tetrakis(4'-hydroxybiphenyl-4-yl)silane | 930598-99-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrakis(4'-hydroxybiphenyl-4-yl)silane
• 英文别名: 4-[4-Tris[4-(4-hydroxyphenyl)phenyl]silylphenyl]phenol
• CAS: 930598-99-5
• 化学式: C₄₈H₃₆O₄Si
• 分子量: 704.897
• InChiKey: XNIBXNNVJUGGNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.55
• 重原子数：
  53
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  溴化氰 、 tetrakis(4'-hydroxybiphenyl-4-yl)silane 在 三乙胺 作用下， 以 丙酮 为溶剂， 反应 2.0h， 以72%的产率得到tetrakis(4'-cyanatobiphenyl-4-yl)silane
  参考文献：
  名称：

  Microporous Cyanate Resins: Synthesis, Porous Structure, and Correlations with Gas and Vapor Adsorptions

  摘要：

  Three silicon and nitrogen-centered cyanate monomers tetrakis(4-cyanatophenyl)silane, tetrakis(4-cyanato-biphenyl)silane, and tris(4-cyanatobiphenyl)amine were designed and synthesized, which were then polymerized via thermal cyclotrimerization reaction to create highly porous cyanate resin networks with systematically varied nodes and linking struts. The chemical structures of monomers and polymers were confirmed by H-1 NMR, FTIR, solid-state C-13 CP/MAS NMR spectra, and elemental analysis. The products are amorphous with 5% weight-loss temperatures over 428 degrees C. The results based on N-2 and CO2 adsorption isotherms show that the pores in these polymers mainly locate in the microporous region, and the BET surface areas are up to 960 m(2) g(-1), which is the highest value for the porous cyanate resin reported to date. The nitrogen- and oxygen-rich characteristics of cyanate resins lead to the networks strong affinity for CO2 and thereby high CO2 adsorption capacity of 11.1 wt % at 273 K and 1.0 bar. The adsorption behaviors of H-2, CO2, benzene, n-hexane, and water vapors were investigated by correlating with the chemical composition and porosity parameters of the networks as well as the physicochemical nature of adsorbates.

  DOI：

  10.1021/ma3008652
• 作为产物：
  描述：

  四(4-溴苯基)硅烷 在 四(三苯基膦)钯 、 三溴化硼 、 potassium carbonate 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 水 为溶剂， 反应 48.5h， 生成 tetrakis(4'-hydroxybiphenyl-4-yl)silane
  参考文献：
  名称：

  Microporous Cyanate Resins: Synthesis, Porous Structure, and Correlations with Gas and Vapor Adsorptions

  摘要：

  Three silicon and nitrogen-centered cyanate monomers tetrakis(4-cyanatophenyl)silane, tetrakis(4-cyanato-biphenyl)silane, and tris(4-cyanatobiphenyl)amine were designed and synthesized, which were then polymerized via thermal cyclotrimerization reaction to create highly porous cyanate resin networks with systematically varied nodes and linking struts. The chemical structures of monomers and polymers were confirmed by H-1 NMR, FTIR, solid-state C-13 CP/MAS NMR spectra, and elemental analysis. The products are amorphous with 5% weight-loss temperatures over 428 degrees C. The results based on N-2 and CO2 adsorption isotherms show that the pores in these polymers mainly locate in the microporous region, and the BET surface areas are up to 960 m(2) g(-1), which is the highest value for the porous cyanate resin reported to date. The nitrogen- and oxygen-rich characteristics of cyanate resins lead to the networks strong affinity for CO2 and thereby high CO2 adsorption capacity of 11.1 wt % at 273 K and 1.0 bar. The adsorption behaviors of H-2, CO2, benzene, n-hexane, and water vapors were investigated by correlating with the chemical composition and porosity parameters of the networks as well as the physicochemical nature of adsorbates.

  DOI：

  10.1021/ma3008652

文献信息

• Microporous Cyanate Resins: Synthesis, Porous Structure, and Correlations with Gas and Vapor Adsorptions
  作者：Hao Yu、Changjiang Shen、Mengzhe Tian、Jing Qu、Zhonggang Wang

  DOI：10.1021/ma3008652

  日期：2012.6.26

  Three silicon and nitrogen-centered cyanate monomers tetrakis(4-cyanatophenyl)silane, tetrakis(4-cyanato-biphenyl)silane, and tris(4-cyanatobiphenyl)amine were designed and synthesized, which were then polymerized via thermal cyclotrimerization reaction to create highly porous cyanate resin networks with systematically varied nodes and linking struts. The chemical structures of monomers and polymers were confirmed by H-1 NMR, FTIR, solid-state C-13 CP/MAS NMR spectra, and elemental analysis. The products are amorphous with 5% weight-loss temperatures over 428 degrees C. The results based on N-2 and CO2 adsorption isotherms show that the pores in these polymers mainly locate in the microporous region, and the BET surface areas are up to 960 m(2) g(-1), which is the highest value for the porous cyanate resin reported to date. The nitrogen- and oxygen-rich characteristics of cyanate resins lead to the networks strong affinity for CO2 and thereby high CO2 adsorption capacity of 11.1 wt % at 273 K and 1.0 bar. The adsorption behaviors of H-2, CO2, benzene, n-hexane, and water vapors were investigated by correlating with the chemical composition and porosity parameters of the networks as well as the physicochemical nature of adsorbates.