1,4,5,8-tetrakis(4-methylaniline)anthracene-9,10-dione | 108313-14-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4,5,8-tetrakis(4-methylaniline)anthracene-9,10-dione
• 英文别名: 1,4,5,8-tetra-p-toluidino-anthraquinone；1,4,5,8-Tetra-p-toluidino-anthrachinon；1,4,5,8-Tetrakis(4-methylanilino)anthracene-9,10-dione
• CAS: 108313-14-0
• 化学式: C₄₂H₃₆N₄O₂
• 分子量: 628.773
• InChiKey: DKJZDSKEHFGPTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  48
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  82.3
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,4,5,8-tetrakis(4-methylaniline)anthracene-9,10-dione 生成 tetrasodium;1,4,5,8-tetrakis(4-methylanilino)-9,10-dioxoanthracene-2,3,6,7-tetrasulfonate
  参考文献：
  名称：

  TAKUMA, XIROSUKEH;KURODA, SIDZUO;GODA, ISAMU;KOSIDA, XITOSI;SOGA, XIROSI

  摘要：

  DOI：
• 作为产物：
  描述：

  4,8-dinitro-1,5-dichloroanthraquinone 、 乙烷,三氯氟- 生成 1,4,5,8-tetrakis(4-methylaniline)anthracene-9,10-dione
  参考文献：
  名称：

  DE127458

  摘要：

  公开号：

文献信息

• [EN] AROMATIC HYDROCARBON-SOLUBLE ANTHRAQUINONE<br/>[FR] ANTHRAQUINONE AROMATIQUE SOLUBLE DANS DES HYDROCARBURES
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2022026225A1

  公开（公告）日：2022-02-03

  The present invention is a method of making 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione (where R is H or a hydrocarbyl group) comprising the step of contacting 1,4,5,8-tetrachloroanthraquinone with a mixture of R-anilines comprising at least two different R groups, under conditions to produce 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione. The present disclosure also provides a reaction mixture of 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione characterized by having the R groups on at least 75% of the 1,4,5,8-tetrakis(R-amino)anthracene-9,10-dione molecules in the mixture becomprised of 2 or more different R groups. The present disclosure also provides a method of improving the solubility of 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione in aromatic hydrocarbons distilled from crude oil, comprising selecting a mixture of 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-diones which are characterized by having at least 75% of the 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione molecules in the mixture comprise two or more different R groups. The compounds of the present invention exhibit a suitable UV visible absorbance profile making them suitable for use as a fuel marker.

  本发明是一种制备1,4,5,8-四(取代苯基氨基)蒽醌-9,10-二酮（其中R为H或烃基）的方法，包括将1,4,5,8-四氯蒽醌与至少含有两种不同R基团的R-苯胺混合物接触，以产生1,4,5,8-四(取代苯基氨基)蒽醌-9,10-二酮。本公开还提供了一种1,4,5,8-四(取代苯基氨基)蒽醌-9,10-二酮的反应混合物，其特征在于至少75%的1,4,5,8-四(取代氨基)蒽醌-9,10-二酮分子中的R基团由两种或更多不同的R基团组成。本公开还提供了一种提高1,4,5,8-四(取代苯基氨基)蒽醌-9,10-二酮在从原油蒸馏出的芳香烃中的溶解度的方法，包括选择至少75%的1,4,5,8-四(取代苯基氨基)蒽醌-9,10-二酮分子中含有两种或更多不同R基团的混合物。本发明化合物具有适当的UV可见吸收特性，适用于用作燃料标记剂。
• Ray absorption filter
  申请人：Sumitomo Chemical Company, Limited

  公开号：US04755012A1

  公开（公告）日：1988-07-05

  A near infrared ray absorption filter, particularly usable as a sharp cut filter for an infrared ray sensor, which comprises as an absorbent capable of controlling transmission of a ray at least one anthraquinone compound represented by the following formula, ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 are different from each other or the same, and stand for a phenyl or naphthyl group unsubstituted or substituted with at least one alkyl, alkoxy, phenoxy or hydroxy group, and the rings A and B are unsubstituted or substituted with at least one lower alkyl group or halogen atom.

  一种近红外线吸收滤光片，特别适用于红外线传感器的锐利切割滤光片，其包含至少一种通过以下式子表示的蒽醌化合物作为吸收剂，该吸收剂能够控制射线的透射： ##STR1## 其中A.sub.1、A.sub.2、A.sub.3和A.sub.4彼此不同或相同，代表未取代或取代至少一个烷基、烷氧基、苯氧基或羟基的苯基或萘基，环A和环B未取代或取代至少一个低烷基或卤素原子。
• Halogenated anthraquinones useful as near infrared absorbing optical filters, and method of making them
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0323184A1

  公开（公告）日：1989-07-05

  High-purity 1,4,5,8-tetraanilidoanthraquinones which are substituted at the p-position of at least one of four anilido benzene rings by a halogen atom are good near infrared rays absorbing filters and are prepared from high purity 1,4,5,8-tetrachloro­anthraquinone by reaction with a correspondingly substituted aniline or mixture of anilines in the presence of a salt of an aliphatic carboxylic acid, a benzyl alcohol derivative and copper ions as reaction catalyst.

  高纯度 1,4,5,8-四苯胺基蒽醌在四个苯胺基苯环中至少有一个环的 p 位被卤素原子取代，是一种良好的近红外吸收滤光器，由高纯度 1,4,5,8-四氯蒽醌与相应取代的苯胺或苯胺混合物在脂肪族羧酸盐、苯甲醇衍生物和铜离子作为反应催化剂的存在下反应制备而成。
• DE172464
  申请人：——

  公开号：——

  公开（公告）日：——
• DE137782
  申请人：——

  公开号：——

  公开（公告）日：——