1-N,3-N,5-N-tris[1,3-bis[(1-heptyltriazol-4-yl)methoxy]-2-[(1-heptyltriazol-4-yl)methoxymethyl]propan-2-yl]benzene-1,3,5-tricarboxamide | 1443767-12-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-N,3-N,5-N-tris[1,3-bis[(1-heptyltriazol-4-yl)methoxy]-2-[(1-heptyltriazol-4-yl)methoxymethyl]propan-2-yl]benzene-1,3,5-tricarboxamide
• CAS: 1443767-12-1
• 化学式: C₁₁₁H₁₈₆N₃₀O₁₂
• 分子量: 2132.89
• InChiKey: NOMWSXNYWCMXKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17
• 重原子数：
  153
• 可旋转键数：
  96
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  447
• 氢给体数：
  3
• 氢受体数：
  30

反应信息

• 作为产物：
  描述：

  1-azidoheptane 、 trimesoyl chloride 在 copper(ll) sulfate pentahydrate 、 sodium ascorbate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 12.0h， 以96%的产率得到1-N,3-N,5-N-tris[1,3-bis[(1-heptyltriazol-4-yl)methoxy]-2-[(1-heptyltriazol-4-yl)methoxymethyl]propan-2-yl]benzene-1,3,5-tricarboxamide
  参考文献：
  名称：

  Synthesis and Characterization of Some Novel Glycodendrimers and N-alkyldendrimers with Amide Core and Triazole Functionality through Click Chemistry

  摘要：

  The syntheses of various types of 1,2,3-triazole-based dendrimers 1-4 with sugar pyranosylazides and N-ethyl and N-heptylazides as a surface unit and benzene-1,3,5-tricorboxlyic amide as core unit through click chemistry approach are described. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.

  DOI：

  10.1080/00397911.2012.696304

文献信息

• Synthesis and Characterization of Some Novel Glycodendrimers and <i>N</i>-alkyldendrimers with Amide Core and Triazole Functionality through Click Chemistry
  作者：Perumal Rajakumar、Ramasamy Anandhan

  DOI：10.1080/00397911.2012.696304

  日期：2013.8.18

  The syntheses of various types of 1,2,3-triazole-based dendrimers 1-4 with sugar pyranosylazides and N-ethyl and N-heptylazides as a surface unit and benzene-1,3,5-tricorboxlyic amide as core unit through click chemistry approach are described. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.