苯基(苯基磺酰基)重氮甲烷 | 186422-68-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯基(苯基磺酰基)重氮甲烷
• 英文名称: phenyl(phenylsulfonyl)diazomethane
• 英文别名: [Benzenesulfonyl(diazo)methyl]benzene
• CAS: 186422-68-4
• 化学式: C₁₃H₁₀N₂O₂S
• 分子量: 258.301
• InChiKey: WXUDUBZIJPMIQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  苯基(苯基磺酰基)重氮甲烷 在 氧气 作用下， 以 gaseous matrix 为溶剂， 生成 苯磺酰基(苯基)甲酮
  参考文献：
  名称：

  Matrix Isolation of Diphenylsulfene and Diphenyl-α-sultine

  摘要：

  Diphenylsulfene (5) and diphenyl-alpha-sultine 6 were generated in cryogenic matrices by three independent routes: (i) the thermal reaction of diphenylcarbene (8) and SO2, (ii) the photochemically induced hetero Wolff rearrangement of sulfonylcarbene 11, and (iii) oxygen transfer from ozone to diphenylsulfine 16. Isotopic labeling with C-13 and O-18 allows for the assignment of several characteristic IR vibrations of 5. Irradiation with lambda > 375 nm results in the rearrangement of 5 to 6, which is the first alpha-sultine that has been characterized spectroscopically. The final Product on UV irradiation of 6 is benzophenone (9) and sulfur monoxide.

  DOI：

  10.1021/ja962949k
• 作为产物：
  描述：

  2-(苯磺酰基)-3-苯基环氧乙烷 在 ammonium hydroxide 、 HOOC-C₆H₄-SO₂N₃ 、 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 20.17h， 生成 苯基(苯基磺酰基)重氮甲烷
  参考文献：
  名称：

  Matrix Isolation of Diphenylsulfene and Diphenyl-α-sultine

  摘要：

  Diphenylsulfene (5) and diphenyl-alpha-sultine 6 were generated in cryogenic matrices by three independent routes: (i) the thermal reaction of diphenylcarbene (8) and SO2, (ii) the photochemically induced hetero Wolff rearrangement of sulfonylcarbene 11, and (iii) oxygen transfer from ozone to diphenylsulfine 16. Isotopic labeling with C-13 and O-18 allows for the assignment of several characteristic IR vibrations of 5. Irradiation with lambda > 375 nm results in the rearrangement of 5 to 6, which is the first alpha-sultine that has been characterized spectroscopically. The final Product on UV irradiation of 6 is benzophenone (9) and sulfur monoxide.

  DOI：

  10.1021/ja962949k

文献信息

• Matrix Isolation of Diphenylsulfene and Diphenyl-α-sultine
  作者：Wolfram Sander、Andreas Kirschfeld、Martin Halupka

  DOI：10.1021/ja962949k

  日期：1997.2.1

  Diphenylsulfene (5) and diphenyl-alpha-sultine 6 were generated in cryogenic matrices by three independent routes: (i) the thermal reaction of diphenylcarbene (8) and SO2, (ii) the photochemically induced hetero Wolff rearrangement of sulfonylcarbene 11, and (iii) oxygen transfer from ozone to diphenylsulfine 16. Isotopic labeling with C-13 and O-18 allows for the assignment of several characteristic IR vibrations of 5. Irradiation with lambda > 375 nm results in the rearrangement of 5 to 6, which is the first alpha-sultine that has been characterized spectroscopically. The final Product on UV irradiation of 6 is benzophenone (9) and sulfur monoxide.