600624

  日期：2011.11.4

  In this study, two red compounds for CF pigment bearing piperidine or morpholine group at 1,5-postion of anthraquinone were newly synthesized. It was observed that maximum values of UV-visible absorption of 1,5-DMAQ and 1,5-DPAQ were 488 and 498 nm, respectively, where 1,5-DMAQ has shown higher blue-shifted value than 1,5-DPAQ. These compounds show high molar extinction coefficient values of 10(3) L/mol.cm and can be processed in spin-coating method. The synthesized materials are expected to be candidates for CF pigments in solution process. In temperature study, 1,5-DPAQ and 1,5-DMAQ were decomposed at 184 degrees C and 225 degrees C.