bis(trimethylsilylethynyl)diphenylaminoborane | 1510847-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(trimethylsilylethynyl)diphenylaminoborane
• 英文别名: N-[bis(2-trimethylsilylethynyl)boranyl]-N-phenylaniline
• CAS: 1510847-74-1
• 化学式: C₂₂H₂₈BNSi₂
• 分子量: 373.453
• InChiKey: YPDPALZAYYEOID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.66
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(trimethylsilylethynyl)diphenylaminoborane 、 三(五氟苯基)硼烷 以 甲苯 为溶剂， 反应 30.0h， 以73%的产率得到
  参考文献：
  名称：

  Borole Formation by 1,1-Carboboration

  摘要：

  Bis(trimethylsilylethynyl)diphenylaminoborane was reacted with the strong Lewis acid B(C6F5)(3) at ambient temperature to give the borole 9 admixed with a small amount of its thermal follow-up product 12. Compound 9 was subsequently stabilized by adduct formation with pyridine (10). Treatment of bis-(trimethylsilylethynyl)phenylborane with B(C6F5)(3) gave the borole 14, which reacted with 3-hexyne to give the [4 + 2] cycloaddition product 15.

  DOI：

  10.1021/ja4110396
• 作为产物：
  描述：

  lithium diphenylamide 以 正戊烷 为溶剂， 生成 bis(trimethylsilylethynyl)diphenylaminoborane
  参考文献：
  名称：

  Borole Formation by 1,1-Carboboration

  摘要：

  Bis(trimethylsilylethynyl)diphenylaminoborane was reacted with the strong Lewis acid B(C6F5)(3) at ambient temperature to give the borole 9 admixed with a small amount of its thermal follow-up product 12. Compound 9 was subsequently stabilized by adduct formation with pyridine (10). Treatment of bis-(trimethylsilylethynyl)phenylborane with B(C6F5)(3) gave the borole 14, which reacted with 3-hexyne to give the [4 + 2] cycloaddition product 15.

  DOI：

  10.1021/ja4110396

文献信息

• Borole Formation by 1,1-Carboboration
  作者：Fang Ge、Gerald Kehr、Constantin G. Daniliuc、Gerhard Erker

  DOI：10.1021/ja4110396

  日期：2014.1.8

  Bis(trimethylsilylethynyl)diphenylaminoborane was reacted with the strong Lewis acid B(C6F5)(3) at ambient temperature to give the borole 9 admixed with a small amount of its thermal follow-up product 12. Compound 9 was subsequently stabilized by adduct formation with pyridine (10). Treatment of bis-(trimethylsilylethynyl)phenylborane with B(C6F5)(3) gave the borole 14, which reacted with 3-hexyne to give the [4 + 2] cycloaddition product 15.