methylene dianthranilate | 111008-67-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methylene dianthranilate
• 英文别名: MDA；(2-Aminobenzoyl)oxymethyl 2-aminobenzoate
• CAS: 111008-67-4
• 化学式: C₁₅H₁₄N₂O₄
• 分子量: 286.287
• InChiKey: MCVOOAUFHIYPSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  105
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  二溴甲烷 生成 methylene dianthranilate
  参考文献：
  名称：

  SALUNKHE D. G.; JAGDALE M. H.; SALUNKHE M. M.; WADGAONKAR P. P., BULL. SOC. CHIM. BELG., 96,(1987) N 3, 247-248

  摘要：

  DOI：

文献信息

• Synthesis of the symmetrical methylene diesters from carboxylic ionic liquids
  作者：D. Gómora-Herrera、I.V. Lijanova、O. Olivares-Xometl、A. Toscano、N.V. Likhanova

  DOI：10.1139/cjc-2017-0042

  日期：2017.7

  The reaction between carboxylic ionic liquids and dichloromethane, which provokes the formation of symmetrical methylene diesters, was carried out. The synthesis of these ionic liquid compounds was carried out in a microwave reactor, and the characterization by spectroscopic techniques of methylene diesters (methylene di-2-furoate, methylene di-2-picolinate, methylene dianthranilate, and methylene dioleate) is described and the crystal structures discussed. The crystal packing of methylene dianthranilate is characterized by trimer formation due to hydrogen bonding via interactions between the hydrogen atom of the primary amine group and the oxygen of the carboxylic group.

  将羧基离子液体与二氯甲烷发生反应，引发对称亚甲基二酯的形成。这些离子液体化合物的合成在微波反应器中进行，并通过光谱技术对亚甲基二酯（亚甲基二-2-呋酸酯、亚甲基二-2-吡啶酸酯、亚甲基二邻氨基苯甲酸酯和亚甲基二油酸酯）进行表征，并讨论晶体结构。亚甲基二邻氨基苯甲酸酯的晶体排列特征是由于氢键作用而形成三聚体，通过主要胺基的氢原子与羧基的氧之间的相互作用。
• Aromatic polyether resins crosslinked by amic acid or imide side chain
  申请人：Won Chan Jong

  公开号：US20060217518A1

  公开（公告）日：2006-09-28

  The present invention relates to aromatic polyether resins crosslinked with amic acid or imide side chain, and more particularly, to the aromatic polyether resin crosslinked by amic acid or imide side chain, which is produced by heat curing of amic acid, wherein introduction of imide groups to the basic backbone provides excellent chemical resistance as well as heat resistance and improves surface roughness when coated as a thin film so that it can be suitable for films and flexible display plate substrate.

  本发明涉及用胺酸或酰亚胺侧链交联的芳香族聚醚树脂，更具体地说，涉及用胺酸或酰亚胺侧链交联的芳香族聚醚树脂，这种芳香族聚醚树脂是用胺酸加热固化制得的，其中在基本骨架上引入酰亚胺基团可提供优异的耐化学性和耐热性，在涂成薄膜时可提高表面粗糙度，从而适用于薄膜和柔性显示板基板。
• Salunkhe, D. G.; Jagdale, M. H.; Salunkhe, M. M., Bulletin des Societes Chimiques Belges, 1987, vol. 96, # 3, p. 247 - 248
  作者：Salunkhe, D. G.、Jagdale, M. H.、Salunkhe, M. M.、Wadgaonkar, P. P.

  DOI：——

  日期：——
• SALUNKHE D. G.; JAGDALE M. H.; SALUNKHE M. M.; WADGAONKAR P. P., BULL. SOC. CHIM. BELG., 96,(1987) N 3, 247-248
  作者：SALUNKHE D. G.、 JAGDALE M. H.、 SALUNKHE M. M.、 WADGAONKAR P. P.

  DOI：——

  日期：——
• US7662904B2
  申请人：——

  公开号：US7662904B2

  公开（公告）日：2010-02-16