N,N,N'-三(2-氨基乙基)乙二胺 | 31295-46-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N,N'-三(2-氨基乙基)乙二胺
• 中文别名: 曲恩汀杂质
• 英文名称: tris(2-aminoethyl)-N,N,N'-ethyldiamine
• 英文别名: 4-(2-aminoethyl)triethylenetetramine；trenen；1,2-Ethanediamine, N,N,N'-tris(2-aminoethyl)-；N'-[2-[bis(2-aminoethyl)amino]ethyl]ethane-1,2-diamine
• CAS: 31295-46-2
• 化学式: C₈H₂₃N₅
• mdl: MFCD03703434
• 分子量: 189.304
• InChiKey: ZORWGXDYTKQJQG-UHFFFAOYSA-N

物化性质

• 沸点：
  308.8±10.0 °C(Predicted)
• 密度：
  1.008±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -3
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  93.3
• 氢给体数：
  4
• 氢受体数：
  5

安全信息

• 危险等级：
  8
• 海关编码：
  2921290000

反应信息

• 作为反应物：
  描述：

  nickel tetrafluoroborate 、 potassium hexacyanochromate(III) 、 水 、 N,N,N'-三(2-氨基乙基)乙二胺 以 乙醇 、 水 为溶剂， 以18%的产率得到[tetracyanidochromate bis((tris(2-aminoethyl)-N,N,N'-ethyldiamine)(μ-cyanido)nickel(II))] tetrafluoroborate monohydrate
  参考文献：
  名称：

  六氰基金属酸盐分子化学，第三部分：二核，三核，四核，六核和七核铬镍配合物：自旋，结构各向异性，分子内和分子间交换偶联的控制

  摘要：

  摘要合成了九种由μ-氰基桥接的多核络合物[Cr（CN）n（CNNiL）6-n] m +（n = 0-5，L =五齿配体）：CrNi，五个CrNi2，CrNi3，CrNi5和CrNi6。该化合物已经通过IR光谱，质谱和X射线晶体学进行了充分表征。已经研究了它们的磁性，并评估了自旋和各向异性值以及分子内和分子间交换耦合。自旋状态从5/2到15/2（铁磁相互作用）变化，有效各向异性因子从0到0.5 cm-1变化。实验中，μ-氰基桥联的自旋载体Cr（III）和Ni（II）之间的交换耦合随着C–N–Ni角的增加而在+4.5到+18.3 cm-1之间变化。通过计算研究，可以提出磁结构相关性，并通过氰基桥合理化Cr（III）（t 2 g 3）和Ni（II）（例如2）之间交换相互作用的最相关特征。为了减少分子间的相互作用，已经通过共结晶成功地将铬（III）-镍（II）化合物与等价的钴（III）-镍（II）进行了稀释。

  DOI：

  10.1016/j.ica.2008.03.045
• 作为产物：
  描述：

  乙烯亚胺 、 三乙烯四胺 在 盐酸 作用下， 以 水 为溶剂， 以61.4%的产率得到四乙烯五胺
  参考文献：
  名称：

  Dalin, A. R.; Bobylev, V. A.; Suslikov, V. F., Journal of general chemistry of the USSR, 1988, vol. 58, # 9, p. 1868 - 1871

  摘要：

  DOI：

文献信息

• [EN] PROCESS FOR MANUFACTURING A CYCLIC UREA ADDUCT OF AN ETHYLENEAMINE COMPOUND<br/>[FR] PROCÉDÉ DE FABRICATION DE PRODUIT D'ADDITION D'URÉE CYCLIQUE D'UN COMPOSÉ ÉTHYLÈNEAMINE
  申请人：AKZO NOBEL CHEMICALS INT BV

  公开号：WO2019030191A1

  公开（公告）日：2019-02-14

  The invention pertains to a process for manufacturing a cyclic urea adduct of an ethyleneamine compound, the ethyleneamine compound having a linear -NH-CH2-CH2-NH- group, the process comprising the steps of - in an absorption step contacting a liquid medium comprising an ethyleneamine compound having a linear -NH-CH2-CH2-NH- group with a CO2-containing gas stream at a pressure of 1 -20 bara, resulting in the formation of a liquid medium into which CO2 has been absorbed, - bringing the liquid medium to cyclic urea formation conditions, and in an urea formation step forming cyclic urea adduct of the ethyleneamine compound, urea formation conditions including a temperature of at least 120°C, wherein the total pressure at the end of the urea formation step is at most 20 bara, wherein the temperature in the absorption step is lower than the temperature in the urea formation step. It has been found that the process according to the invention makes it possible to obtain cyclic urea adducts in an efficient manner in the absence of metal-containing catalysts and to perform the process under relatively mild conditions, in particular relatively low pressure. More specifically, by separating the CO2 absorption step from the urea formation step, the CO2 absorption step can be carried out at relatively low temperatures and pressures. And because the CO2 is already present in the system at the beginning of the urea formation step, the pressure in the urea formation step does not need to be high.

