11,13-Tetradecadienyl acetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 11,13-Tetradecadienyl acetate
• 英文别名: tetradeca-11,13-dienyl acetate
• 化学式: C₁₆H₂₈O₂
• 分子量: 252.39
• InChiKey: FNGLZFYTQNKDJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• METHOD OF PRODUCING ALIPHATIC ALDEHYDE COMPOUND HAVING TERMINAL CONJUGATED DIENE STRUCTURE AND INTERMEDIATE THEREFOR
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20170297987A1

  公开（公告）日：2017-10-19

  Provided are a method for producing a terminal conjugated dienal compound without an oxidation reaction and a terminal hydroxyacetal compound useful as an intermediate in the method. More specifically, provided are a method for producing an (E)-dienal compound comprising the steps of: a metalation reaction of an alkynal acetal compound (1) to obtain an organic metal compound (2), an addition reaction of (2) to ethylene oxide to obtain a hydroxyalkynal acetal compound (3), a reduction reaction of (3) to obtain an (E)-hydroxyalkenal acetal compound (4), a functional group conversion reaction of (4) to obtain an (E)-alkenal acetal compound (5) having a leaving group X, an elimination reaction of (5) to obtain an (E)-dienal acetal compound (6), and a hydrolysis reaction of (6) to obtain the (E)-dienal compound (7); and others.

  提供了一种无需氧化反应的生产末端共轭二烯醛化合物和末端羟基缩醛化合物的方法。更具体地，提供了一种生产(E)-二烯醛化合物的方法，包括以下步骤：将炔醛缩醛化合物（1）进行金属化反应以得到有机金属化合物（2），将（2）加入到环氧乙烷中进行加成反应以得到羟基炔醛缩醛化合物（3），将（3）进行还原反应以得到(E)-羟基烯醛缩醛化合物（4），将（4）进行官能团转化反应以得到具有离去基X的(E)-烯醛缩醛化合物（5），将（5）进行消除反应以得到(E)-二烯醛缩醛化合物（6），最后进行水解反应以得到(E)-二烯醛化合物（7）；还包括其他步骤。
• SLOW-RELEASE FORMULATION CONTAINING GEL COMPOSITION FOR USE ON PESTS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2805615A1

  公开（公告）日：2014-11-26

  Provided is a sustained release preparation comprising an insect pest-targeting gel composition, the preparation being free from leakage or reaction of a volatile substance and being capable of releasing the volatile substance at a constant rate. More specifically, provided is a sustained release preparation comprising a polymer tube and an insect pest-targeting gel composition in the polymer tube, the composition comprising one or more volatile substances and an oil gelling agent, wherein the volatile substances are comprised in an amount of from 70.0 to 99.0% by weight by the insect pest-targeting composition and are released outside of the polymer tube through the polymer tube.

  本发明提供了一种包含害虫靶向凝胶组合物的缓释制剂，该制剂中的挥发性物质不会泄漏或发生反应，并且能够以恒定的速率释放挥发性物质。更具体地说，本发明提供了一种持续释放制剂，包括聚合物管和聚合物管中的害虫靶向凝胶组合物，该组合物包括一种或多种挥发性物质和油胶凝剂，其中挥发性物质的含量为害虫靶向组合物重量的 70.0% 至 99.0%，并通过聚合物管释放到聚合物管外。
• SUSTAINED RELEASE PHEROMONE PREPARATION AND METHOD FOR CONTROLLING INSECT PEST USING THE SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3888460A1

  公开（公告）日：2021-10-06

  There is provided a sustained release pheromone preparation including a mixture containing a first unsaturated aliphatic acetate compound having one carbon-carbon double bond and a second unsaturated aliphatic acetate compound having two carbon-carbon double bonds in a mass ratio of 0.5:99.5 to 99.5:0.5, each compound having the same total number of carbon atoms; and a container containing the mixture therein and including, as a part or whole of the container, a membrane of a linear aliphatic polyester containing one or more selected from the following repeating unit (I); wherein the preparation targets at at least one type of insect pest whose sex pheromone substances contains both of the first and second compounds, or targets at at least one type of insect pest whose sex pheromone substance contains one of them and at least one type of insect pest sex pheromone substance or substances contains the other or both of them.

