9,10-二氢-9,10-二氧代蒽-1,2-二磺酸 | 103150-81-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 9,10-二氢-9,10-二氧代蒽-1,2-二磺酸
• 中文别名: 蒽醌二磺酸；蒽并醌二磺酸,同质异能素混合物
• 英文名称: anthraquinonedisulphonic acid
• 英文别名: disulfoanthraquinone；Anthraquinone disulfonic acid；anthraquinonedisulfonic acid；Anthrachinon-1,2-disulfonsaeure；9,10-Dihydro-9,10-dioxoanthracenedisulphonic acid；9,10-dioxoanthracene-1,2-disulfonic acid
• CAS: 103150-81-8；53123-81-2
• 化学式: C₁₄H₈O₈S₂
• 分子量: 368.345
• InChiKey: PTKWYSNDTXDBIZ-UHFFFAOYSA-N

物化性质

• 密度：
  1.800±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  160
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  硫酸 、 蒽醌 生成 1-蒽醌磺酸 、 9,10-二氢-9,10-二氧代蒽-1,2-二磺酸
  参考文献：
  名称：

  Lauer, Journal fur praktische Chemie (Leipzig 1954), 1931, vol. <2> 130, p. 185 - 225

  摘要：

  DOI：

文献信息

• [EN] PREPARATION OF BETA QUINACRIDONE PIGMENTS<br/>[FR] PREPARATION DE PIGMENTS DE BETA QUINACRIDONE
  申请人：CIBA SC HOLDING AG

  公开号：WO2004048479A1

  公开（公告）日：2004-06-10

  A novel method for the preparation of a beta quinacridone pigment is described by the oxidation of 6,13-dihydroquinacridone in the presence of polyvinyl pyrrolidone, a catalyst and optionally a particulate quinacridone and/or a particle growth inhibitor using hydrogen peroxide as the oxidant.

  描述了一种制备β喹诺啉颜料的新方法，该方法通过在聚乙烯吡咯烷酮存在下氧化6,13-二氢喹诺啉，使用过氧化氢作为氧化剂，并可选地使用颗粒喹诺啉和/或颗粒生长抑制剂作为催化剂。
• Process for converting natural gas into higher alkanes
  申请人：BP OIL INTERNATIONAL LIMITED

  公开号：EP1939159A1

  公开（公告）日：2008-07-02

  The present invention relates to a process for converting natural gas into higher alkanes having at least 3 carbon atoms (C3+), preferably at least 4 carbon atoms (C4+). It comprises a stage (1) for separating the components of the natural gas so as to isolate (a) methane and (b) alkanes having at least 2 carbon atoms (C2+), a stage (2) for non-oxidative methane coupling, comprising contacting the methane thus isolated with a metal catalyst (C1) capable of producing, in contact with alkane, reactions involving the splitting and recombining of carbon-carbon and/or carbon-hydrogen and/or carbon-metal bonds, so as to form a mixture (M1) comprising ethane and hydrogen, optionally a stage (3) comprising separating and isolating ethane from the mixture (M1), a stage (4) for ethane metathesis, comprising contacting the ethane isolated in stage (3) or the mixture (M1) obtained in stage (2) and preferably the alkanes (C2+) isolated in stage (1) with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of carbon-carbon and/or carbon-hydrogen and/or carbon-metal bonds, so as to form a mixture (M2) comprising higher alkanes (C3+), preferably (C4+) and methane, and a stage (5) comprising separating and isolating said higher alkanes from the mixture (M2). Methane can be separated and isolated in stage (5) and preferably recycled in stage (2).

  本发明涉及一种将天然气转化为至少具有3个碳原子（C3+），优选至少具有4个碳原子（C4+）的高碳烷烃的过程。它包括以下阶段：（1）分离天然气的组分以隔离（a）甲烷和（b）至少具有2个碳原子（C2+）的烷烃；（2）非氧化甲烷偶联阶段，包括将隔离的甲烷与能够在碱金属催化剂（C1）的作用下产生涉及碳-碳和/或碳-氢和/或碳-金属键的裂解和重组反应的烷烃接触，从而形成包含乙烷和氢的混合物（M1），可选地，包括（3）阶段，其中分离并隔离来自混合物（M1）的乙烷；（4）乙烷醚交换阶段，包括将在阶段（3）中隔离的乙烷或在阶段（2）中获得的混合物（M1）以及优选在阶段（1）中隔离的烷烃（C2+）与能够在碱金属催化剂（C2）的作用下产生涉及碳-碳和/或碳-氢和/或碳-金属键的裂解和重组反应的烷烃接触，从而形成包含较高碳烷烃（C3+），优选（C4+）和甲烷的混合物（M2）；（5）阶段，其中分离并隔离所述较高碳烷烃从混合物（M2）中。甲烷可以在阶段（5）中分离并隔离，优选在阶段（2）中回收。
• Process for converting methane into liquid alkane mixtures
  申请人：BP OIL INTERNATIONAL LIMITED