  该发明涉及一种制造具有线性-NH-CH2- -NH-基团的乙二胺化合物的环式脲加合物的工艺，该工艺包括以下步骤：-在吸收步骤中，将包含具有线性-NH- - -NH-基团的乙二胺化合物的液体介质与含CO2气流在1-20 bara的压力下接触，导致形成已吸收 的液体介质，-将液体介质带到环式脲形成条件，并在脲形成步骤中形成乙二胺化合物的环式脲加合物，脲形成条件包括至少120°C的温度，在脲形成步骤结束时的总压力最多为20 bara，在吸收步骤中的温度低于脲形成步骤中的温度。发现该发明的工艺使得在无金属催化剂的情况下以相对温和的条件，特别是相对低压下有效地获得环式脲加合物成为可能。更具体地，通过将 吸收步骤与脲形成步骤分离， 吸收步骤可以在相对低温和压力下进行。由于在脲形成步骤开始时系统中已经存在 ，因此脲形成步骤中的压力不需要很高。
• NITROGEN-CONTAINING HETEROCYCLIC EPOXY CURING AGENTS, COMPOSITIONS AND METHODS
  申请人：Air Products and Chemicals, Inc.

  公开号：US20170137562A1

  公开（公告）日：2017-05-18

  Amine-epoxy curing agents are disclosed including at least one saturated heterocyclic compound having two nitrogen heteroatoms according to formula (I) and at least one saturated fused bicyclic heterocyclic compound having three nitrogen heteroatoms according to formula (II): wherein X is independently selected from a hydrogen atom, a linear or branched C 1 to C 4 alkyl group and a substituted or un-substituted phenyl group, Y 1 is a direct bond or a divalent polyethylene polyamine group having 1 to 8 nitrogen atoms or a divalent polyethylene polyamine derivative having 1 to 8 nitrogen atoms, Y 2 is a direct bond or a divalent polyethylene polyamine group having 1 to 7 nitrogen atoms and R is independently a hydrogen atom or a group selected from C 1 -C 8 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups.

  本发明揭示了一种氨基-环氧固化剂，其中包括至少一个具有两个氮杂原子的饱和杂环化合物，其符合公式（I）；以及至少一个具有三个氮杂原子的饱和融合双环杂环化合物，其符合公式（II）：其中X独立地选自氢原子、线性或支链C1到C4烷基基团和取代或未取代的苯基基团，Y1是直接键或具有1到8个氮原子的二价聚乙烯多胺基团或具有1到8个氮原子的二价聚乙烯多胺衍生物，Y2是直接键或具有1到7个氮原子的二价聚乙烯多胺基团，R独立地是氢原子或从C1-C8线性、环状和支链烷基、烯基和烷基苯基基团中选择的基团。
• Hydrazine-Assisted Syntheses and Properties of Mercury Tellurides Containing Transition-Metal Complexes
  作者：Peipei Sun、Shuzhen Liu、Shufen Li、Limei Zhang、Hui Sun、Dingxian Jia

  DOI：10.1021/acs.inorgchem.7b00115

  日期：2017.6.5

  of [Hg2Te4]n. D and E are the first examples of telluromercurates incorporated with TM complex units via TM–Te bonds. Compound F contains fivefold coordinated [Zn(atep)]2+ cations and zigzag [Hg5Te124–]n polymeric anion. The [Hg5Te124–]n anion is a new species of the binary telluromercurates. It is built from [Hg4Te6] and [HgTe2(Te4)] subunits via interconnectivity, which generates Hg3Te3 and Hg4Te4

  在反应性和配位肼的协助下，过渡金属碲固化物[Mn（trien）（N 2 H 4）2 ] 2 [Hg 2 Te 4 ] 2（A），[Zn（trien）（N 2 H 4）2 ] Hg 2 Te 4（B），[Mn（tepa）（N 2 H 4）] 2 Hg 4 Te 12（C），[TM（trien）（Hg 2 Te 4）]（TM = Mn（D），Zn （E））和[Zn（atep）] 2 Hg 5 Te 12（atep = 4-（2-氨基乙基）三亚乙基四胺）（F）在三亚乙基四胺（trien）或四亚乙基五胺（tepa）溶剂中以元素Te作为前驱体溶剂热制备。较低的温度范围。化合物A和B由混合配位阳离子[TM（trien）（N 2 H 4）2 ] 2+（TM = Mn，Zn）和一维聚阴离子[Hg 2 Te 4 ] 2–和五元汞组成。2 Te 3环共面。化合物C由两个[Mn（tepa）（N 2 H 4）]
• PHOTOACTIVABLE NITROGEN BASES
  申请人：Dietliker Kurt

