N,N,N'-三(3-氨基丙基)乙二胺 | 79506-61-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N,N'-三(3-氨基丙基)乙二胺
• 英文名称: N,N,N'-tris(3-aminopropyl)ethylenediamine
• 英文别名: N'-[2-[bis(3-aminopropyl)amino]ethyl]propane-1,3-diamine
• CAS: 79506-61-9
• 化学式: C₁₁H₂₉N₅
• 分子量: 231.385
• InChiKey: YCSRPJMGDRNYCY-UHFFFAOYSA-N

物化性质

• 沸点：
  348.4±10.0 °C(Predicted)
• 密度：
  0.975±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.9
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  93.3
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3,3'-(乙烯二亚胺)二丙腈 、 N,N,N'-tris(2-cyanoethyl)-1,2-ethylenediamine 、 3-[(2-氨乙基)氨]基]丙烯腈 在 lithium hydroxide 氢气 作用下， 以 水 为溶剂， 70.0~80.0 ℃ 、2.75 MPa 条件下， 生成 N,N,N'-三(3-氨基丙基)乙二胺 、 N-(2-乙氨基)-1,3-丙二胺 、 N,N-二(3-氨丙基)乙基乙胺
  参考文献：
  名称：

  Selective Manufacture of N,N'-BIS(Cyanoethyl)-1,2-Ethylenediamine and N, N'-BIS(3-aminopropyl)-1,2-Ethylenediamine

  摘要：

  一种制备N,N'-双(3-氨丙基)-1,2-乙二胺的方法，包括在大约2:1的摩尔比下反应丙烯腈和乙二胺，以制备N,N'-双(氰乙基)-1,2-乙二胺反应产物，并对反应产物进行氢化，改进提高反应选择性以制备N,N'-双(2-氰乙基)-乙二胺和N,N'-双(3-氨丙基)-1,2-乙二胺的方法，包括在总反应物质的基础上加入2-30重量％的水，使丙烯腈和乙二胺在水的存在下进行反应。

  公开号：

  US20080194857A1

文献信息

• BENZYLATED MANNICH BASE CURING AGENTS, COMPOSITIONS, AND METHODS
  申请人：EVONIK DEGUSSA GMBH

  公开号：US20170240691A1

  公开（公告）日：2017-08-24

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R 1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R 2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein R A is substituted or unsubstituted benzyl; R B is each independently R A , or a hydrogen atom, or a group selected from C 1 -C 16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C 2 -C 10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  含有苄基曼尼希碱基组分的组合物和固化剂。所述苄基曼尼希碱基组分包括以下反应产物：(a)至少具有一个取代基的取代酚化合物，所述取代基的公式为(I)：其中R1各自独立地是具有1到4个碳原子的线性或支链烷基，R2是氢、甲基、乙基或苯基；(b)苄基化的聚烯烃聚醚胺(II)：其中RA是取代或未取代的苄基，RB各自独立地是RA或氢原子，或选自C1-C16线性、环状和支链烷基、烯基和烷基芳基基团；X、Y和Z各自独立地选自C2-C10烷基和环状烷基基团；y是0到7的整数，z是0到4的整数；可选地，(c)多功能胺。还公开了胺-环氧组合物和由这些组合物制成的物品。
• NITROGEN-CONTAINING HETEROCYCLIC EPOXY CURING AGENTS, COMPOSITIONS AND METHODS
  申请人：Air Products and Chemicals, Inc.

  公开号：US20170137562A1

  公开（公告）日：2017-05-18

  Amine-epoxy curing agents are disclosed including at least one saturated heterocyclic compound having two nitrogen heteroatoms according to formula (I) and at least one saturated fused bicyclic heterocyclic compound having three nitrogen heteroatoms according to formula (II): wherein X is independently selected from a hydrogen atom, a linear or branched C 1 to C 4 alkyl group and a substituted or un-substituted phenyl group, Y 1 is a direct bond or a divalent polyethylene polyamine group having 1 to 8 nitrogen atoms or a divalent polyethylene polyamine derivative having 1 to 8 nitrogen atoms, Y 2 is a direct bond or a divalent polyethylene polyamine group having 1 to 7 nitrogen atoms and R is independently a hydrogen atom or a group selected from C 1 -C 8 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups.

  本发明揭示了一种氨基-环氧固化剂，其中包括至少一个具有两个氮杂原子的饱和杂环化合物，其符合公式（I）；以及至少一个具有三个氮杂原子的饱和融合双环杂环化合物，其符合公式（II）：其中X独立地选自氢原子、线性或支链C1到C4烷基基团和取代或未取代的苯基基团，Y1是直接键或具有1到8个氮原子的二价聚乙烯多胺基团或具有1到8个氮原子的二价聚乙烯多胺衍生物，Y2是直接键或具有1到7个氮原子的二价聚乙烯多胺基团，R独立地是氢原子或从C1-C8线性、环状和支链烷基、烯基和烷基苯基基团中选择的基团。
• [EN] AMIDOAMINE AND POLYAMIDE CURING AGENTS, COMPOSITIONS, AND METHODS<br/>[FR] AGENTS, COMPOSITIONS ET PROCÉDÉS DE DURCISSEMENT D'AMIDOAMINE ET DE POLYAMIDES
  申请人：EVONIK DEGUSSA GMBH

  公开号：WO2017136333A1

  公开（公告）日：2017-08-10

  A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I): wherein each R is independently H or CH2CH2CH2NH2; R1 is H, CH3CH2CH2N-, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.

  本发明涉及一种包括肽胺固化剂组合物或聚酰胺固化剂组合物的组成物。该组合物包括以下反应产物：(1)胺组分，包括至少一种结构为(I)的多功能胺，其中每个R独立地为H或CH2CH2CH2NH2; R1为H、CH3CH2CH2N-、C1-C21烷基或C1-C21烯基; n为2; m为1或2；(2)脂肪酸或酯组分，选自二聚脂肪酸或酯组分、单功能脂肪酸或酯组分及其组合物。该肽胺固化剂组合物在常温下仍保持液态。
• Alkylated Aminopropylated Methylene-Di-(Cyclohexylamine) And Uses Thereof
  申请人：Vedage Gamini Ananda

  公开号：US20090018278A1

  公开（公告）日：2009-01-15

  The present invention provides epoxy curing agent compositions comprising alkylated aminopropylated methylene-di-(cyclohexylamine) compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.

  本发明提供了含有烷基化氨基丙基甲基二(环己胺)化合物的环氧固化剂组合物。还公开了氨基-环氧组合物和由这些氨基-环氧组合物制成的物品。
• Alkylated Polyalkylene Polyamines And Uses Thereof
  申请人：Vedage Gamini Ananda

  公开号：US20090029175A1

  公开（公告）日：2009-01-29

  The present invention provides curing agent compositions comprising alkylated polyalkylene polyamine compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.

  本发明提供了包含烷基化聚烯烃聚胺化合物的固化剂组合物。还公开了胺-环氧组合物和由这些胺-环氧组合物制成的制品。