1-Chloro-3-(4-ethenylphenyl)benzene | 1276023-43-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Chloro-3-(4-ethenylphenyl)benzene
• CAS: 1276023-43-8
• 化学式: C₁₄H₁₁Cl
• 分子量: 214.694
• InChiKey: SLBHDBUVBUJKOQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-Chloro-3-(4-ethenylphenyl)benzene 在 四丁基氟化铵 、 戴斯-马丁氧化剂 、 9-硼双环[3.3.1]壬烷 、 三氟乙酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 7.1h， 生成 N-(7-chloro-4a-methyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)-4-methylbenzenesulfonamide
  参考文献：
  名称：

  手性布朗斯台德酸催化对映选择性多烯环化

  摘要：

  描述了由BINOL衍生的手性N-磷酰胺（NPA）催化的亚胺质子化引发的第一个对映选择性多烯环化反应。NPA的亚胺离子和手性抗衡阴离子之间形成的离子对在控制整体转化的立体化学方面起着重要作用。该策略为包含三个连续立体中心的稠合三环框架提供了一种高效方法，该框架在天然产物中广泛发现。此外，（NP）-紫杉醇的首个催化不对称全合成反应是通过NPA催化的对映选择性多烯环化反应完成的，这是构建三环核的关键步骤，具有优异的收率和对映选择性。

  DOI：

  10.1002/anie.201711603

文献信息

• Graft copolymer and process for producing the same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0490269A1

  公开（公告）日：1992-06-17

  There is provided a process for producing a styrenic graft copolymer which comprises coplymerizing a styrenic monomer and a styrenic monomer having a hydrocarbon radical with an unsaturated bond in the presence of a catalyst comprising as primary ingredient (A) a transition metal compound and (B) a contact product of an organoaluminum compound and a condensation agent or (C) a compound which produces an ionic complex by reacting with the above-mentioned transition metal compound and subsequently graft polymerizing an ethylenically unsaturated monomer onto the resultant styrenic copolymer. The above-described styrenic graft copolymer is greatly improved in terms of compatibility, adhesivity, coatability and wettability while preserving heat resistance and chemical resistance thereof, and thus effective as a variety of constructional materials and compatibilizing agents. Furthermore, the composition or multi-layer material comprising the above-mentioned styrenic graft copolymer is widely utilized in a variety of application field including film, sheet, especially stampable sheet, container, packaging material, automobile parts, electrical and electronic parts, etc.

  提供了一种生产苯乙烯接枝共聚物的工艺，该工艺包括在催化剂存在下，使苯乙烯单体和具有不饱和键烃基的苯乙烯单体共聚，催化剂的主要成分包括(A)过渡金属化合物和(B)有机铝化合物与缩合剂的接触产物或(C)通过与上述过渡金属化合物反应产生离子络合物的化合物，然后将乙烯基不饱和单体接枝聚合到生成的苯乙烯共聚物上。上述过渡金属化合物反应生成离子络合物的化合物，然后将乙烯不饱和单体接枝聚合到生成的苯乙烯共聚物上。 上述苯乙烯接枝共聚物在保持其耐热性和耐化学性的同时，在相容性、粘合性、涂覆性和润湿性方面得到了极大的改善，因此可以有效地用作各种建筑材料和相容剂。此外，由上述苯乙烯接枝共聚物组成的组合物或多层材料可广泛应用于各种应用领域，包括薄膜、片材，尤其是可冲压片材、容器、包装材料、汽车零件、电子电气零件等。
• STYRENIC COPOLYMER AND PRODUCTION THEREOF
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0511407A1

  公开（公告）日：1992-11-04

  A styrenic copolymer having at least one structural unit represented by general formula (I) and either a structural unit represented by general formula (II) or a structural unit represented by general formula (IX), the content of the unit (II) or the unit (IX) being 0.01 to 99.9 mole %. In these formulae each symbol is as defined in the specification. This copolymer is highly syndiotactic in the stereoregularity of the chain composed of the structural units (I) and is excellent in the adhesion and compatibility with other resins.

  一种苯乙烯共聚物，至少有一个结构单元由通式(I)和一个结构单元由通式(II)或一个结构单元由通式(IX)表示，单元(II)或单元(IX)的含量为 0.01 至 99.9 摩尔%。在这些式子中，每个符号都与说明书中的定义相同。这种共聚物由结构单元（I）组成的链具有高度的立体均匀性，与其他树脂的粘合性和相容性极佳。
• Graft copolymer, process for production thereof and resin composition containing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0559108A1

  公开（公告）日：1993-09-08

  There are disclosed a graft copolymer formed by grafting a styrenic monomer onto a high polymer having double bonds in the side chain to constitute highly syndiotactic polystyrenic chain as the graft component, the graft copolymer having a content of graft component of 0.005 to 99% by weight and a reduced viscosity of 0.01 to 30 dl/g as measured at a concentration of 0.05 g/dl in 1,2,4-trichlorobenzene at 135°C or a melt index of 0.001 to 500 g/10 minutes as measured at 300°C under a load of 2.16 kg; a process for efficiently producing the above graft copolymer using a catalyst comprising specific components; and a resin composition comprising the above graft copolymer, a highly syndiotactic styrenic polymer or other thermoplastic resin and, when necessary, an inorganic or organic filler. The above graft copolymer and resin composition are excellent in resistance to heat and chemicals, electrical properties, moldability, compatibility, impact resistance, etc.

