N,N,N-三戊基-1-戊烷铵高氯酸盐 | 4328-09-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 中文名称: N,N,N-三戊基-1-戊烷铵高氯酸盐
• 中文别名: 四戊基高氯酸铵
• 英文名称: tetra-n-pentylammonium perchlorate
• 英文别名: tetrapentylammonium perchlorate；Tetra-pentyl-ammonium-hydroxid；N,N,N-Tripentylpentan-1-aminium perchlorate；tetrapentylazanium;perchlorate
• CAS: 4328-09-0
• 化学式: C₂₀H₄₄N*ClO₄
• 分子量: 398.027
• InChiKey: DSBPYRNQAGOJAI-UHFFFAOYSA-M

物化性质

• 熔点：
  117-119 °C

计算性质

• 辛醇/水分配系数(LogP)：
  1.81
• 重原子数：
  26
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  74.3
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险品标志：
  O,Xi
• 安全说明：
  S17,S26,S36
• 危险类别码：
  R8,R36/37/38
• 危险品运输编号：
  UN1479 5.1/PG 2

反应信息

• 作为产物：
  描述：

  四戊基溴化铵 在 sodium perchlorate 作用下， 生成 N,N,N-三戊基-1-戊烷铵高氯酸盐
  参考文献：
  名称：

  4-甲基-戊丹-2-一†中高氯酸季铵盐和苦味酸盐的电导率和解离常数†

  摘要：

  在25° C下研究了14个离子载体在4-甲基-戊烷-2-酮中的离解，即7个对称的（C 1至C 7）和5个不对称的季铵高氯酸根盐和2个四烷基苦味酸铵（均具有线性烃链）。 C（εr = 12.92）使用电导法。季铵阳离子，CT的缔合常数的值+，与CLO 4 -变化从（7.4±0.3）·10 3 L·摩尔-1为四甲基铵至（2.4±0.1）·10 3 L·摩尔-1用于四己基和四庚基铵；对Ct +的大小有明显的依赖性，特别是对于对称阳离子而言，是显而易见的。限制摩尔电导率的值Λ 0 / S·摩尔-1 ·厘米2变化从122.8至90.0（±0.7）。Λ的情节0相对于总的van der阳离子的范德华体积，的倒数立方根V的Ct -1/3，靠近线性高达四戊和十六，而对于较大的阳离子（以21至28个碳原子）在Λ 0值留下几乎是恒定的。同时，具有相同V Ct值的对称和不对称阳离子具有相同的迁移率。

  DOI：

  10.1021/je9008969

文献信息

• METHOD FOR PRODUCING SILOXANE RESIN
  申请人：Kaneka Corporation

  公开号：EP3208295A1

  公开（公告）日：2017-08-23

  An object of the present invention is to rapidly produce condensates of various silane compounds containing different organic substituents by accelerating condensation reactions of the silane compounds containing hydrolyzable silyl groups without using acid or base catalysts. The present invention relates to a method for producing a siloxane resin, including: hydrolyzing and condensing a silane compound (B) containing a hydrolyzable silyl group represented by formula (I) below using a neutral salt (A) as a catalyst, the formula (I) being: RnSiX4-n wherein R represents an organic group having a carbon atom directly bonded to Si; X represents a hydroxyl group or a hydrolyzable group; and n represents an integer of 0-3, provided that when n is 2 or greater, each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.

  本发明的目的是在不使用酸或碱催化剂的情况下，通过加速含有可水解硅基的硅烷化合物的缩合反应，快速生产含有不同有机取代基的各种硅烷化合物的缩合物。本发明涉及一种生产硅氧烷树脂的方法，包括：使用中性盐（A）作为催化剂，水解和缩合含有下式（I）所代表的可水解硅基的硅烷化合物（B），式（I）为：RnSiX4-n 其中，R 代表具有与 Si 直接键合的碳原子的有机基团；X 代表羟基或可水解基团；n 代表 0-3 的整数，但当 n 为 2 或更大时，每个 R 可以相同或不同，当（4-n）为 2 或更大时，每个 X 可以相同或不同。
• PHOTOCURABLE AND THERMOSETTING RESIN COMPOSITION, CURED PRODUCT AND LAMINATE
  申请人：Kaneka Corporation

  公开号：EP3235845A1

  公开（公告）日：2017-10-25

  A condensation product having a high epoxy group residual ratio is obtained by accelerating, with use of neither an acid catalyst nor a base catalyst, hydrolysis and condensation reaction of a silyl group in a silane compound containing an epoxy structure-containing group. Then, a cured product is formed, which has high abrasion resistance, high chemical resistance and low cure shrinkage. The condensation product is synthesized from silane compounds at a specific ratio in the presence of a neutral salt catalyst, which silane compounds are represented by General Formula (I) and General Formula (II), respectively, and then cured with use of a curing agent which cures an epoxy group.

