5-propyl-5"-bromo-2,2':5',2"-terthiophene | 934276-42-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 5-propyl-5"-bromo-2,2':5',2"-terthiophene
• 英文别名: 5-Propyl-5''-bromo-2,2':5',2''-terthiophene；2-bromo-5-[5-(5-propylthiophen-2-yl)thiophen-2-yl]thiophene
• CAS: 934276-42-3
• 化学式: C₁₅H₁₃BrS₃
• 分子量: 369.37
• InChiKey: HEWDRNFVPCHPDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-propyl-5"-bromo-2,2':5',2"-terthiophene 、 5,5-dimethyl-2-(4-pentylphenyl)-1,3,2-dioxaborinane 在 四(三苯基膦)钯 sodium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 反应 1.0h， 以78%的产率得到5-propyl-5"-(4-pentylphenyl)-2,2':5',2"-terthiophene
  参考文献：
  名称：

  EP2036900

  摘要：

  公开号：
• 作为产物：
  描述：

  5-Propyl-[2,2';5',2'']terthiophene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 四氢呋喃 为溶剂， 以92%的产率得到5-propyl-5"-bromo-2,2':5',2"-terthiophene
  参考文献：
  名称：

  Organic Semiconductors with Helical Structure Based on Oligothiophene derivatives Exhibiting Chiral Nematic Phase

  摘要：

  We have synthesized 2-[5-(4-[(S)-2-methylbutoxy]phenyl)-3-methyl]-2'''-propyl-2: 5'-2'-5 ''-2 ''-5"'-quaterthiophene (10), a liquid crystalline semiconductor that exhibits a chiral nematic phase, and used the time-of-flight technique to determine its carrier mobility behavior. In the chiral nematic phase, the positive carrier mobility was 2 x 10(-4)cm(2)/Vs at 120 degrees C and the negative carrier mobility was 1 x 10-4 cm(2)/Vs, both of which we attribute to electronic processes. For the negative carrier, in addition to the fast electronic process, we also observed a slow carrier transport, having mobility on the order of 10(-5)cm(2)/Vs, which we attribute to ionic conduction. Chiral dimers containing binaphthyl group exhibited stable glassy cholesteric phase and cholesteric thin films with selective reflection band in visible light area could be fabricated. They emitted circularly polarized light with dichroic parameter of 1.3 when UV light was illuminated.

  DOI：

  10.1080/15421400701735723

文献信息

• SMECTIC LIQUID CRYSTAL COMPOUND
  申请人：Funahashi Masahiro

  公开号：US20100237327A1

  公开（公告）日：2010-09-23

  According to the present invention, a liquid crystal semiconductor capable of exhibiting a highly ordered smectic phase at approximately room temperature, being used for formation of a smectic liquid crystal thin film that is stable at room temperature by a solution process, and showing excellent ambipolar charge-transporting properties, a thin film transistor comprising the same, and the like are provided. Also, the following are provided: a smectic liquid crystal compound represented by the following general formula (1) wherein R 1 represents a straight-chain alkyl group having 1 to 8 carbon atoms, R 2 represents an alkyl or alkoxy group having 1 to 8 carbon atoms, and “n” is an integer of 0 to 3; an ambipolar charge-transporting material comprising the smectic liquid crystal compound; an organic semiconductor thin film having a thin film layer comprising the smectic liquid crystal compound; and a thin film transistor comprising the organic semiconductor thin film.

  根据本发明，提供了一种液晶半导体，能够在近似室温时表现出高度有序的蜡状相，通过溶液法形成在室温下稳定的蜡状液晶薄膜，并显示出优异的双极性电荷传输特性，以及包括它的薄膜晶体管等。此外，还提供以下内容：由下列通式（1）表示的蜡状液晶化合物，其中R1表示具有1至8个碳原子的直链烷基，R2表示具有1至8个碳原子的烷基或烷氧基，“n”是0至3的整数；包括蜡状液晶化合物的双极性电荷传输材料；具有包括蜡状液晶化合物的薄膜层的有机半导体薄膜；以及包括有机半导体薄膜的薄膜晶体管。
• Smectic liquid crystal compound
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：US07915609B2

  公开（公告）日：2011-03-29

  According to the present invention, a liquid crystal semiconductor capable of exhibiting a highly ordered smectic phase at approximately room temperature, being used for formation of a smectic liquid crystal thin film that is stable at room temperature by a solution process, and showing excellent ambipolar charge-transporting properties, a thin film transistor comprising the same, and the like are provided. Also, the following are provided: a smectic liquid crystal compound represented by the following general formula (1) wherein R1 represents a straight-chain alkyl group having 1 to 8 carbon atoms, R2 represents an alkyl or alkoxy group having 1 to 8 carbon atoms, and “n” is an integer of 0 to 3; an ambipolar charge-transporting material comprising the smectic liquid crystal compound; an organic semiconductor thin film having a thin film layer comprising the smectic liquid crystal compound; and a thin film transistor comprising the organic semiconductor thin film.

  根据本发明，提供了一种液晶半导体，能够在近似室温下表现出高度有序的液晶相，通过溶液过程用于形成在室温下稳定的液晶相薄膜，并展现出优异的双极电荷传输特性，以及包括该液晶半导体的薄膜晶体管等。此外，还提供以下物质：由下列通式（1）表示的液晶相化合物，其中R1表示1至8个碳原子的直链烷基，R2表示1至8个碳原子的烷基或烷氧基，“n”是0至3的整数；包含该液晶相化合物的双极电荷传输材料；具有包含该液晶相化合物的薄膜层的有机半导体薄膜；以及包括该有机半导体薄膜的薄膜晶体管。
• US7915609B2
  申请人：——

  公开号：US7915609B2

  公开（公告）日：2011-03-29
• Organic Semiconductors with Helical Structure Based on Oligothiophene derivatives Exhibiting Chiral Nematic Phase
  作者：Masahiro Funahashi、Nobuyuki Tamaoki

  DOI：10.1080/15421400701735723

  日期：2007.12.13

  We have synthesized 2-[5-(4-[(S)-2-methylbutoxy]phenyl)-3-methyl]-2'''-propyl-2: 5'-2'-5 ''-2 ''-5"'-quaterthiophene (10), a liquid crystalline semiconductor that exhibits a chiral nematic phase, and used the time-of-flight technique to determine its carrier mobility behavior. In the chiral nematic phase, the positive carrier mobility was 2 x 10(-4)cm(2)/Vs at 120 degrees C and the negative carrier mobility was 1 x 10-4 cm(2)/Vs, both of which we attribute to electronic processes. For the negative carrier, in addition to the fast electronic process, we also observed a slow carrier transport, having mobility on the order of 10(-5)cm(2)/Vs, which we attribute to ionic conduction. Chiral dimers containing binaphthyl group exhibited stable glassy cholesteric phase and cholesteric thin films with selective reflection band in visible light area could be fabricated. They emitted circularly polarized light with dichroic parameter of 1.3 when UV light was illuminated.
• EP2036900
  申请人：——

  公开号：——

  公开（公告）日：——