1,1-dimethyl-tridecylamine | 2626-48-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,1-dimethyl-tridecylamine
• 英文别名: 2-Amino-2-methyl-tetradecan；2-Methyltetradecan-2-amine
• CAS: 2626-48-4
• 化学式: C₁₅H₃₃N
• 分子量: 227.434
• InChiKey: ZPPKOTQMXJSSFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,1-dimethyl-tridecylamine 在 正丁基锂 、 草酰氯 作用下， 以 四氢呋喃 、 正己烷 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 1.5h， 生成 N-fluoro-N-(2-methyltetradecan-2-yl)benzamide
  参考文献：
  名称：

  Ni-Catalyzed Remote Radical/Cross-Electrophile Coupling Cascade for Selective C(sp³)–H Arylation

  摘要：

  DOI：

  10.1021/acs.orglett.2c00666
• 作为产物：
  描述：

  1-碘十二烷 在 盐酸 、 二苯基膦叠氮化物 、 三乙胺 、 sodium hydroxide 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 甲醇 、 水 、 溶剂黄146 、 甲苯 为溶剂， 反应 17.0h， 生成 1,1-dimethyl-tridecylamine
  参考文献：
  名称：

  钯催化未活化的γ-亚甲基C（sp3）的芳基化作用？H和δ-C ？含恶唑啉-羧酸盐助剂的H键

  摘要：

  未活化的γ的钯-催化的芳基化-亚甲基C（SP 3） H和远程δ-C  H键通过使用恶唑啉甲酸甲酯定向基团已被开发。在广泛的底物范围和对官能团（即卤素，硝基，氰基，醚，三氟甲基，胺和酯）的高耐受性下发生丙烯酸化。可以在酸性条件下除去恶唑啉型助剂。

  DOI：

  10.1002/chem.201502621

文献信息

• [EN] SOLVENTS<br/>[FR] SOLVANTS
  申请人：BIONIQS LTD

  公开号：WO2009034329A1

  公开（公告）日：2009-03-19

  There is described the use of a protic ionic liquid comprising a trialkylammonium salt as a solvent.

  这里描述了一种包含三烷基铵盐的质子离子液体作为溶剂的使用。
• Novel Amine-Borane Compounds and Uses Thereof
  申请人：Srebnik Morris

  公开号：US20100284914A1

  公开（公告）日：2010-11-11

  Novel families of amine-borane compounds, including fluorinated aminoboranes, novel bis-aminoboranes and aminoboranes having saturated and unsaturated ling alkyl chains are provided. Processes of preparing, pharmaceutical compositions and methods utilizing these novel compounds are also provided. Radiolabeled aminoboranes and uses thereof in radioimaging (e.g., PET) and radiotherapy are further provided.

  提供了新型的胺硼烷化合物家族，包括氟化胺硼烷，新型的双胺硼烷和具有饱和和不饱和长烷基链的胺硼烷。还提供了制备这些新化合物的方法、制药组合物和利用这些新化合物的方法。此外，还提供了放射性标记的胺硼烷及其在放射性成像（例如PET）和放射性治疗中的用途。
• Process for producing mixed tertiary amine oxide
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0146048A2

  公开（公告）日：1985-06-26

  A process for producing an aqueous solution of a straight-chain alkyl tertiary amine oxide and a branched-chain alkyl tertiary amine oxide by reacting aliphatic tertiary amines with a aqueous solution of hydrogen peroxide is disclosed. In this process, a tertiary amine which mainly consists of a branched-chain tertiary amine is first reacted with excess hydrogen peroxide, and then, a straight-chain alkyl tertiary amine which is substantially free of a branched-chain alkyl group is added to the reaction mixture for permitting further reaction with hydrogen peroxide. The process achieves a high overall conversion of the starting amines, and the final product has an extremely low level of residual hydrogen peroxide.

