N-(4-vinyl)benzyl ethylenediamine | 106673-75-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4-vinyl)benzyl ethylenediamine
• 英文别名: VBEDA；1,2-Ethanediamine, N-[(4-ethenylphenyl)methyl]-；N'-[(4-ethenylphenyl)methyl]ethane-1,2-diamine
• CAS: 106673-75-0
• 化学式: C₁₁H₁₆N₂
• 分子量: 176.261
• InChiKey: WLRJEEHPOZXDMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 N-(4-vinyl)benzyl ethylenediamine 以 甲醇 、 乙腈 为溶剂， 生成 [Cu(N-(4-vinyl)benzyl ethylenediamine)2][ClO4]2
  参考文献：
  名称：

  Cu(II)-containing cross-linked polymers for the hydrolysis of 4-nitrophenyl phosphate

  摘要：

  The protonation constants of N-(4-vinyl)benzyl ethylenediamine (L1), 1-(4-vinyl)benzyl dielhylenetriamine (L2), 4-(4-vinyl)benzyl diethylenetriamine (L3), and the stability constants of their Cu(II) and Zn(II) complexes have been potentiometrically determined. The crystal structures of [Cu(L1)(2)][ClO4](2) and [CuL2(NO3)(2)]. CH3CO2C2H5 are reported. [Cu(L1)(2)][ClO4](2) crystallizes in the monoclinic system with space group P2(1)/c, having lattice parameters a = 12.48(2), b = 12.062(16), c = 9.188(15) Angstrom, beta = 97.46(7)degrees, and Z = 2. [CuL2(NO3)(2)]. CH3CO2C2H5 crystallizes in the monoclinic system with space group P2(1)/n, having lattice parameters a = 10.239(2), b = 9.177(1), c = 24.096(4) Angstrom, beta = 95.99(1)degrees, and Z = 2. Kinetic studies show that the Cu(II)-containing cross-linked polymers made from incorporating [Cu(L1)(2)]X-2 and [CuL3]X-2 (X = ClO4-, NO3-) catalyze the hydrolysis of 4-nitrophenyl phosphate with first-order rate constants 1.33 x 10(-5) and 1.04 x 10(-6) s(-1), respectively, at 55 degreesC and pH 8.5. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00241-3
• 作为产物：
  描述：

  4-氯甲基苯乙烯 、 乙二胺 以 二氯甲烷 为溶剂， 反应 26.0h， 生成 N-(4-vinyl)benzyl ethylenediamine
  参考文献：
  名称：

  Adsorption and desorption of calcium ions by temperature swing with copolymer of thermosensitive and chelating components grafted on porous ethylene vinyl acetate disk

  摘要：

  A novel adsorbent composed of a copolymer of a thermosensitive component, N-isopropylacrylamide (NIPAM), and a chelating component, N-(4-vinyl)benzylethylenediamine (VBEDA), was developed, and the adsorption and desorption behaviors of Ca2+ ions were investigated. The copolymer of NIPAM and VBEDA was grafted onto the pore surfaces of a porous ethylene vinyl acetate (EVA) disk by a plasma-initiated polymerization method. The copolymerization ratios of VBEDA were 3 and 6 mol%. Although a hydrophilic component, VBEDA, was copolymerized with NIPAM, the transition temperature of the copolymer was almost the same as that of poly(NIPAM). The permeability through the polymer-grafted EVA disk strongly depended on the temperature. It was quite low below the transition temperature of the grafted polymer, and increased drastically when the temperature exceeded the transition temperature. The polymer-grafted EVA disk adsorbed Ca2+ ions at low temperatures and the adsorption amount decreased significantly when the temperature exceeded the transition temperature of the grafted polymer, and repeated adsorption and desorption by temperature swings were possible. Furthermore, it was suggested that one Ca2+ ion was captured by three VBEDA groups, and this multi-point coordination bond was destroyed by heating as a result of shrinkage of the grafted poly(NIPAM-co-VBEDA) chains, leading to desorption of Ca2+ ion. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2013.09.006

文献信息

• SILVER- AND COPPER-CHELATING IONIC LIQUIDS, POLYMERS, AND GELS, AND USES THEREOF
  申请人：Massachusetts Institute of Technology

  公开号：US20190327964A1

  公开（公告）日：2019-10-31

  Disclosed are methods of antimicrobial treatment using ionic liquids (ILs), IL complexes, polymers comprising ILs, and polymers comprising neutral ethylene diamine compounds. Also disclosed are novel IL complexes, polymers comprising ILs, and polymers comprising neutral ethylene diamine compounds.

