2,2-bis(5-isocyanatomethyl-2-furyl)propane | 88768-56-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2,2-bis(5-isocyanatomethyl-2-furyl)propane
• 英文别名: 2,2-bis(5-isocyanatomethyl-furan-2-yl)propane；2,2'-(Propane-2,2-diyl)bis[5-(isocyanatomethyl)furan]；2-(isocyanatomethyl)-5-[2-[5-(isocyanatomethyl)furan-2-yl]propan-2-yl]furan
• CAS: 88768-56-3
• 化学式: C₁₅H₁₄N₂O₄
• 分子量: 286.287
• InChiKey: ODCDLJJEBDKLSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  85.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  (5,5’-(propane-2,2-diyl)bis(furan-5,2-diyl))dimethanamine 、 氯甲酸三氯甲酯 在 甲烷 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以75.8%的产率得到2,2-bis(5-isocyanatomethyl-2-furyl)propane
  参考文献：
  名称：

  Isocyanate intermediates. II. Trichloromethyl chloroformate - A convenient reagent for the Preparation of Diisocyanates with benzene or furan rings

  摘要：

  DOI：

  10.1002/prac.19923340218

文献信息

• Polyurethane prepolymer and aqueous polyurethane dispersion
  申请人：Stichting Dutch Polymer Institute

  公开号：EP2360196A1

  公开（公告）日：2011-08-24

  The invention relates to a polyurethane prepolymer prepared by reacting a mixture comprising a short-chain renewable diisocyanate and a long-chain renewable diisocyanate and one or more diols. The short-chain renewable diisocyanate has at most 10 atoms and at most two ether group between the two isocyanate groups, and has at most 16 carbon atoms in the molecule. The long-chain renewable diisocyanate has either more than 12 atoms or more than ether group between the two isocyanate groups, or has more than 20 carbon atoms in the molecule. The invention also relates to an aqueous dispersion comprising the polyurethane prepolymer and a coating obtainable from the prepolymer.

  本发明涉及一种聚氨酯预聚物，其制备方法是使由短链可再生二异氰酸酯和长链可再生二异氰酸酯以及一种或多种二元醇组成的混合物发生反应。短链可再生二异氰酸酯最多有 10 个原子，两个异氰酸酯基团之间最多有两个醚基，分子中最多有 16 个碳原子。长链可再生二异氰酸酯有超过 12 个原子，或两个异氰酸酯基团之间有多个醚基，或分子中有超过 20 个碳原子。本发明还涉及一种包含聚氨酯预聚物的水性分散体和一种由该预聚物制成的涂层。
• Water dispersible polyamide building blocks
  申请人：Lubrizol Advanced Materials, Inc.

  公开号：US10266651B2

  公开（公告）日：2019-04-23

  Water dispersible polyamides having carboxylic acid groups are disclosed. These are made by reacting polycarboxyl is acids or anhydrides thereof with amine containing monomer or an amide terminated polyamide under reaction conditions such that a few of the carboxylic acid groups are residual and can promote dispersion in water. These polyamides after dispersion can be chain extended to higher molecular weight polymers or can be terminally functionalized with reactive groups such as isocyanate, epoxy, vinyl, acetoacetonate, or silanol groups. Composites and hybrids of these polyamides with vinyl polymers are also disclosed and claimed.

  本发明公开了具有羧酸基团的水分散性聚酰胺。这些聚酰胺是通过聚羧酸或其酸酐与含胺单体或酰胺末端聚酰胺在反应条件下进行反应而制成的，反应条件使少数羧酸基团残留并可促进在水中的分散。分散后的这些聚酰胺可以链延伸为更高分子量的聚合物，也可以用异氰酸酯、环氧树脂、乙烯基、乙酰丙酮酸酯或硅醇基团等活性基团进行端基官能化。此外，还公开了这些聚酰胺与乙烯基聚合物的复合材料和混合物。
• Aqueous primer coating composition and use
  申请人：HERCULES LLC

  公开号：US10301478B2

  公开（公告）日：2019-05-28

  An aqueous primer coating composition to a substrate comprises an aqueous cationic polyurethane and an aqueous polymer of oxazoline or N-vinylpyrrolidone. Also disclosed is a method applying the coating composition to the substrate and an electrophotographical printing medium coated with the coating composition.

  一种用于基材的水性底漆涂料组合物，包括一种水性阳离子聚氨酯和一种水性噁唑啉或 N-乙烯基吡咯烷酮聚合物。还公开了一种将涂层组合物涂到基底上的方法和涂有涂层组合物的电致发光印刷介质。
• Waterborne polyamide and their chain extension with isocyanates to form cationic waterborne polyureas dispersions
  申请人：Lubrizol Advanced Materials, Inc.

  公开号：US10640616B2

  公开（公告）日：2020-05-05

  An improved process for forming polyamide dispersions in water utilizing carbon dioxide to facilitate dispersion of the polyamide is disclosed. The polyamides are generally below 30,000 or 40,000 g/mole molecular weight when dispersed, but can be chain extended with polyfunctional species such as polyisocyanates after dispersion. The dispersions are useful in coatings, adhesives, and inks. Composites and hybrids of these other polyamides with vinyl polymers are also disclosed and claimed.

  本发明公开了一种在水中形成聚酰胺分散体的改进工艺，利用二氧化碳促进聚酰胺的分散。分散后的聚酰胺分子量一般低于 30,000 或 40,000 克/摩尔，但在分散后可以用多官能团（如多异氰酸酯）进行链延伸。分散体可用于涂料、粘合剂和油墨。此外，还公开了这些其他聚酰胺与乙烯基聚合物的复合材料和混合物。
• Guanylurea alcohol phosphates and their use as reactants in polyurethane and epoxy resin applications
  申请人：Lubrizol Advanced Materials, Inc.

  公开号：US10662275B2

  公开（公告）日：2020-05-26

  Guanylurea alcohol phosphate salts are disclosed. Flame retardant thermoplastic and thermoset polymers can be made by incorporating said guanylurea alcohol phosphate salts into polymers and these polymers have improved properties over similar thermoplastic or thermoset polymers where guanylurea phosphate salts are added as flame retardant dispersions to said polymer. Flame retardant polyurethane foams where the guanylurea alcohol phosphate salts have been incorporated into the polyurethane are a particularly preferred embodiment.

  本发明公开了番脲醇磷酸酯盐。阻燃热塑性聚合物和热固性聚合物可通过将所述番酰脲醇磷酸酯盐掺入聚合物中制成，与将番酰脲磷酸酯盐作为阻燃分散体添加到所述聚合物中的类似热塑性聚合物或热固性聚合物相比，这些聚合物具有更好的性能。阻燃聚氨酯泡沫是一种特别优选的实施方案，其中已将番脲醇磷酸酯盐加入到聚氨酯中。