(E)-6-Tridecensaeure | 37011-91-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-6-Tridecensaeure
• 英文别名: tridec-6t-enoic acid；(E)-tridec-6-enoic acid
• CAS: 37011-91-9
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: JFSULGQQCJJKOU-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-6-Tridecensaeure 在 lithium aluminium tetrahydride 、 三溴化磷 作用下， 以 甲苯 为溶剂， 生成 1-bromo-6E-tridecene
  参考文献：
  名称：

  肿瘤抑制剂。3.从美国锥花根中鉴定和合成溶瘤烃。

  摘要：

  DOI：

  10.1021/jm00276a013
• 作为产物：
  描述：

  (E)-4-十一烯-1-醇 在 三溴化磷 作用下， 以 甲苯 为溶剂， 生成 (E)-6-Tridecensaeure
  参考文献：
  名称：

  肿瘤抑制剂。3.从美国锥花根中鉴定和合成溶瘤烃。

  摘要：

  DOI：

  10.1021/jm00276a013

文献信息

• Hybrid onium salt
  申请人：Ishihara Masami

  公开号：US20050020710A1

  公开（公告）日：2005-01-27

  The present invention relates to a hybrid type onium salt having an iodonium salt and a sulfonium salt in the molecule, useful, for example, as a cationic type photopolymerization initiator and an acid generator for a chemically amplified resist and provides a hybrid type onium salt shown by the general formula [1]: [wherein R 1 to R 3 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which maybe substituted; Q 1 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T 1 is an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; and R 4 is an alkyl group, an alkenyl group, an aryl group or an aralkyl group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted or a group shown by the general formula [2]: (wherein R 5 to R 7 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which maybe substituted; Q 2 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T 2 an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; A 3 is a counter anion; m is an integer of 0 to 4; and two ns are each independently an integer of 0 to 5); A 1 and A 2 are each independently a counter anion; and m and n are the same as described above], and a polymerization initiator or an acid generator, comprising said onium salt.

  本发明涉及一种杂化型离子盐，其分子中具有碘化离子盐和亚砜盐，例如，作为阳离子型光聚合引发剂和化学放大型抗蚀剂的酸发生剂有用，并提供由通式[1]所示的杂化型离子盐：[其中R1至R3分别独立地是卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基，可被取代；Q1是直链、氧原子、硫原子或较低的烷基链；T1是烷基或芳基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基；R4是烷基、烯丙基、芳基或芳基烷基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基或由通式[2]所示的基：（其中R5至R7分别独立地是卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基，可被取代；Q2是直链、氧原子、硫原子或较低的烷基链；T2是烷基或芳基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基；A3是一个对离子；m是0到4的整数；两个n各自独立地是0到5的整数）；A1和A2各自独立地是一个对离子；m和n与上述描述相同]，以及包含该离子盐的聚合引发剂或酸发生剂。
• HYBRID ONIUM SALT
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：EP1443042A1

  公开（公告）日：2004-08-04

  The present invention relates to a hybrid type onium salt having an iodonium salt and a sulfonium salt in the molecule, useful, for example, as a cationic type photopolymerization initiator and an acid generator for a chemically amplified resist and provides a hybrid type onium salt shown by the general formula [1]: [wherein R1 to R3 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which may be substituted; Q1 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T1 is an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; and R4 is an alkyl group, an alkenyl group, an aryl group or an aralkyl group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted or a group shown by the general formula [2]: (wherein R5 to R7 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which may be substituted; Q2 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T2 an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; A3 is a counter anion; m is an integer of 0 to 4; and two ns are each independently an integer of 0 to 5); A1 and A2 are each independently a counter anion; and m and n are the same as described above], and a polymerization initiator or an acid generator, comprising said onium salt.

  本发明涉及一种分子中含有碘盐和锍盐的混合型鎓盐，例如可用作阳离子型光聚合引发剂和化学放大抗蚀剂的酸发生剂，并提供了通式[1]所示的混合型鎓盐： [其中R1至R3各自独立地为卤原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或可被取代的氨基；Q1为直链、氧原子、硫原子或低级亚烷基链；T1 是亚烷基或亚芳基，其取代基可选自由卤原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基组成的组；R4 是烷基、烯基、芳基或芳烷基，其取代基可选自卤原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基或通式 [2] 所示的基团： (其中 R5 至 R7 各自独立地为卤原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或可被取代的氨基；Q2 为直链、氧原子、硫原子或低级亚烷基链；T2 一个亚烷基或一个亚芳基，其取代基可选自卤原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基组成的组；A3为反阴离子；m为0至4的整数；两个n各自独立地为0至5的整数）；A1和A2各自独立地为反阴离子；m和n与上述相同]，以及包含所述鎓盐的聚合引发剂或酸发生器。
• US7101918B2
  申请人：——

  公开号：US7101918B2

  公开（公告）日：2006-09-05