  本发明涉及使用离子液体（ILs）、IL复合物、含有ILs的聚合物以及含有中性乙二胺化合物的聚合物进行抗微生物处理的方法。同时还公开了新型IL复合物、含有ILs的聚合物以及含有中性乙二胺化合物的聚合物。
• CHELATING MONOMERS AND POLYMERS
  申请人：Zhang Hongmin

  公开号：US20070254378A1

  公开（公告）日：2007-11-01

  This invention provides chelating moieties that comprise an aryl group. Monomers that include the chelating moieties can be polymerized into chelating polymers. Chelating polymers are useful to chelate metals. Chelating polymers in the form of metal chelates are useful for binding analytes, such as polypeptides that comprise histidine residues. Chelating polymers can be includes in articles such as chips and chromatographic materials.

  本发明提供了包含芳基的螯合基团。包括螯合基团的单体可以聚合成螯合聚合物。螯合聚合物可用于螯合金属。以金属螯合物形式的螯合聚合物可用于结合分析物，例如包含组氨酸残基的多肽。螯合聚合物可以包含在芯片和色谱材料等物品中。
• Silver- and copper-chelating ionic liquids, polymers, and gels, and uses thereof
  申请人：Massachusetts Institute of Technology

  公开号：US11026419B2

  公开（公告）日：2021-06-08

  Disclosed are methods of antimicrobial treatment using ionic liquids (ILs), IL complexes, polymers comprising ILs, and polymers comprising neutral ethylene diamine compounds. Also disclosed are novel IL complexes, polymers comprising ILs, and polymers comprising neutral ethylene diamine compounds.

  公开了使用离子液体（IL）、IL 复合物、包含 IL 的聚合物以及包含中性乙二胺化合物的聚合物进行抗菌处理的方法。还公开了新型离子液体复合物、包含离子液体的聚合物和包含中性乙二胺化合物的聚合物。
• Systems and methods incorporating ionic liquids for electrochemically mediated capturing of Lewis acid gases
  申请人：Massachusetts Institute of Technology

  公开号：US11298649B2

  公开（公告）日：2022-04-12

  The present invention generally relates to methods and systems for capturing a Lewis acid gas (e.g., CO2). In some embodiments, the methods and systems utilize an ionic liquid incorporated into one or more electrochemical cells.

  本发明一般涉及捕集路易斯酸气体（如二氧化碳）的方法和系统。在某些实施例中，这些方法和系统利用离子液体与一个或多个电化学电池结合。
• Immobilized metalchelate complexes for catalysis and decontamination of pesticides and chemical warfare nerve-agents
  申请人：——

  公开号：US20030054949A1

  公开（公告）日：2003-03-20

  The present invention relates to the preparation of metal chelate complexes immobilized on a support, immobilized metal chelate complexes and methods of using the supports and immobilized metal chelate complexes for the adsorption and/or hydrolysis of phosphate esters. More specifically, processes for the preparation of immobilized metal chelate complexes by attachment of metal chelate complexes to solids, polymers, micelles, liposomes, tubules and other self-organized polymolecular associations immobilized metal chelate complexes made by such processes and use of the supports and immobilized metal chelate complexes for the adsorption and/or hydrolysis of phosphate ester group containing compounds such as chemical warfare nerve agents and pesticides, are disclosed. The present invention provides the ability to efficiently decontaminate phosphate ester compounds under a wide range of conditions in a practical and cost-effective manner.

  本发明涉及制备固定在载体上的金属螯合物、固定化金属螯合物以及使用载体和固定化金属螯合物吸附和/或水解磷酸酯的方法。更具体地说，本发明公开了通过将金属螯合物附着到固体、聚合物、胶束、脂质体、小管和其他自组织多分子联合体上制备固定化金属螯合物的工艺，以及使用这些支撑物和固定化金属螯合物吸附和/或水解含有磷酸酯基团的化合物（如化学战神经毒剂和杀虫剂）的方法。本发明提供了在各种条件下以实用和具有成本效益的方式有效净化磷酸酯化合物的能力。