o-(Methylthio)-phenyl ethyl sulphide | 83500-73-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: o-(Methylthio)-phenyl ethyl sulphide
• 英文别名: 1-(ethylthio)-2-(methylthio)benzene；1-Ethylsulfanyl-2-methylsulfanylbenzene
• CAS: 83500-73-6
• 化学式: C₉H₁₂S₂
• 分子量: 184.326
• InChiKey: JHLHNKXNEGQVHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  o-(Methylthio)-phenyl ethyl sulphide 在 双氧水 作用下， 以 溶剂黄146 为溶剂， 生成 1-(乙基磺酰基)-2-(甲基磺酰基)苯
  参考文献：
  名称：

  Selective Dealkylation of Bis[alkylthio]benzenes: Elimination-Substitution Competition with Methoxide and Methanethiolate Ions in Hexamethylphosphoric Triamide

  摘要：

  DOI：

  10.1055/s-1982-29844
• 作为产物：
  描述：

  o-(Isopropylthio)-phenyl methyl sulphide 、 碘乙烷 在 sodium methylate 作用下， 生成 o-(Methylthio)-phenyl ethyl sulphide
  参考文献：
  名称：

  Selective Dealkylation of Bis[alkylthio]benzenes: Elimination-Substitution Competition with Methoxide and Methanethiolate Ions in Hexamethylphosphoric Triamide

  摘要：

  DOI：

  10.1055/s-1982-29844

文献信息

• Photosensitive resin composition, light-shielding color filter and production process therefor, and image sensor
  申请人：FUJIFILM Corporation

  公开号：EP2105792A1

  公开（公告）日：2009-09-30

  A photosensitive resin composition is provided that includes at least (A) titanium black, (B) two or more types of polymerizable compounds, (C) a resin, (D) a photopolymerization initiator, and (E) an organic solvent. There are also provided a light-shielding color filter formed by using the photosensitive resin composition, and a process for producing a light-shielding color filter, the process including a step of coating a substrate with the photosensitive resin composition, a step of imagewise exposing, and a step of developing to form a pattern. Furthermore, there is provided an image sensor that includes the light-shielding color filter.

  提供了一种光敏树脂组合物，它至少包括 (A) 钛黑、(B) 两种或两种以上的可聚合化合物、(C) 树脂、(D) 光聚合引发剂和 (E) 有机溶剂。此外，还提供了一种通过使用感光树脂组合物形成的遮光彩色滤光片，以及一种生产遮光彩色滤光片的工艺，该工艺包括用感光树脂组合物涂覆基底的步骤、图像曝光步骤，以及显影以形成图案的步骤。此外，还提供了一种包括遮光彩色滤光片的图像传感器。
• Metallation reactions. XXVI. α,α′-Dimetallation of 1,2-bis(methylthiobenzene)
  作者：M.G. Cabiddu、S. Cabiddu、E. Cadoni、S. De Montis、C. Fattuoni、S. Melis、F. Sotgiu

  DOI：10.1016/s0040-4020(99)00873-x

  日期：1999.12

  alpha,alpha'-Dimetallation of bis(methylthio)benzene (1) with butyllithium or with superbases gives 2 with good yield. This species allows the simultaneous introduction of two electrophiles in thiomethyl groups. Alternatively it was possible to functionalize these groups with two different electrophiles by two successive one-flask monometallations. Compound 2 rise to gives heterocyclic compounds. (C) 1999 Elsevier Science Ltd. All rights reserved.
• TIECCO, M.;TINGOLI, M.;TESTAFERRI, L.;CHIANELLI, D.;MAIOLO, F., SYNTHESIS, BRD, 1982, N 6, 479-480
  作者：TIECCO, M.、TINGOLI, M.、TESTAFERRI, L.、CHIANELLI, D.、MAIOLO, F.

  DOI：——

  日期：——
• PHOTOSENSITIVE RESIN COMPOSITION, LIGHT-SHIELDING COLOR FILTER AND PRODUCTION PROCESS THEREFOR, AND IMAGE SENSOR
  申请人：FUJIMORI Toru

  公开号：US20090246650A1

  公开（公告）日：2009-10-01

  A photosensitive resin composition is provided that includes at least (A) titanium black, (B) two or more types of polymerizable compounds, (C) a resin, (D) a photopolymerization initiator, and (E) an organic solvent. There are also provided a light-shielding color filter formed by using the photosensitive resin composition, and a process for producing a light-shielding color filter, the process including a step of coating a substrate with the photosensitive resin composition, a step of imagewise exposing, and a step of developing to form a pattern. Furthermore, there is provided an image sensor that includes the light-shielding color filter.
• US8110324B2
  申请人：——

  公开号：US8110324B2

  公开（公告）日：2012-02-07