6,13-Bis(2,3,4,5,6-pentafluoroanilino)-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone | 1175631-76-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6,13-Bis(2,3,4,5,6-pentafluoroanilino)-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• 英文别名: 6,13-bis(2,3,4,5,6-pentafluoroanilino)-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• CAS: 1175631-76-1
• 化学式: C₂₆H₆F₁₀N₄O₄
• 分子量: 628.342
• InChiKey: YZWUWLDDEGONKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  98.8
• 氢给体数：
  2
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  1,4,5,8-萘四甲酸酐 、 五氨基氟丙基氢氧吡啶 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以55%的产率得到6,13-Bis(2,3,4,5,6-pentafluoroanilino)-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
  参考文献：
  名称：

  Naphthalene-bis-hydrazimide: radical anions and ICT as new bimodal probes for differential sensing of a library of amines

  摘要：

  报告中介绍了一种胺类双模传感新策略，并首次应用自由基阴离子作为探针，以比色法区分胺类化合物库。

  DOI：

  10.1039/b903097b

文献信息

• Naphthalene-bis-hydrazimide: radical anions and ICT as new bimodal probes for differential sensing of a library of amines
  作者：M. R. Ajayakumar、Pritam Mukhopadhyay

  DOI：10.1039/b903097b

  日期：——

  A new strategy of a bimodal sensing for amines and the first applications of radical anions as probes to colorimetrically differentiate a library of amines is reported.

  报告中介绍了一种胺类双模传感新策略，并首次应用自由基阴离子作为探针，以比色法区分胺类化合物库。
• Single-Electron Transfer Driven Cyanide Sensing: A New Multimodal Approach
  作者：M. R. Ajayakumar、Pritam Mukhopadhyay、Sarita Yadav、Subhasis Ghosh

  DOI：10.1021/ol1008558

  日期：2010.6.4

  A new SET-driven reaction-based strategy is reported for sensing of cyanide with indicators having low LUMO levels. The cyanide-specific reaction produces an air-stable radical anion marker and by virtue of its spin, charge, signal outputs. High selectivity and sensitivity (0.2-16 mu M) were observed when compared to other reducing anions. This new indicator system exhibits regenerability and dip-stick sensing, and fabrication of an electronic sensing device for cyanide is demonstrated.