N,2,6-三甲基苯胺盐酸盐 | 70522-62-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N,2,6-三甲基苯胺盐酸盐
• 英文名称: N,2,6-trimethylaniline hydrochloride
• 英文别名: N,2,6-trimethylaniline;hydrochloride
• CAS: 70522-62-2
• 化学式: C₉H₁₃N*ClH
• 分子量: 171.67
• InChiKey: GIWCHKXBXYCETK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.77
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  12
• 氢给体数：
  2
• 氢受体数：
  1

安全信息

• 海关编码：
  2921430090

反应信息

• 作为反应物：
  描述：

  N,2,6-三甲基苯胺盐酸盐 、 光气 在 苯 、 正己烷 作用下， 以 苯 为溶剂， 反应 1.0h， 以to give 2,6-dimethylphenyl-N-methylcarbamoyl chloride (m.p. 79°-80° C.)的产率得到N-methyl-N-2,6-dimethylphenylcarbamoylchloride
  参考文献：
  名称：

  Amidinourea local anesthetics

  摘要：

  一种通过给患者注射氨基脲类物质来产生局部麻醉作用的方法。

  公开号：

  US04147804A1
• 作为产物：
  描述：

  N-(2,6-二甲基苯)甲酰胺 、 盐酸 在 ice 、 水 、 sodium hydroxide 、 乙醚 、 Sodium sulfate-III 、 异丙醇 、 甲醇 作用下， 以 ice methanol 、 四氢呋喃 为溶剂， 反应 24.0h， 以methanol to give N,2,6-trimethylaniline hydrochloride (m.p. 255-257 dec.)的产率得到N,2,6-三甲基苯胺盐酸盐
  参考文献：
  名称：

  Method for the treatment of arrhythmia

  摘要：

  一种通过给予氨基脲类化合物治疗心律失常的方法。

  公开号：

  US04178387A1

文献信息

• Synthetic Routes to, Transformations of, and Rather Surprising Stabilities of (<i>N</i>-Methyl-<i>N</i>-phenylcarbamoyl)sulfenyl Chloride, ((<i>N</i>-Methyl-<i>N</i>-phenylcarbamoyl)dithio)carbonyl Chloride, and Related Compounds
  作者：Alex M. Schrader、Alayne L. Schroll、George Barany

  DOI：10.1021/jo201329n

  日期：2011.10.7

  The title compound classes, (carbamoyl)sulfenyl chlorides and ((carbamoyl)dithio)carbonyl chlorides, have been implicated previously as unstable, albeit trappable, intermediates in organosulfur chemistry. The present work reports for each of these functional groups: (i) several routes to prepare it in the N-methylaniline family; (ii) its direct structural characterization by several spectroscopic techniques;

  先前已经将标题化合物类别（（氨基甲酰基）亚磺酰氯和（（氨基甲酰基）二硫代）羰基氯）认为是有机硫化学中不稳定的，尽管可捕集的中间体。本工作报告了这些官能团的每一个：（i）在N-甲基苯胺家族中制备它的几种途径；（ii）通过几种光谱技术对其结构进行直接表征；（iii）其相当意外的稳定性以及其分解时的最终命运；（iv）一系列进一步的化学转化，产生高度稳定的衍生物，每个衍生物都经过全面表征。进行了相关的动力学和机理实验，包括一些被对甲基和2,6-二甲基取代的N-甲基苯胺。鉴于标题化合物可以分离并且相对稳定，它们可以在制备用于半胱氨酸的巯基功能的硫解和/或光不稳定保护基中以及在开发新的蛋白质合成和修饰试剂中找到应用。
• Olefin polymerisation catalysts and processes for producing olefin polymers
  申请人：TOSOH CORPORATION

  公开号：EP0849292A1

  公开（公告）日：1998-06-24

  Catalysts for olefin polymerization which consist essentially of a transition metal compound, a modified clay compound and an organic aluminum compound, wherein the modified clay compound comprises a reaction product of a clay mineral and a proton acid salt of a specific amine compound, as well as a method of polymerizing olefins using such catalysts. It is possible thereby to obtain olefin polymers with high productivity and low ash content.

  烯烃聚合催化剂，主要由过渡金属化合物、改性粘土化合物和有机铝化合物组成，其中改性粘土化合物包括粘土矿物和特定胺化合物的质子酸盐的反应产物，以及使用这种催化剂聚合烯烃的方法。由此可以获得生产率高、灰分含量低的烯烃聚合物。
• ETHYLENE POLYMER, CATALYST FOR PRODUCTION OF ETHYLENE POLYMER, AND PROCESS FOR PRODUCTION OF ETHYLENE POLYMER
  申请人：Tosoh Corporation

  公开号：EP1964860B1

  公开（公告）日：2017-07-05
• ETHYLENE POLYMER, CATALYST FOR ETHYLENE POLYMER PRODUCTION, AND METHOD FOR PRODUCING ETHYLENE POLYMER
  申请人：Yamada Satoru

  公开号：US20090137755A1

  公开（公告）日：2009-05-28

  An object of the present invention relates to provide an ethylene polymer having excellent mechanical strength and excellent molding processability in a wide molding processing temperature range. The invention relates to use an ethylene polymer comprising a repeating unit derived from ethylene, or a repeating unit derived from ethylene and a repeating unit derived from a C 3-8 α-olefin, the ethylene polymer being satisfied with the following (A) to (F). (A) Density (d(kg/m 3 )) is from 910 to 970, (B) MFR(g/10 min)) is from 0.01 to 50, (C) terminal vinyl number is 0.2 or less per 1,000 carbon atoms, (D) melt strength (MS 160 (mN)) measured at 160° C. and MFR are satisfied with MS 160 >90−130×log(MFR), (E) melt strength (MS 190 (mN)) measured at 190° C. and MS 160 are satisfied with MS 160 /MS 190 <1.8, and (F) fluidized activation energy (E a (kJ/mol)) and d are satisfied with 127−0.107 d
• ETHYLENE-alpha-OLEFIN COPOLYMER AND MOLDED ARTICLE
  申请人：Nozue Yoshinobu

  公开号：US20130005930A1

  公开（公告）日：2013-01-03

  An ethylene-α-olefin copolymer, wherein the ethylene-α-olefin copolymer has a density of 860 to 950 kg/m 3 and a melt flow rate of 0.01 to 100 g/10 min, wherein in a molecular weight curve measured by gel permeation chromatography, the molecular weight of the copolymer providing the highest peak exists within the range of 10,000 to 20,000, wherein the height of the peak at a molecular weight of 177,000 is 5 to 30% where the height of the highest peak is 100%, wherein a characteristic relaxation time of the copolymer satisfies a relation represented by formula (1), and wherein the ethylene-α-olefin copolymer exhibits more than one melt peak observed by a differential scanning calorimeter. 40.2×MFR −0.606 <τ<71.8×MFR −0.175 (1)