6-bromohexanoic acid 1-vinylallyl ester | 426820-30-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 6-bromohexanoic acid 1-vinylallyl ester
• 英文别名: Penta-1,4-dien-3-yl 6-bromohexanoate
• CAS: 426820-30-6
• 化学式: C₁₁H₁₇BrO₂
• 分子量: 261.159
• InChiKey: CIZWXSJPRXFJDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5,5'-bis(4-hydroxyphenyl)-2,2'-bithiophene 、 6-bromohexanoic acid 1-vinylallyl ester 在 potassium carbonate 、 potassium iodide 作用下， 以 DMF (N,N-dimethyl-formamide) 为溶剂， 以41%的产率得到6-[4-(5'-[5-(1-vinyl-allyloxycarbonyl)-pentyloxy]-phenyl-[2,2']bithiophenyl-5-yl)-phenoxy]-hexanoic acid 1-vinyl-allyl ester
  参考文献：
  名称：

  [EN] REACTIVE MESOGENIC CHARGE TRANSPORT COMPOUNDS CONTAINING AT LEAST TWO THIOPHENE GROUPS
  [FR] COMPOSES MESOGENES REACTIFS A PROPRIETES DE TRANSPORT DE CHARGE

  摘要：

  公开号：

  WO2005080369A3
• 作为产物：
  描述：

  1,4-戊二烯-3-醇 、 6-溴己酸 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 生成 6-bromohexanoic acid 1-vinylallyl ester
  参考文献：
  名称：

  Electroluminescent Nematic Polymer Networks with Polarised Emission

  摘要：

  Electroluminescence with a polarisation ratio of 12:1 from a uniformly aligned nematic network is reported. Diene photo-active end-groups were used, which polymerise by a selective cyclisation reaction. Surface alignment was achieved for the first time using a doped polymer photoalignment layer, oriented by exposure to polarised UV light. Threshold voltages between 2 V and 8 V were found and a brightness of 90 cd m(-2) was obtained. Both the PL and EL intensities were higher after photochemical crosslinking.

  DOI：

  10.1080/10587250108025021

文献信息

• Electron-transporting and photopolymerisable liquid crystals
  作者：Panos Vlachos、Stephen M. Kelly、Bassam Mansoor、Mary O’Neill

  DOI：10.1039/b200526c

  日期：2002.4.11

  The synthesis of a novel, photopolymerisable liquid crystal (reactive mesogen) with a high mobility of electrons in the smectic C phase at room temperature is reported for the first time as a potential charge transport layer for OLEDs.

  首次报道了一种新型光聚合液晶（反应性介晶）的合成，该液晶在室温下在近晶 C 相中具有高电子迁移率，可作为 OLED 的潜在电荷传输层。
• Light emitting polymer
  申请人：O'Neill Mary

  公开号：US20050096404A1

  公开（公告）日：2005-05-05

  There is provided a process for forming a light emitting polymer comprising photopolymerization of a reactive mesogen having an endgroup which is susceptible to photopolymerization e.g. by a radical polymerization process. Also provided are methods for using the light emitter in displays, backlights, electronic apparatus and security viewers.

  提供了一种形成发光聚合物的过程，包括通过光引发聚合反应，使用具有易于光引发聚合末端基团的反应性介质，例如通过自由基聚合反应进行。还提供了使用该发光聚合物在显示器、背光、电子设备和安全观察器中的方法。
• Liquid crystal alignment layer
  申请人：——

  公开号：US20030021913A1

  公开（公告）日：2003-01-30

  A liquid crystal alignment layer that consists of an alignment layer and a transport material chemically bound to the alignment layer. Also, methods for forming the liquid crystal alignment layer, and displays for electronic apparatus incorporating the liquid crystal alignment layer.

  一种液晶取向层，由取向层和化学上与取向层结合的传输材料组成。此外，还提供了形成液晶取向层的方法以及包含液晶取向层的电子设备显示器。
• Light emitter for a display
  申请人：——

  公开号：US20030027017A1

  公开（公告）日：2003-02-06

  A light emitter for a display consisting of a photoalignment layer. A light emitting polymer is photoaligned on the photoalignment layer. Also, methods for forming the light emitter and use of the light emitter in displays, backlights, electronic apparatus and security viewers.

  一种用于显示器的光发射器，由光定向层组成。光发射聚合物通过光定向层进行光定向。此外，还提供了制备光发射器的方法以及在显示器、背光、电子设备和安全观察器中使用光发射器的方法。
• Reactive mesogenic charge transport compounds
  申请人：Heeney Martin

  公开号：US20050184274A1

  公开（公告）日：2005-08-25

  The invention relates to new reactive mesogenic compounds with charge transport properties comprising at least two thiophene groups, their use as semiconductors or charge transport materials, in optical, electro-optical or electronic devices like for example liquid crystal displays, optical films, organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as RFID tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices, and to a field effect transistor, light emitting device or ID tag comprising the reactive mesogenic charge transport compounds.

  本发明涉及一种新的具有电荷传输性质的反应性介向化合物，包括至少两个噻吩基团，其用作半导体或电荷传输材料，用于光学、电光或电子设备，例如液晶显示器、光学薄膜、有机场效应晶体管（FET或OFET）用于薄膜晶体管液晶显示器和集成电路器件，例如RFID标签、平面显示器中的电致发光器件以及光伏和传感器器件，以及包括反应性介向电荷传输化合物的场效应晶体管、发光器件或ID标签。