Tricylc[3.3.1.1(3,3,5-triacetic acid | 500885-89-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Tricylc[3.3.1.1(3,3,5-triacetic acid
• 英文别名: 2-[3,5-bis(carboxymethyl)-1-adamantyl]acetic acid
• CAS: 500885-89-2
• 化学式: C₁₆H₂₂O₆
• 分子量: 310.347
• InChiKey: JHROBECYBTUGNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  甲醇 、 Tricylc[3.3.1.1(3,3,5-triacetic acid 在 硫酸 作用下， 反应 20.0h， 以1.42 g的产率得到trimethyl 2,2',2"-(adamantane-1,3,5-triyl)triacetate
  参考文献：
  名称：

  Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design

  摘要：

  A series of new adamantane and diamantane hydrazides was synthesized and coupled with organo-functionalized Sn/S clusters of the general type [(RSn4S6)-Sn-I] (R-I = CMe2CH2COMe) to form diamondoid-decorated Sn/S dusters. The new ligand precursors as well as the resulting hybrid compounds were analyzed by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction, and first insights were gained in the installation of sterically highly demanding and at the same time rigid mono-, di-, and trifunctionalized diamondoid ligands on tetrelchalcogenide cages.

  DOI：

  10.1021/om500014z
• 作为产物：
  描述：

  2,2',2"-(adamantane-1,3,5-triyl)triacetonitrile 在 potassium hydroxide 作用下， 以 二乙二醇 为溶剂， 反应 24.0h， 生成 Tricylc[3.3.1.1(3,3,5-triacetic acid
  参考文献：
  名称：

  Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design

  摘要：

  A series of new adamantane and diamantane hydrazides was synthesized and coupled with organo-functionalized Sn/S clusters of the general type [(RSn4S6)-Sn-I] (R-I = CMe2CH2COMe) to form diamondoid-decorated Sn/S dusters. The new ligand precursors as well as the resulting hybrid compounds were analyzed by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction, and first insights were gained in the installation of sterically highly demanding and at the same time rigid mono-, di-, and trifunctionalized diamondoid ligands on tetrelchalcogenide cages.

  DOI：

  10.1021/om500014z

文献信息

• ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, RESIN COMPOSITION CONTAINING THE ADAMANTANE DERIVATIVE AND USE THEREOF
  申请人：Okada Yasunari

  公开号：US20100093947A1

  公开（公告）日：2010-04-15

  Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.
• US8022151B2
  申请人：——

  公开号：US8022151B2

  公开（公告）日：2011-09-20
• Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design
  作者：Beatrix E. K. Barth、Boryslav A. Tkachenko、Jens P. Eußner、Peter R. Schreiner、Stefanie Dehnen

  DOI：10.1021/om500014z

  日期：2014.4.14

  A series of new adamantane and diamantane hydrazides was synthesized and coupled with organo-functionalized Sn/S clusters of the general type [(RSn4S6)-Sn-I] (R-I = CMe2CH2COMe) to form diamondoid-decorated Sn/S dusters. The new ligand precursors as well as the resulting hybrid compounds were analyzed by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction, and first insights were gained in the installation of sterically highly demanding and at the same time rigid mono-, di-, and trifunctionalized diamondoid ligands on tetrelchalcogenide cages.