[2-(Diphenyl-phosphinoyl)-ethyl]-trimethyl-ammonium; iodide | 84543-05-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [2-(Diphenyl-phosphinoyl)-ethyl]-trimethyl-ammonium; iodide
• 英文别名: 2-(Diphenylphosphoryl)-N,N,N-trimethylethan-1-aminium iodide；2-diphenylphosphorylethyl(trimethyl)azanium;iodide
• CAS: 84543-05-5
• 化学式: C₁₇H₂₃NOP*I
• 分子量: 415.254
• InChiKey: IOBSVSPNXVTMLV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.29
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [2-(Diphenyl-phosphinoyl)-ethyl]-trimethyl-ammonium; iodide 在 三氯硅烷 作用下， 以51%的产率得到2-(diphenylphosphino)-N,N,N-trimethylethanaminium iodide
  参考文献：
  名称：

  Dicarbonylbis[2-(diphenylphosphino)-N,N-dimethyethanamine]-bis-[μ-(2-methyl)-2-propanethiolato]dirhodium and dicarbonylbis[2-(diphenylphosphino)-N,N,N-trimethylethanaminium]-bis-[μ-(2-methyl)-2-propanethiolato]dirhodium tetraphenylborate. Their syntheses, characterization and application as hydrogenation catalyst

  摘要：

  [Rh(CO)(2)(mu-S-t-Bu)](2) (1) reacts with [Ph(2)PCH(2)CH(2)NMe(3)](+)[BPh(4)](-) (2) as well as with the neutral Ph(2)PCH(2)CH(2)NMe(2) (4) to give the water soluble cationic dinuclear rhodium complex [Rh(CO)(Ph(2)PCH(2)CH(2)NMe(3))(mu-S-t-BU)](2+)(2)[BPh(4)](2-)(2) (3) and the neutral dinuclear complex [Rh(CO)(Ph(2)PCH(2)CH(2)NMe(2))(mu-S-t-Bu)](2) (5), respectively. Both are highly active catalysts for hydrogenation. The NMR spectra of the new compounds and the X-ray crystal structure analysis of 5 are reported and discussed.

  DOI：

  10.1016/0022-328x(94)05015-4
• 作为产物：
  描述：

  N,N-dimethyl-2-diphenylphosphinoethylamine 在 双氧水 作用下， 以 丙酮 为溶剂， 反应 5.0h， 生成 [2-(Diphenyl-phosphinoyl)-ethyl]-trimethyl-ammonium; iodide
  参考文献：
  名称：

  Crystal and molecular structure of [(C6H5)2P(=0)(CH2CH2N(CH3)3 +][I−]

  摘要：

  DOI：

  10.1007/bf01664651

文献信息

• Dicarbonylbis[2-(diphenylphosphino)-N,N-dimethyethanamine]-bis-[μ-(2-methyl)-2-propanethiolato]dirhodium and dicarbonylbis[2-(diphenylphosphino)-N,N,N-trimethylethanaminium]-bis-[μ-(2-methyl)-2-propanethiolato]dirhodium tetraphenylborate. Their syntheses, characterization and application as hydrogenation catalyst
  作者：Herbert Schumann、Holger Hemling、Nurit Goren、Jochanan Blum

  DOI：10.1016/0022-328x(94)05015-4

  日期：1995.1

  [Rh(CO)(2)(mu-S-t-Bu)](2) (1) reacts with [Ph(2)PCH(2)CH(2)NMe(3)](+)[BPh(4)](-) (2) as well as with the neutral Ph(2)PCH(2)CH(2)NMe(2) (4) to give the water soluble cationic dinuclear rhodium complex [Rh(CO)(Ph(2)PCH(2)CH(2)NMe(3))(mu-S-t-BU)](2+)(2)[BPh(4)](2-)(2) (3) and the neutral dinuclear complex [Rh(CO)(Ph(2)PCH(2)CH(2)NMe(2))(mu-S-t-Bu)](2) (5), respectively. Both are highly active catalysts for hydrogenation. The NMR spectra of the new compounds and the X-ray crystal structure analysis of 5 are reported and discussed.
• Crystal and molecular structure of [(C6H5)2P(=0)(CH2CH2N(CH3)3 +][I−]
  作者：Melvyn Rowen Churchill、Ronald F. See、Robert L. Rominger、Jim D. Atwood

  DOI：10.1007/bf01664651

  日期：1996.11