Tricyclo<8.2.2.2^4,7>hexadeca-4,10-diene | 159591-87-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: Tricyclo<8.2.2.2^4,7>hexadeca-4,10-diene
• 英文别名: Tricyclo[8.2.2.24,7]hexadeca-1(12),6-diene
• CAS: 159591-87-4
• 化学式: C₁₆H₂₄
• 分子量: 216.367
• InChiKey: PHLAOGMPIUDCCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  对二甲苯二聚体 以10%的产率得到
  参考文献：
  名称：

  Lin Shaw-Tao, Wharry Donald L., Yates Robert L., Garti Nissim, Pranata Ju+, J. Org. Chem, 59 (1994) N 23, S 7056-7060

  摘要：

  DOI：

文献信息

• Catalytic Hydrogenation of [2.2]Paracyclophane. Unsaturated Intermediates
  作者：Shaw-Tao Lin、Donald L. Wharry、Robert L. Yates、Nissim Garti、Julianto Pranata、Samuel Siegel、Peter Skrabal

  DOI：10.1021/jo00102a034

  日期：1994.11

  The catalytic hydrogenation of [2.2]paracyclophane (1) was repeated to determine whether the claim that 1 yields an octahydro[2.2]paracyclophane (2) which contains a 1,4-cyclohexadienic structural unit can be substantiated. Decahydro[2.2]paracyclophane and three isomeric dienes (I-III), as well as perhydroparacyclophane, are isolated. The NMR spectra (H-1 and C-13) of the dienes are inconsistent with the earlier proposal, and the failure of the dienes to be aromatized by treatment with DDQ indicates that the trisubstituted double bonds reside in different six-membered rings. Computations of conformational energies aid the assignment of structures to the dienes.
• Lin Shaw-Tao, Wharry Donald L., Yates Robert L., Garti Nissim, Pranata Ju+, J. Org. Chem, 59 (1994) N 23, S 7056-7060
  作者：Lin Shaw-Tao, Wharry Donald L., Yates Robert L., Garti Nissim, Pranata Ju+

  DOI：——

  日期：——