  公开号：EP2022772A1

  公开（公告）日：2009-02-11

  The present invention relates to a process for converting methane into a liquid mixture of (C3+) alkanes having 3 carbon atoms and more, preferably (C4+) alkanes having 4 carbon atoms and more, especially (C5+) alkanes having 5 carbon atoms and more. It comprises a stage (1) comprising converting methane into acetylene, performed by submitting methane to a thermal cracking reaction, so as to form a reaction mixture (M1) comprising acetylene and hydrogen, a stage (2) comprising converting acetylene into ethane, performed by contacting the acetylene or the reaction mixture (M1) previously obtained with hydrogen in the presence of a hydrogenation catalyst (C1), so as to form a reaction mixture (M2) comprising ethane, a stage (3) comprising simultaneous ethane self- and cross-metathesis reactions performed by contacting the ethane or the reaction mixture (M2) previously obtained with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, so as to form a reaction mixture (M3) comprising methane and a mixture of the (C3+), preferably the (C4+), especially the (C5+) alkanes, and a stage (4) comprising fractionating the reaction mixture (M3) so as to separate and to isolate said mixture in liquid form. Preferably, the methane is also separated in stage (4) and recycled into stage (1) for methane conversion into acetylene

  本发明涉及一种将甲烷转化为液态混合物的过程，该混合物包含有3个或更多碳原子的（C3+）烷烃，优选是含有4个或更多碳原子的（C4+）烷烃，特别是含有5个或更多碳原子的（C5+）烷烃。该过程包括以下阶段：阶段（1）包括将甲烷转化为乙炔，通过将甲烷提交给热裂解反应来实现，从而形成包含乙炔和氢的反应混合物（M1）；阶段（2）包括将乙炔转化为乙烷，通过在氢气存在下将乙炔或先前获得的反应混合物（M1）与氢气接触，并在氢化催化剂（C1）的存在下进行，从而形成包含乙烷的反应混合物（M2）；阶段（3）包括通过将乙烷或先前获得的反应混合物（M2）与能够在与烷烃接触时产生涉及C-C和/或C-H和/或C-金属键的裂解和重组反应的金属催化剂（C2）接触，同时进行乙烷自身和交叉甲醚反应，从而形成包含甲烷和（C3+）烷烃混合物的反应混合物（M3），优选是（C4+），特别是（C5+）烷烃；阶段（4）包括对反应混合物（M3）进行分馏，以便将所述混合物分离并以液态形式分离。优选地，甲烷也在阶段（4）中分离并回收到阶段（1）用于将甲烷转化为乙炔。
• METHOD OF DERIVATISING AN ANALYTE FOR SUBSEQUENT DETECTION THROUGH A NUCLEIC ACID BASED SENSOR
  申请人：ULMER JENS

  公开号：US20100089769A1

  公开（公告）日：2010-04-15

  A method of derivatising an analyte for subsequent detection through a nucleic acid based sensor and a sensor based thereon.

  一种将待测物衍生化以便通过基于核酸的传感器进行后续检测的方法，以及基于该方法的传感器。
• [EN] SYNTHESIS OF SMALL PARTICLE SIZE QUINACRIDONE OF BETA CRYSTAL PHASE<br/>[FR] SYNTHESE D'UNE PHASE CRISTALLINE BETA DE QUINACRIDONE DE FAIBLE GRANULOMETRIE
  申请人：CIBA SC HOLDING AG

  公开号：WO2004067642A1

  公开（公告）日：2004-08-12

  The present invention relates to a process for the synthesis of beta-quinacridone by oxidation in the presence of selected additives that promote the formation of the desired crystal phase and particle size.

  本发明涉及一种在选定的添加剂存在下进行氧化合成β-喹诺酮的过程，这些添加剂促进所需的晶体相和粒度的形成。