  本发明公开了一种通过脂肪族叔胺与过氧化氢水溶液反应生产直链烷基叔胺氧化物和支链烷基叔胺氧化物水溶液的工艺。在该工艺中，首先将主要由支链叔胺组成的叔胺与过量的过氧化氢反应，然后将基本上不含支链烷基的直链烷基叔胺加入反应混合物中，以便与过氧化氢进一步反应。该工艺实现了起始胺的高整体转化率，最终产品的过氧化氢残留量极低。
• Novel perfluoropolyether derivatives, and lubricants and magnetic recording medium using the same
  申请人：SONY CORPORATION

  公开号：EP0519406A2

  公开（公告）日：1992-12-23

  Novel perfluoropolyether derivatives are described which are obtained from perfluoropolyethers having a carboxyl group at one or both ends and monoamines or diamines. The derivative is useful as a lubricant owing to its significantly improved lubricity. The lubricity is shown under severe high or low temperature and humidity conditions over a long term. The derivative is especially useful as a lubricant for magnetic recording mediums of the coating and metal thin film types.

  本文描述了新型全氟聚醚衍生物，该衍生物由一端或两端带有羧基的全氟聚醚和单胺或二胺制成。这种衍生物的润滑性能显著提高，可用作润滑剂。这种润滑性可在严酷的高温或低温和潮湿条件下长期保持。该衍生物特别适用于涂层型和金属薄膜型磁记录介质的润滑剂。
• Catalyst and process for producing a rigid polyurethane foam
  申请人：Tosoh Corporation

  公开号：EP1382624A1

  公开（公告）日：2004-01-21

  The present invention relates to: (1) a catalyst for producing a rigid polyurethane foam by means of at least one blowing agent selected from the group consisting of 1,1,1,3,3-pentafluoropropane (HFC-245fa), 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and a low boiling point hydrocarbon, which comprises: (A) an aliphatic amine compound and at least one amine compound selected from the group consisting of triethylenediamine, N,N,N',N'-tetramethyl-1,6-hexanediamine and N,N-dimethylcyclohexylamine: or (B) an amine compound having an alkyl ether group and/or an aryl ether group in its molecule; (2) a catalyst for producing a rigid polyisocyanurate foam by means of at least one blowing agent selected from the group consisting of 1,1,1,3,3-pentafluoropropane (HFC-245fa), 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and a low boiling point hydrocarbon, which comprises an aliphatic amine compound and a polyisocyanurate catalyst and (3) a process for producing a rigid polyurethane foam excellent in the adhesive strength and flame retardancy of the foam and (4) a process for producing a rigid polyisocyanurate foam excellent in the flame retardancy, adhesive strenght and dimensional stability of the foam.

  本发明涉及 (1) 用至少一种发泡剂生产硬质聚氨酯泡沫塑料的催化剂，该发泡剂选自 1,1,1,3,3-五氟丙烷(HFC-245fa)、1,1,1,3,3-五氟丁烷(HFC-365mfc)和低沸点碳氢化合物组成的组，该催化剂包括 (A) 脂肪族胺化合物和至少一种选自三乙二胺、N,N,N',N'-四甲基-1,6-己二胺和 N,N-二甲基环己胺的胺化合物：或 (B) 分子中含有烷基醚基和/或芳基醚基的胺化合物； (2) 通过至少一种发泡剂生产硬质聚异氰脲酸酯泡沫塑料的催化剂，该发泡剂选 自 1,1,1,3,3-五氟丙烷(HFC-245fa)、1,1,1,3,3-五氟丁烷(HFC-365mfc)和低沸点碳氢化合物组成的 组，其中包括脂肪族胺化合物和聚异氰脲酸酯催化剂，以及 (3) 生产粘合强度和阻燃性能优异的硬质聚氨酯泡沫塑料的工艺，以及 (4) 生产硬质聚异氰脲酸酯泡沫塑料的工艺，泡沫塑料的阻燃性、粘合强度和 尺寸稳定性极佳。