1,2-bis-(2-(2-pyridyl)benzimidazolyl)ethane | 102948-77-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1,2-bis-(2-(2-pyridyl)benzimidazolyl)ethane
• 英文别名: 1,2-bis-(2-[2]pyridyl-benzimidazol-1-yl)-ethane；1,2-Bis-(2-[2]pyridyl-benzimidazol-1-yl)-aethan；1,1'-(Ethane-1,2-diyl)bis[2-(pyridin-2-yl)-1H-benzimidazole]；2-pyridin-2-yl-1-[2-(2-pyridin-2-ylbenzimidazol-1-yl)ethyl]benzimidazole
• CAS: 102948-77-6
• 化学式: C₂₆H₂₀N₆
• 分子量: 416.485
• InChiKey: BFVAZZBXAAYRQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  32
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 sodium perchlorate 、 1,2-bis-(2-(2-pyridyl)benzimidazolyl)ethane 在 水 作用下， 以 乙醇 、 水 为溶剂， 以74%的产率得到bis(2,2'-bipyridine)(1,2-bis(2-(2-pyridyl)benzimidazolyl)ethane)ruthenium(II) perchlorate * H2O
  参考文献：
  名称：

  Ohno, Takeshi; Nozaki, Koichi; Haga, Masa-Aki, Inorganic Chemistry, 1992, vol. 31, # 4, p. 548 - 555

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-bis(2-nitrophenyl)-1,2-ethanediamine 在 盐酸 、 tin 、 乙醇 作用下， 生成 1,2-bis-(2-(2-pyridyl)benzimidazolyl)ethane
  参考文献：
  名称：

  Sexadentate Chelate Compounds.¹ X

  摘要：

  DOI：

  10.1021/ja01548a015

文献信息

• Intramolecular electron transfer in photoexcited ruthenium(II)-rhodium(III) binuclear compounds
  作者：Koichi Nozaki、Takeshi Ohno、Masaaki Haga

  DOI：10.1021/j100205a051

  日期：1992.12

  Lifetimes of metal-to-ligand charge-transfer excited states, (3CT)Ru, of ruthenium(II) were measured for ruthenium(II)-rhodium(III) compounds, [Ru(bpy)2(L-L)Rh(bpy)2]5+, and its analogous compounds in a wide temperature range (170-300 K) in the fluid solvent of a mixture of propionitrile and butyronitrile. The interventing ligands (L-L) used were 2,6-bis(2'-pyridyl)benzdiimidazole (dpimbH-2), 2,2'-bis(2''-pyridyl)bibenzimidazole (bpbimH-2), 1,1'-dimethyl-2,2'-bis(2''-pyridyl)-6,6'-bibenzimidazole (dmbpbim), and bis[2-(2'-pyridyl)benzimidazoyl]ethane (dpbime). The rapid quenching of (3CT)Ru can be explained in terms of an intramolecular electron transfer (ET), (3CT)Ru-Rh(III) --> Ru(III)-Rh(II), which is followed by a fast backward ET to regenerate the ground state. The frequency factors obtained from the temperature dependence of the ET rates were found to be almost constant, (1.1-4.1) x 10(11) s-1, irrespective of the intervening ligands, indicating that the ET processes are adiabatic. These factors were in agreement with the value (4-6) x 10(11) s-1 calculated provided that the ET is influenced by the relaxation dynamics of the solvent. The activation energy (E(a)) ranged from 0.17 to 0.22 eV depending on the bridging ligands. Using the reorganization energy, lambda, determined from the metal-to-metal charge-transfer transition of a mixed-valence compound, [Ru(bpy)2(L-L)Ru(bpy)2]5+, E(a) was evaluated on the basis of the classical ET theory. The E(a) values calculated by considering the temperature dependence of lambda and the solvent motion were in good agreement with the observed values except for bpbimH-2.
• Sexadentate Chelate Compounds.¹ X
  作者：Francis Lions、Kenneth V. Martin

  DOI：10.1021/ja01548a015

  日期：1958.8
• Ohno, Takeshi; Nozaki, Koichi; Haga, Masa-Aki, Inorganic Chemistry, 1992, vol. 31, # 4, p. 548 - 555
  作者：Ohno, Takeshi、Nozaki, Koichi、Haga, Masa-Aki

  DOI：——

  日期：——