  本发明公开了一种接枝共聚物，该接枝共聚物是通过将苯乙烯单体接枝到侧链中具有双键的高聚物上而形成的，作为接枝组分，该接枝共聚物的接枝组分含量为 0.005 至 99%（重量百分比），在浓度为 0.05克/分升，在135℃的1,2,4-三氯苯中测得，或在300℃、载荷为2.16公斤的条件下测得，熔融指数为0.001至500克/10分钟；使用由特定组分组成的催化剂高效生产上述接枝共聚物的工艺；以及由上述接枝共聚物、高对位苯乙烯聚合物或其他热塑性树脂以及必要时无机或有机填料组成的树脂组合物。上述接枝共聚物和树脂组合物具有优异的耐热性、耐化学性、电气性能、成型性、相容性、抗冲击性等。
• Styrenic polymer, process for producing same and multi-layer material comprising same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0570931A2

  公开（公告）日：1993-11-24

  There are disclosed a styrenic polymer of highly syndiotactic configuration which has a functional group at a ceasing terminal of a styrenic monomer, and a reduced viscosity of 0.01 to 20 dl/g (0.05 g/dl in 1,2,4-trichlorobenzene at 135°C); a multi-layer material comprising at least one layer composed of the above styrenic polymer; a multi-layer material comprising at least one layer composed of a resin composition containing (A) the above styrenic polymer and (B) at least one member selected from a thermoplastic resin, an inorganic filler and an organic filler; and a process for producing the above styrenic polymer which comprises polymerising a styrenic monomer in the presence of a specific catalyst and subjecting the resultant polymer to terminal-functionalizing treatment. The above-disclosed styrenic polymer is markedly improved in compatibility and adhesiveness and is expected to find a wide range of applications requiring adhesiveness with metals, etc.

  本发明公开了一种苯乙烯单体的终止端具有官能团、粘度降低至 0.01 至 20 dl/g （在 135°C 的 1，2，4-三氯苯中为 0.05克/分升(在135℃的1,2,4-三氯苯中)；一种多层材料，包括至少一层由上述苯乙烯聚合物组成的多层材料；一种多层材料，包括至少一层由树脂组合物组成的多层材料，该树脂组合物含有(A)上述苯乙烯聚合物和(B)至少一种选自热塑性树脂、无机填料和有机填料的成分；以及一种生产上述苯乙烯聚合物的工艺，该工艺包括在特定催化剂存在下聚合苯乙烯单体，并将所得聚合物进行末端官能化处理。上述公开的苯乙烯聚合物在兼容性和粘合性方面有明显改善，有望广泛应用于需要与金属等粘合的领域。
• Styrenic block copolymer and process for producing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0570932A2

  公开（公告）日：1993-11-24

  There are disclosed a styrenic block copolymer having a reduced viscosity of 0.01 to 20 dl/g (0.05 g/l in 1,2,4-trichlorobenzene at 135°C) which comprises highly syndiotactic styrenic-polymer segments and 10⁻⁴ to 10 mol% of heteroatom-containing styrenic polymer segments; a resin composition comprising the above styrenic block copolymer and a thermoplastic resin, an inorganic filler or an organic filler; a multi-layer material comprising at least one layer composed of the above styrenic block copolymer or the above resin composition; and a process for producing the above styrenic block copolymer which comprises polymerizing a styrenic monomer in the presence of a specific catalyst and adding a heteroatom-containing styrenic monomer to successively proceed with copolymerizaiton reaction. The above-disclosed styrenic block copolymer and the resin composition exhibit excellent compatibiity and adhesivenesss, and the multi-layer material is expected to find a wide range of applications in automobile parts, electrical and electronic parts as well as film, sheet, etc.

  本发明公开了一种苯乙烯嵌段共聚物，其粘度降低至 0.01 至 20 dl/g （在 135°C 的 1，2，4-三氯苯中为 0.05 g/l in 1,2,4-trichlorobenzene at 135°C)的苯乙烯嵌段共聚物，它由高度齐聚的苯乙烯聚合物段和 10-⁴ 至 10 摩尔%的含杂原子的苯乙烯聚合物段组成；一种树脂组合物，它由上述苯乙烯嵌段共聚物和一种热塑性树脂、一种无机填料或一种有机填料组成；一种多层材料，其中至少一层由上述苯乙烯嵌段共聚物或上述树脂组合物构成；以及一种生产上述苯乙烯嵌段共聚物的工艺，该工艺包括在特定催化剂存在下聚合苯乙烯单体，并加入含杂原子的苯乙烯单体以连续进行共聚反应。上述苯乙烯嵌段共聚物和树脂组合物具有优异的相容性和粘合性，多层材料有望广泛应用于汽车部件、电子电气部件以及薄膜、板材等领域。