4-Methyl-3-cyclohexenylmethyl-4-methyl-3-cyclohexencarboxylat; 4-Methyl-cyclohex-3-en-carbonsaeure-(4-methyl-cyclohex-3-enyl-methylester) | 94573-03-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-Methyl-3-cyclohexenylmethyl-4-methyl-3-cyclohexencarboxylat; 4-Methyl-cyclohex-3-en-carbonsaeure-(4-methyl-cyclohex-3-enyl-methylester)
• 英文别名: 4-Methyl-cyclohex-3-enecarboxylic acid 4-methyl-cyclohex-3-enylmethyl ester；(4-methylcyclohex-3-en-1-yl)methyl 4-methylcyclohex-3-ene-1-carboxylate
• CAS: 94573-03-2
• 化学式: C₁₆H₂₄O₂
• 分子量: 248.365
• InChiKey: GETRETOMMCEVTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  丙烯醛 、 天然橡胶 在 aluminum trisphenoxide polymer 作用下， 以 甲苯 为溶剂， 反应 11.0h， 以54%的产率得到4-Methyl-3-cyclohexenylmethyl-4-methyl-3-cyclohexencarboxylat; 4-Methyl-cyclohex-3-en-carbonsaeure-(4-methyl-cyclohex-3-enyl-methylester)
  参考文献：
  名称：

  Aluminum Trisphenoxide Polymer as a Lewis Acidic, Solid Catalyst

  摘要：

  DOI：

  10.1055/s-1999-2523

文献信息

• PROCESS FOR THE EPOXIDATION OF OLEFINS
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160083360A1

  公开（公告）日：2016-03-24

  The subject invention is related to a process for the epoxidation of olefin with peroxide, comprising reacting peroxide with olefin in the presence a solvent, wherein the solvent has Hansen Solubility Parameters (HSPs) of δ T,solvent and δ H,solvent and the epoxide product has Hansen Solubility Parameters (HSPs) of δ T,product and δ H,product , and wherein: δ T,product −6≦δ T,solvent ≦δ T,product +6, and δ H,product −6≦δ H,solvent .

  该发明涉及一种过氧化物与烯烃进行环氧化反应的方法，包括在溶剂存在的情况下，将过氧化物与烯烃反应，其中溶剂具有Hansen溶解度参数（HSPs）δT，溶剂和δH，溶剂，环氧产物具有Hansen溶解度参数（HSPs）δT，产物和δH，产物，并且满足以下条件：δT，产物-6≦δT，溶剂≦δT，产物+6，以及δH，产物-6≦δH，溶剂。
• Active energy ray curable composition
  申请人：Konica Minolta Holdings, Inc.

  公开号：US20040167315A1

  公开（公告）日：2004-08-26

  An active energy ray curable composition containing an epoxy compound having at least one oxirane ring having substituents at positions &agr; and &bgr; of the oxirane ring.

  一种活性能量射线可固化组合物，其中包含至少具有一个环氧环的氧化环己烷化合物，其在环氧环的α和β位置具有取代基。
• ACTIVE ENERGY RAY CURABLE COMPOSITION
  申请人：SASA Nobumasa

  公开号：US20060264529A1

  公开（公告）日：2006-11-23

  An active energy ray curable composition containing an epoxy compound having at least one oxirane ring having substituents at positions α and β of the oxirane ring.

  一种活性能量射线可固化的组合物，包含至少具有一个环氧基团的环氧化合物，其在环氧基团的α和β位置具有取代基。
• CONTINUOUS PROCESS OF OLEFINIC EPOXIDATION BY SUPPORTED HETEROPOLY ACID
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160177023A1

  公开（公告）日：2016-06-23

  The subject invention is related to a continuous process of epoxidation of an olefin with supported heteropoly acid catalyst, which does not involve the use of an additive(s). The subject invention separates the products and oxides through a continuous process to reduce backmixing, thereby achieving an efficacy equal to that of a process involving the use of an additive. By excluding additives from the process, the subject invention has a lower cost, and avoids the need for additional wastewater treatment since no alkali metal or alkali earth metal compound is formed during the reaction. Moreover, the continuous process of the invention is also beneficial in industrial manufacturing.
• US9499505B2
  申请人：——

  公开号：US9499505B2

  公开（公告）日：2016-11-22