  公开号：US20100105794A1

  公开（公告）日：2010-04-29

  Compounds of the Formula (I), (II) and (III) wherein Ar is for example phenylene, biphenylene or naphthylene, all of which are unsubstituted or substituted by C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, CN, OR 11 , SR 11 , CH2OR 11 , COOR 12 , CONR 12 R 13 or halogen; R 1 , R 2 , R 7 and R 8 independently of one another other are hydrogen or C 1 -C 6 -alkyl; R 3 and R 5 together and R 4 and R 6 together form a C 2 -C 6 -alkylene bridge which is unsubstituted or substituted by one or more C 1 -C 4 -alkyl; R 11 is hydrogen or C 1 -C 6 -alkyl; R 12 and R 13 independently of one another for example are hydrogen, phenyl, C 1 -C 18 -alkyl, C 1 -C 18 -alkyl which is interrupted by one or more O; n is 1-10; X is O, S or NR 10 ; A and A 1 are suitable linking groups; are suitable as photolatent bases.

  公式(I)、(II)和(III)的化合物，其中Ar可以是苯基、联苯基或萘基，它们都可以是未取代或被C1-C4烷基、C2-C4烯基、CN、OR11、SR11、CH2OR11、COOR12、CONR12R13或卤素取代的；R1、R2、R7和R8独立地是氢或C1-C6烷基；R3和R5在一起，R4和R6在一起形成一个未取代或被一个或多个C1-C4烷基取代的C2-C6烷基桥；R11是氢或C1-C6烷基；R12和R13独立地可以是氢、苯基、C1-C18烷基、被一个或多个O中断的C1-C18烷基；n为1-10；X为O、S或NR10；A和A1是适当的连接基团；它们适用于光致潜基。
• Aqueous polyurethane-ureas dispersions and their use for the production of coatings having improved humidity resistance
  申请人：MOBAY CORPORATION

  公开号：EP0292750A1

  公开（公告）日：1988-11-30

  The present invention is directed to stable, aqueous dispersions of polyurethane-ureas which are formed by a) preparing isocyanate-terminated prepolymers containing about 5 to 190 milliequivalents per 100 grams of polyurethane-urea of chemically incorporated potential anionic groups and/or anionic groups and up to about 10% by weight, based on the weight of the polyurethane-urea, of lateral and/or terminal hydrophilic chains containing ethylene oxide units, b) converting a sufficient amount of the potential anionic groups to anionic groups either before, during or after preparing the prepolymer such that the blend of step (c) can be stably dispersed in water, wherein at least about 50% of the counterions of the anionic groups are derived from volatile organic compounds, c) blending said prepolymer either before, during or after step (b) with an epoxy resin which is not dispersible in water and contains at least one epoxide group, such that the equivalent ratio of potential anionic groups and anionic groups having counterions derived from volatile organic compounds to epoxide groups, is about 0.2 to 20.0, d) dispersing the blend of prepolymer and epoxy resin in water and e) chain extending said dispersed blend with a polyamine having an average functionality of about 2.0 to 6.0 in an amount sufficient to provide a ratio of amino groups to isocyanate groups of about 0.6:1.0 to 1.0:1.0. The present invention is also directed to the use of the aqueous polyurethane-urea dispersions for the production of coated substrates having improved humidity resistance.

  本发明涉及聚氨酯-脲的稳定水性分散体，其形成方法如下 a) 制备异氰酸酯封端预聚物，每 100 克聚氨酯脲中含有约 5 至 190 毫当量的化学合成的潜在阴离子基团和/或阴离子基团，以及按聚氨酯脲重量计最多约 10%（含环氧乙烷单元的侧向和/或末端亲水链）、 b) 在制备预聚物之前、期间或之后，将足够量的潜在阴离子基团转化为阴离子基团，使步骤（c）的混合物能稳定地分散在水中，其中至少约 50%的阴离子基团的反离子来自挥发性有机化合物、 c) 在步骤(b)之前、期间或之后，将所述预聚物与不能在水中分散且含有至少一个环氧基团的环氧树脂混合，使潜在阴离子基团和具有来自挥发性有机化合物的反离子的阴离子基团与环氧基团的当量比约为 0.2 至 20.0、 d) 将预聚物和环氧树脂的混合物分散在水中，并 e) 用平均官能度约为 2.0 至 6.0 的多胺对上述分散混合物进行扩链，其用量足以使氨基与异氰酸酯基的比例达到约 0.6:1.0 至 1.0:1.0。 本发明的另一个目的是使用水性聚氨酯-尿素分散体生产具有更好防潮性能的涂层基材。