tris(methallyl)phosphine oxide | 94037-62-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: tris(methallyl)phosphine oxide
• 英文别名: trimethallyl-phosphine oxide；Tris-(2-methyl-allyl)-phosphinoxyd；Trimethallyl-phosphinoxid；3-[Bis(2-methylprop-2-enyl)phosphoryl]-2-methylprop-1-ene
• CAS: 94037-62-4
• 化学式: C₁₂H₂₁OP
• 分子量: 212.272
• InChiKey: PLQXTFMLOBXCPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tris(methallyl)phosphine oxide 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 20.0h， 以31%的产率得到tris(2-methyl-2,3-epoxypropyl)phosphine oxide
  参考文献：
  名称：

  Sosnovsky; Lukszo, European Journal of Medicinal Chemistry, 1984, vol. 19, # 4, p. 331 - 340

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Methylallylmagnesium Chloride 在 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以17%的产率得到tris(methallyl)phosphine oxide
  参考文献：
  名称：

  Sosnovsky; Lukszo, European Journal of Medicinal Chemistry, 1984, vol. 19, # 4, p. 331 - 340

  摘要：

  DOI：

文献信息

• Jones et al., Journal of the Chemical Society, 1947, p. 1446,1449
  作者：Jones et al.

  DOI：——

  日期：——
• SOSNOVSKY, G.;LUKSZO, J., EUR. J. MED. CHEM., 1984, 19, N 4, 331-340
  作者：SOSNOVSKY, G.、LUKSZO, J.

  DOI：——

  日期：——
• METHODS OF FORMING A NANOCRYSTAL
  申请人：Ye Enyi

  公开号：US20110033368A1

  公开（公告）日：2011-02-10

  Methods of forming a nanocrystal are provided. The nanocrystal may be a binary nanocrystal of general formula M1A or of general formula M1O, a ternary nanocrystal of general formula M1M2A, of general formula M1AB or of general formula M1M2O or a quaternary nanocrystal of general formula M1M2AB. M1 is a metal of Groups II-IV, Group VII or Group VIII of the PSE. A is an element of Group VI or Group V of the PSE. O is oxygen. A homogenous reaction mixture in a non-polar solvent of low boiling point is formed, that includes a metal precursor containing the metal M1 and, where applicable M2. For an oxygen containing nanocrystal the metal precursor contains an oxygen donor. Where applicable, A is also included in the homogenous reaction mixture. The homogenous reaction mixture is under elevated pressure brought to an elevated temperature that is suitable for forming a nanocrystal.
• [EN] METHODS OF FORMING A NANOCRYSTAL<br/>[FR] PROCÉDÉS DE FORMATION D'UN NANOCRISTAL
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2009045177A1

  公开（公告）日：2009-04-09

  Methods of forming a nanocrystal are provided. The nanocrystal may be a binary nanocrystal of general formula M1A or of general formula M1O, a ternary nanocrystal of general formula M1M2A, of general formula M1AB or of general formula M1M2O or a quaternary nanocrystal of general formula M1M2AB. M1 is a metal of Groups II - IV, Group VII or Group VIII of the PSE. A is an element of Group VI or Group V of the PSE. O is oxygen. A homogenous reaction mixture in a non-polar solvent of low boiling point is formed, that includes a metal precursor containing the metal M1 and, where applicable M2. For an oxygen containing nanocrystal the metal precursor contains an oxygen donor. Where applicable, A is also included in the homogenous reaction mixture. The homogenous reaction mixture is under elevated pressure brought to an elevated temperature that is suitable for forming a nanocrystal.