  本发明提供了一种缓释信息素制剂，包括一种混合物，其中含有具有一个碳碳双键的第一种不饱和脂肪族醋酸酯化合物和具有两个碳碳双键的第二种不饱和脂肪族醋酸酯化合物，其质量比为 0.5:99.5 至 99.5:0.5。5，每种化合物具有相同的碳原子总数；以及 一个容器，其中装有混合物，作为容器的一部分或整体，包括一层线性脂肪族聚酯膜，该膜含有选自以下重复单元 (I) 的一个或多个；其中制剂针对至少一种昆虫害虫，其性信息素物质含有第一和第二种化合物，或针对至少一种昆虫害虫，其性信息素物质含有其中一种，而至少一种昆虫害虫性信息素物质含有另一种或两种化合物。
• Method of producing aliphatic aldehyde compound having terminal conjugated diene structure and intermediate therefor
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10040742B2

  公开（公告）日：2018-08-07

  Provided are a method for producing a terminal conjugated dienal compound without an oxidation reaction and a terminal hydroxyacetal compound useful as an intermediate in the method. More specifically, provided are a method for producing an (E)-dienal compound comprising the steps of: a metalation reaction of an alkynal acetal compound (1) to obtain an organic metal compound (2), an addition reaction of (2) to ethylene oxide to obtain a hydroxyalkynal acetal compound (3), a reduction reaction of (3) to obtain an (E)-hydroxyalkenal acetal compound (4), a functional group conversion reaction of (4) to obtain an (E)-alkenal acetal compound (5) having a leaving group X, an elimination reaction of (5) to obtain an (E)-dienal acetal compound (6), and a hydrolysis reaction of (6) to obtain the (E)-dienal compound (7); and others.

  本发明提供了一种无需氧化反应即可生产端基共轭二烯醛化合物的方法，以及一种可用作该方法中间体的端基羟基乙醛化合物。更具体地说，提供了一种生产(E)-二烯醛化合物的方法，该方法包括以下步骤：炔醛缩醛化合物 (1) 的金属化反应，得到有机金属化合物 (2)； (2) 与环氧乙烷的加成反应，得到羟基炔醛缩醛化合物 (3)； (3) 的还原反应，得到 (E)- 羟基烯醛缩醛化合物 (4)、(4)的官能团转化反应，得到具有离去基团 X 的(E)-烯醛缩醛化合物(5)；(5)的消去反应，得到(E)-二烯醛缩醛化合物(6)；(6)的水解反应，得到(E)-二烯醛化合物(7)；等。
• Insect pest-targeting gel composition and sustained release preparation comprising that
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10244750B2

  公开（公告）日：2019-04-02

  Provided are an insect pest-targeting gel composition causing neither leakage nor reaction of a volatile substance and capable of releasing the volatile substance at a constant rate; and a sustained release preparation including the insect pest-targeting gel composition. More specifically, provided is an insect pest-targeting gel composition including one or more volatile substances and an oil gelling agent, wherein the volatile substance is included in an amount of from 70.0 to 99.0% by weight by the insect pest-targeting gel composition.

  本发明提供了一种害虫靶向凝胶组合物，该组合物不会导致挥发性物质泄漏或反应，并能以恒定速率释放挥发性物质；还提供了一种包含该害虫靶向凝胶组合物的缓释制剂。更具体地说，提供了一种包含一种或多种挥发性物质和油胶凝剂的害虫靶向凝胶组合物，其中挥发性物质的含量为害虫靶向凝胶组合物重量的 70.0% 至 99.0%。