2-dodecyl-1,3-dioxolane | 15138-51-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: 2-dodecyl-1,3-dioxolane
• CAS: 15138-51-9
• 化学式: C₁₅H₃₀O₂
• 分子量: 242.402
• InChiKey: QNSAURSZMJBKMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-dodecyl-1,3-dioxolane 在 硫酸 作用下， 反应 10.0h， 以92%的产率得到十三醛
  参考文献：
  名称：

  Iwamoto, Minoru; Kubota, Noboru; Takagi, Yoshikazu, Agricultural and Biological Chemistry, 1982, vol. 46, # 9, p. 2383 - 2386

  摘要：

  DOI：
• 作为产物：
  描述：

  3-氯丙环乙烯缩醛 在 dilithium tetrachlorocuprate 、 18-冠醚-6 、 magnesium 、 sodium iodide 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 反应 7.0h， 生成 2-dodecyl-1,3-dioxolane
  参考文献：
  名称：

  Iwamoto, Minoru; Kubota, Noboru; Takagi, Yoshikazu, Agricultural and Biological Chemistry, 1982, vol. 46, # 9, p. 2383 - 2386

  摘要：

  DOI：

文献信息

• Differentiating CBr and CCl Bond Activation by Using Solvent Polarity: Applications to Orthogonal Alkyl-Alkyl Negishi Reactions
  作者：Niloufar Hadei、George T. Achonduh、Cory Valente、Christopher J. O'Brien、Michael G. Organ

  DOI：10.1002/anie.201100705

  日期：2011.4.18

  A pot to share: A CalkylCl bond can be rendered “dormant” or “active” in the Negishi alkyl–alkyl cross‐coupling by a simple solvent polarity “switch” (see scheme). Adjustment from a 1:2 to a 2:1 solvent ratio of dimethylimidazolidinone:tetrahydrofuran enables orthogonal alkyl–alkyl Negishi cross‐coupling strategies to be carried out on bifunctional bromochloroalkanes in one pot at room temperature

  一个共享的锅：通过简单的溶剂极性“转换”，在Negishi烷基-烷基交叉偶联中，AC烷基Cl键可被“休眠”或“激活”。将二甲基咪唑啉酮：四氢呋喃的溶剂比例从1：2调整为2：1，可以在室温下在一锅中对双官能溴氯烷烃进行正交烷基-烷基Negishi交叉偶联策略。
• Photoalkylation of cyclic acetals
  作者：I. Rosenthal、Dov Elad

  DOI：10.1021/jo01266a067

  日期：1968.2
• IWAMOTO, MINORU;KUBOTA, NOBORU;TAKAGI, YOSHIKAZU;KOGAMI, KUNIO;HAYASHI, K+, AGR. AND BIOL. CHEM., 1982, 46, N 9, 2383-2385
  作者：IWAMOTO, MINORU、KUBOTA, NOBORU、TAKAGI, YOSHIKAZU、KOGAMI, KUNIO、HAYASHI, K+

  DOI：——

  日期：——
• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.