  在不使用酸催化剂也不使用碱催化剂的情况下，通过加速含有环氧结构基团的硅烷化合物中硅烷基的水解和缩合反应，可获得具有高环氧基残留率的缩合产品。然后形成一种固化产品，它具有高耐磨性、高耐化学性和低固化收缩率。缩合产物是在中性盐催化剂存在下，以特定比例从硅烷化合物中合成的，硅烷化合物分别由通式（I）和通式（II）表示，然后使用固化剂固化环氧基团。
• Method for producing siloxane resin
  申请人：Kaneka Corporation

  公开号：US10040907B2

  公开（公告）日：2018-08-07

  A method for producing a siloxane resin, by hydrolyzing and condensing a silane compound containing a hydrolyzable silyl group represented by RnSiX4-n using a neutral salt as a catalyst. In the formula RnSiX4-n, R represents an organic group having a carbon atom directly bonded to Si, X represents a hydroxyl group or a hydrolyzable group, and n represents an integer of 0 to 3, provided that when n is 2 or greater each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.

  一种生产硅氧烷树脂的方法，使用一种中性盐作为催化剂，通过水解和缩合含有 RnSiX4-n 所代表的可水解硅基的硅烷化合物。在式 RnSiX4-n 中，R 代表具有与 Si 直接键合的碳原子的有机基团，X 代表羟基或可水解基团，n 代表 0 至 3 的整数，条件是当 n 为 2 或更大时，每个 R 可以相同或不同，而当 (4-n) 为 2 或更大时，每个 X 可以相同或不同。
• Photocurable and thermosetting resin composition, cured product, and laminate
  申请人：Kaneka Corporation

  公开号：US10563088B2

  公开（公告）日：2020-02-18

  A curable composition includes a condensation product having a weight average molecular weight of 30,000 or less and a curing agent, the condensation product being obtained by hydrolysis and condensation of a first and second silane compound in the presence of a neutral salt catalyst. The condensation product also has a ratio Y/X of 0.2 or less, wherein X is the number of moles of an OR3 group directly bonded to silicon atoms of the first and second silane compounds, and Y is the number of moles of an OR3 group directly bonded to a silicon atom of the condensation product. The first silane compound is represented by R1—(SiR2a(OR3)3-a), and the second silane compound is represented by R4—(SiR2a(OR3)3-a).

  一种可固化组合物包括一种重量平均分子量为 30,000 或更小的缩合产物和一种固化剂，该缩合产物是由第一和第二硅烷化合物在中性盐催化剂存在下水解和缩合得到的。缩合产物的比率 Y/X 也为 0.2 或以下，其中 X 是直接键合到第一和第二硅烷化合物硅原子上的 OR3 基团的摩尔数，Y 是直接键合到缩合产物硅原子上的 OR3 基团的摩尔数。第一硅烷化合物用 R1-(SiR2a(OR3)3-a)表示，第二硅烷化合物用 R4-(SiR2a(OR3)3-a)表示。
• PHOTOCURABLE AND THERMOSETTING RESIN COMPOSITION, CURED PRODUCT, AND LAMINATE
  申请人：Kaneka Corporation

  公开号：US20170283649A1

  公开（公告）日：2017-10-05

  A curable composition includes a condensation product having a weight average molecular weight of 30,000 or less and a curing agent, the condensation product being obtained by hydrolysis and condensation of a first and secondsilane compound in the presence of a neutral salt catalyst. The condensation product also has a ratio Y/X of 0.2 or less, wherein X is the number of moles of an OR 3 group directly bonded to silicon atoms of the first and second silane compounds, and Y is the number of moles of an OR 3 group directly bonded to a silicon atom of the condensation product. The first silane compound is represented by R 1 —(SiR 2 a (OR 3 ) 3-a ), and the second silane compound is represented by R 4 —(SiR 2 a (OR 3 ) 3-a ).